1. Effect of MnO2 on the Piezoelectric Properties of the 0.75Pb(Zr0.47Ti0.53)O3–0.25Pb(Zn1/3Nb2/3)O3 Ceramics.
- Author
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Hwi-Yeol Park, Chan-Hee Nam, In-Tae Seo, Jae-Hong Choi, Sahn Nahm, Hyeung-Gyu Lee, Kwang-Jin Kim, and Seong-Min Jeong
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PIEZOELECTRICITY ,CERAMICS ,INDUSTRIAL chemistry ,IRON metallurgy ,POWDER metallurgy ,ISOSTATIC pressing ,CRYSTALLOGRAPHY - Abstract
MnO
2 was added to 0.75Pb(Zr0.47 Ti0.53 )O3 –0.25Pb(Zn1/3 Nb2/3 )O3 (0.75PZT–0.25PZN) ceramics in order to make a high-power piezoelectric material. The Mn4+ ion produced a defect dipole consisting of an Mn4+ ion and an oxygen vacancy that transformed the 0.75PZT–0.25PZN ceramics into hard materials. The Qm value significantly increased with the addition of MnO2 and reached a value of 1680 for the 1.5 mol% MnO2 -added 0.75PZT–0.25PZN ceramic. Moreover, this specimen exhibited a high kp of 0.53 with a ℇ3 T /ℇ0 of 1518. Additionally, the 1.5 mol% MnO2 -added 0.75PZT–0.25PZN ceramics sintered at 900°C for 4 h also exhibited high piezoelectric properties of Qm =1115, kp =0.50, and ℇ3 T /ℇ0 =1537. [ABSTRACT FROM AUTHOR]- Published
- 2010
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