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1. A Co2N2 Diamond-Core Resting State of Cobalt(I): A Three-Coordinate CoI Synthon Invoking an Unusual Pincer-Type RearrangementThis work was supported by Indiana University, the Camille and Henry Dreyfus Foundation (Teacher-Scholar Award to D.J.M.), the Alfred P. Sloan Foundation (Fellowship award to D.J.M.), the National Institutes of Health (HG003894 to M.-H.B.), and the National Science Foundation (CHE-0348941 grant and PECASE award to D.J.M.). A.R.F. acknowledges the Department of Education for a GAANN Fellowship and Dr. Allen R. Siedle for insightful advice. We are also grateful to Prof. Karsten Meyer and Dr. Ingrid Castro-Rodriguez for collecting SQUID data of compound 1.

3. dl-Proline.

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