Search

Solid‐state batteries (SSBs) that use solid electrolytes instead of flammable liquid electrolytes have the potential to generate higher specific capacity and offer better safety. Magnesium (Mg) based SSBs with Mg metal anodes are considered to be one of the most promising energy storage candidates, because it gives high theoretical volumetric capacities of 3830 mAh cm−3. Here, we demonstrate an atomic layer deposition (ALD) process with a double nitrogen plasma process that successfully produces nitrogen‐incorporated magnesium phosphorus oxynitride (MgPON) solid‐state electrolyte (SSE) thin films at a low deposition temperature of 125 °C. The ALD MgPON SSEs exhibit an ionic conductivity of 0.36 and 1.2 μS cm−1 at 450 and 500 °C, respectively. The proposed ALD strategy shows the ability of conformal deposition nitrogen‐doped SSEs on pattered substrates and is attractive for using nitride ion‐conducing films as protective or wetting interlayers in solid‐state Mg and Li batteries. [ABSTRACT FROM AUTHOR]

Solid‐state batteries (SSBs) that use solid electrolytes instead of flammable liquid electrolytes have the potential to generate higher specific capacity and offer better safety. Magnesium (Mg) based SSBs with Mg metal anodes are considered to be one of the most promising energy storage candidates, because it gives high theoretical volumetric capacities of 3830 mAh cm−3. Here, we demonstrate an atomic layer deposition (ALD) process with a double nitrogen plasma process that successfully produces nitrogen‐incorporated magnesium phosphorus oxynitride (MgPON) solid‐state electrolyte (SSE) thin films at a low deposition temperature of 125 °C. The ALD MgPON SSEs exhibit an ionic conductivity of 0.36 and 1.2 μS cm−1 at 450 and 500 °C, respectively. The proposed ALD strategy shows the ability of conformal deposition nitrogen‐doped SSEs on pattered substrates and is attractive for using nitride ion‐conducing films as protective or wetting interlayers in solid‐state Mg and Li batteries. [ABSTRACT FROM AUTHOR]

We propose a three-terminal nanometer metal switch that utilizes a solid electrolyte where a nanoscale metal filament is stretched and retracted. Its operating principle is based on electrochemical reaction and ion migration in the electrolyte. The fabricated device is composed of a solid electrolyte layer (CuS), a gate (Cu), a source (Cu), and a drain (Pt). After the Cu filament is formed between the source and the drain by applying the drain voltage, repeatable on/off switching in the drain current is obtained by controlling the gate voltage. The on/off current ratio can be as high as 10, and the programmable cycle is around 50. Each state can be kept for up to 40 days. Since the gate is separated from the current path, the switching current can be reduced to 10 μA, which is two orders of magnitude smaller than that of a two-terminal switch. In this paper, we present the operating principle and electrical characteristics of the three-terminal switches, and discuss how suitable they are for reconfigurable circuits. © 2011 Wiley Periodicals, Inc. Electron Comm Jpn, 94(4): 55-61, 2011; Published online in Wiley Online Library (). DOI 10.1002/ecj.10214 [ABSTRACT FROM AUTHOR]

We have investigated solid electrolyte switches that utilize electrochemical reactions (deposition and dissolution) of metallic ions. The switch turns off or on when a metallic bridge electrochemically forms or dissolves in the solid electrolyte. Each state is nonvolatile and the switching is repeatable up to 105 cycles. The promising application is a programmable switch in a field programmable logic because of its small size (<30 nm) and low ON resistance (<100Ω). This paper discusses the electrical characteristics, operation principle, and applications of the solid electrolyte switch. © 2008 Wiley Periodicals, Inc. Electr Eng Jpn, 165(1): 68–73, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/eej.20542 [ABSTRACT FROM AUTHOR]