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The low‐cost cobalt(II) catalyst has been used for the first time to achieve P(O)‐radical‐mediated bisfunctionalization of alkenes with diarylphosphine oxide and peroxides. This simple process is performed under mild conditions to afford a wide variety of phosphonation‐peroxidation products in a one‐pot manner. Computational studies are carried out to provide a theoretical support for the P(O)‐radical‐involved bisfunctionalization of alkenes. [ABSTRACT FROM AUTHOR]

Common treatment for CAD includes strict photoprotection, emollients, topical corticosteroids or topical calcineurin inhibitors, and systemic immunosuppressants. To editor, Chronic actinic dermatitis (CAD), characterized by typical skin eruptions, is an immune-mediated disease mainly involve sun-exposed areas of the skin. [Extracted from the article]

It might affect patients' sleep quality and daily activities, making them anxious, depressed and unfocused.1,2 Topical corticosteroids (TCSs) and topical calcineurin inhibitors (TCIs) are the first-line medical therapy for AD. In recent years, targeted biological therapies, which are thought to be safer than systemic immunosuppressants, have been investigated in the treatment of AD. [Extracted from the article]