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To ensure the safety of hydrogen refueling stations (HRSs) and protective targets in the surrounding area, this paper has introduced a risk‐based safe distance assessment method for a 35MP HRSs, emphasizing the impact of the station's surrounding area. The findings indicate that the safe distance is determined by vapor cloud explosion (VCE) accident scenarios arising from pipeline leaks (compressor‐hydrogen storage tanks) at 125 m. Therefore, a crucial focus should be placed on safeguarding and maintaining hydrogen pipelines. Furthermore, based on societal risk, the requirement of a 358‐m safe distance specifies that the population gathering within this range should be <500 people, virtually eliminating the possibility of constructing hydrogen stations in urban residential areas. Only in scenarios where VCE risks are not considered, less‐populated surrounding environments might reduce the safe distance of hydrogen stations. Eliminating the risk scenarios of VCE is a crucial approach to lowering the safe distance of HRSs, making establishing such stations in urban centers feasible. Therefore, factors such as open spaces, well‐ventilated facilities, and blast walls become critical elements in reducing the safe distance of HRSs. [ABSTRACT FROM AUTHOR]

Petrochemical enterprises store and process a large number of flammable, explosive, toxic and harmful chemicals, and their security protection systems are vulnerable. Once damaged by man‐made malicious will cause serious losses and adverse effects. Previous studies on the vulnerability of petrochemical enterprises have insufficient consideration of systematicity and uniqueness, and lack consideration of the correlation and game of vulnerability elements. In this study, from the perspective of system, the elements of the security accident system vulnerability are analyzed, and the vulnerability analysis model of security accident system is put forward by studying the interaction between the elements. Threat and exposure constitute the external vulnerability of security accident system, sensitivity and adaptability constitute the internal vulnerability of security accident system; and the threat plays a counter role with sensitivity and adaptability through exposure, which promotes the evolution of vulnerability; Moreover, the different vulnerability elements of security accident system evolve step by step, with the evolution of security accidents. Finally, an illustrative case proves the feasibility of the vulnerability analysis model proposed in this study. The results of this research enrich the theoretical research on vulnerability, provide a reference for the prevention and control of security accidents in petrochemical enterprises. [ABSTRACT FROM AUTHOR]