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To investigate the electromagnetic scattering problem related to a foil in a turbulent hypersonic plasma environment, the scattering field formulas for hypersonic plasma turbulence were improved by applying the anisotropic power spectrum. Using the theory of electromagnetic scattering of a conducting object, the second moment of a conducting object's scattering field is obtained in the hypersonic plasma turbulence. Finally, the backscattering cross-section of the foil surrounded by the hypersonic plasma turbulence was calculated. The results showed that the fractal dimension led to an increase in the complexity of the hypersonic turbulent structure, and thus had a greater influence on the electromagnetic wave scattering. The scattering cross-section of the foil in the hypersonic turbulence decreases rapidly. Meanwhile, the anisotropic parameters in the model represent scale-dependent stretching of the turbulent eddy. As the anisotropic parameters of the turbulence increase, there will be less scattering of the hypersonic turbulence. At this point, the total scattering cross-section of the foil in hypersonic plasma turbulence increases gradually. By improving the aerodynamic shape of the aircraft, it can produce a large number of anisotropic turbulent eddies which can effectively improve the passive jamming capability when the foil is cast. [ABSTRACT FROM AUTHOR]

On the basis of the fractal theory and measurements of hypersonic turbulence, the spectral index, and twodimensional (2D) power spectrum of the refractive index fluctuation are derived, and the 2D band-limited Weierstrass fractal function is applied to simulate the refractive index fluctuation in hypersonic turbulence. Thus, the impact of hypersonic turbulence on synthetic aperture radar (SAR) imaging system is simulated using the fractal phase screen method. Results show that the resolution of SAR imaging is severely deteriorated under the influence of hypersonic turbulence. The phase error caused by the turbulence microstructures in the plasma sheath becomes more apparent with the increase in the fractal dimension of the hypersonic turbulence. The larger Reynolds number associated with the hypersonic turbulence results in a more evident microstructure fluctuation and inferior imaging quality. Furthermore, when an aircraft flies at high speed, the azimuth focus is considerably sensitive to the turbulence microstructure along the direction of flow field. Consequently, hypersonic turbulence in the plasma sheath has a significantly larger effect on the azimuth than on the range in point-target imaging. [ABSTRACT FROM AUTHOR]

We demonstrated an asymmetric 1,3-dipolar cycloaddition of azomethine betaines with alkylidene malonates by using a chiral N, N′-dioxide-NiII complex as a catalyst. Both aromatic- and aliphatic-substituted alkylidene malonates were found to be suitable for the reaction. A range of trans-pyrazolone derivatives was exclusively obtained with excellent yields (up to 99 % yield) and good enantioselectivities (up to 97 % ee) under mild reaction conditions. The reaction could be carried out on a gram scale with the good results being maintained. Control experiments were performed to elucidate the specific diastereoselectivity of the reaction. The formation of single trans isomers was dominated by secondary orbital interactions between the ester groups of the dipolarophile and the azomethine imine. On the basis of the experimental results and previous reports, a possible catalytic model was assumed. [ABSTRACT FROM AUTHOR]

Optimized conditions render possible the preparation of various pyrazolidinone derivatives as important substructures. [ABSTRACT FROM AUTHOR]