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Nickel oxide is one of the most promising hole‐transporting materials in inverted perovskite solar cells (PSCs) but suffers from undesired reactions with perovskite which leads to limited device performance and stability. Self‐assembled monolayers (SAMs) are demonstrated to effectively optimize the NiOx/perovskite interface, but the significance of the compactness of the SAM at the interface is less investigated. Here, a series of methoxy‐substituted triphenylamine functionalized benzothiadiazole (TBT) based SAM molecules, TBT‐BA, TBT‐FBA, and TBT‐DBA, with benzoic acid, 2‐fluorobenzoic acid and isophthalic acids as anchoring groups are used to modify NiOx. TBT‐BA with the simplest structure is demonstrated to form the densest SAM on NiOx, thus optimized NiOx/SAM/perovskite interface is achieved with enhanced charge collection and suppressed interfacial reaction and recombination. TBT‐BA can also passivate the perovskite most effectively due to the highest binding energy toward perovskite, thus the corresponding inverted PSCs show the highest PCE of 24.8% and maintain 88.7% of the initial PCE after storage at 60 °C for 2635 h in the glovebox. The work provides important insights into designing SAM molecules for modification transporting layers for efficient and stable PSCs. [ABSTRACT FROM AUTHOR]

BACKGROUND: Resistance to dicamba in Chenopodium album was first documented over a decade ago, however, the molecular basis of dicamba resistance in this species has not been elucidated. In this research, the resistance mechanism in a dicamba‐resistant C. album phenotype was investigated using a transcriptomics (RNA‐sequence) approach. RESULTS: The dose–response assay showed that the resistant (R) phenotype was nearly 25‐fold more resistant to dicamba than a susceptible (S) phenotype of C. album. Also, dicamba treatment significantly induced transcription of the known auxin‐responsive genes, Gretchen Hagen 3 (GH3), small auxin‐up RNAs (SAURs), and 1‐aminocyclopropane‐1‐carboxylate synthase (ACS) genes in the susceptible phenotype. Comparing the transcripts of auxin TIR/AFB receptors and auxin/indole‐3‐acetic acid (AUX/IAA) proteins identified from C. album transcriptomic analysis revealed that the R phenotype contained a novel mutation at the first codon of the GWPPV degron motif of IAA16, resulting in an amino acid substitution of glycine (G) with aspartic acid (D). Sequencing the IAA16 gene in other R and S individuals further confirmed that all the R individuals contained the mutation. CONCLUSION: In this research, we describe the dicamba resistance mechanism in the only case of dicamba‐resistant C. album reported to date. Prior work has shown that the dicamba resistance allele confers significant growth defects to the R phenotype investigated here, suggesting that dicamba‐resistant C. album carrying this novel mutation in the IAA16 gene may not persist at high frequencies upon removal of dicamba application. © 2024 The Authors. Pest Management Science published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry. [ABSTRACT FROM AUTHOR]

Background: Robotic gastrectomy is increasingly utilized for gastric cancer, but high morbidity remains a concern. Myosteatosis or low skeletal muscle density reflecting fatty infiltration, associates with complications after other cancer surgeries but has not been evaluated for robotic gastrectomy. Methods: This retrospective study analysed 381 patients undergoing robotic gastrectomy for gastric cancer from September 2019 to October 2022. Myosteatosis was quantified on preoperative computed tomography (CT) images at lumbar 3 (L3). Propensity score matching addressed potential confounding between myosteatosis and non‐myosteatosis groups. Outcomes were postoperative complications, 30 days mortality, 30 days readmissions and survival. Results: Myosteatosis was present in 33.6% of patients. Myosteatosis associated with increased overall (47.7% vs. 26.5%, p < 0.001) and severe complications (12.4% vs. 4.9%, p < 0.001). After matching, myosteatosis remained associated with increased overall complications, major complications, intensive care unit (ICU) transfer and readmission (all p < 0.05). Myosteatosis independently predicted overall [odds ratio (OR) = 2.86, 95% confidence interval (CI): 1.57–5.20, p = 0.001] and severe complications (OR = 4.81, 95% CI: 1.51–15.27, p = 0.008). Myosteatosis also associated with reduced overall (85.0% vs. 93.2%, p = 0.015) and disease‐free survival (80.3% vs. 88.4%, p=0.029). On multivariate analysis, myosteatosis independently predicted poorer survival [hazard ratio (HR) = 2.83, 95% CI: 1.32–6.08, p=0.012] and disease‐free survival (HR = 1.83, 95% CI: 1.01–3.30, p=0.032). Conclusion: Preoperative CT‐defined myosteatosis independently predicts increased postoperative complications and reduced long‐term survival after robotic gastrectomy for gastric cancer. Assessing myosteatosis on staging CT could optimize preoperative risk stratification. [ABSTRACT FROM AUTHOR]

The excessive use of nonrenewable energy has brought about serious greenhouse effect. Converting CO2 into high‐value‐added chemicals is undoubtedly the best choice to solve energy problems. Due to the excellent cost‐effectiveness and dramatic catalytic performance, nickel‐based catalysts have been considered as the most promising candidates for the electrocatalytic CO2 reduction reaction (eCO2RR). In this work, the electrocatalytic reduction mechanism of CO2 over Ni‐based materials is reviewed. The strategies to improve the eCO2RR performance are emphasized. Moreover, the research on Ni‐based materials for syngas generation is briefly summarized. Finally, the prospects of nickel‐based materials in the eCO2RR are provided with the hope of improving transition‐metal‐based electrocatalysts for eCO2RR in the future. [ABSTRACT FROM AUTHOR]

2D/3D‐structured perovskites are promising for high‐performance and stable solar cells due to the passivation ability and hydrophobic character of the large organic cations. However, most of the 2D/3D‐structured perovskites prepared by adding ammonium halides into the precursors or depositing ammonium halides on top of a 3D perovskite film ignore the buried interface which is crucial for the device efficiency and stability. Here, 2D/3D/2D‐structured perovskite films with optimized buried interface are constructed by depositing phenethylammonium bromide (PEABr) on top and 2D perovskite PEA2FA2Pb3Br10 at the bottom of 3D Cs0.07FA0.85MA0.08Pb(I0.95Br0.05)3 perovskite. Thus, a power conversion efficiency (PCE) of 24.2% is achieved due to the minimal nonradiative recombination. The encapsulated device also shows an improved stability, maintaining 93.5% of the initial value after 1000 h under 1 sun equivalent illumination at the maximum power point. This strategy may provide important insights into designing perovskite film structures to achieve high‐performance solar cells with high stability. [ABSTRACT FROM AUTHOR]

Background: Eosinophilic chronic rhinosinusitis (ECRS) is predominantly characterized by nasal type 2 inflammation. The pathogenesis of this condition is complex. High levels of IL‐17A are associated with eosinophil infiltration in some inflammatory diseases and contribute to the severity and insensitivity of corticosteroid therapy for chronic rhinosinusitis. Methods: In the first experiment, we constructed a modified ECRS mouse model using four groups of mice: phosphate‐buffered saline (PBS)‐sensitized and nasal instillation (control); PBS‐sensitized and Staphylococcus aureus enterotoxin B (SEB) nasal instillation after nasal tamponade (SEB group); ovalbumin (OVA)‐sensitized and nasal instillation (OVA group); and OVA‐sensitized combined with OVA and SEB nasal instillation after nasal tamponade (OVA + SEB group). In the second experiment, we examined the role of IL‐17A by dividing the mice into four groups: control group; ECRS group; ECRS + anti‐IL‐17A group; and ECRS + IL‐17A group. The latter two groups received intraperitoneal injections of anti‐IL‐17A antibody or IL‐17A, respectively. Results: We constructed a modified ECRS mouse model (OVA + SEB group), where the IL‐17A levels were upregulated in the nasal sinus of ECRS mice and the IL‐17A levels were significantly correlated with eosinophil infiltration. We further demonstrated that IL‐17A induced type 2 inflammation and eosinophil infiltration in the ECRS group of mice. In contrast, IL‐17A neutralization attenuated type 2 inflammatory cytokine secretion and eosinophil infiltration. Conclusion: OVA sensitization and unilateral nasal tamponade, combined with SEB and OVA alternate nasal instillation (OVA + SEB group), could be used to construct a more typical ECRS mouse model in which IL‐17A enhanced the expression of type 2 cytokines and eosinophil infiltration. [ABSTRACT FROM AUTHOR]

Over the past 20 years, the Gravity Recovery and Climate Experiment (GRACE), and its successor mission, GRACE‐Follow On (GRACE‐FO) have made significant contributions to time‐variable gravity field modeling. A Chinese low‐low satellite‐to‐satellite tracking gravimetry mission (i.e., Chinese future gravimetry mission) has been confirmed to be selected as the polar‐orbiting satellite gravimetry mission for China, because of the capability to collect gravity data globally. However, the analysis of potential contributions to geosciences from GRACE‐FO coupling with the Chinese future gravimetry mission is still limited. This study combines GRACE‐FO and Chinese future gravimetry missions as the Dual GRACE‐like Polar satellite Constellation (DGPC). By carefully choosing the initial orbit parameters of the Chinese future gravimetry mission with the differential evolution algorithm, the DGPC is expected to mitigate the temporal aliasing effects by improving the temporal resolution of time‐variable gravity solutions (i.e., 1‐day and 3‐day solutions). Regarding the spectral‐domain evaluation, zonal, tesseral, and sectorial coefficients estimated by the DGPC show approximately 6.01%–13.42% noise reductions compared with GRACE‐FO. Regarding the spatial‐domain evaluation, the DGPC can suppress noises of about 39.44% and 31.12% in annual amplitude and long‐term trend, respectively. On this basis, this paper analyzes the effectiveness of the DGPC in potential contributions to geosciences (e.g., hydrology, glaciology, and seismology). Specifically, the DGPC can improve accuracy by about 36.96%, 25.85%, and 33.16% with respect to GRACE‐FO for signals in the subhumid basin, signals of ice‐sheet mass balance over Greenland, and coseismic displacement of the fault zone, respectively. In general, the potential capability for high‐frequency signals recovery of the DGPC would facilitate contributions of satellite gravimetry to geosciences. Plain Language Summary: The Gravity Recovery And Climate Experiment (GRACE) mission and its successor GRACE Follow On (GRACE‐FO) have made significant contributions to time‐variable gravity field modeling. A polar gravity satellite mission (i.e., Chinese future gravimetry mission) has been confirmed to be selected as the polar‐orbiting satellite gravimetry mission for China because of its capability to collect gravity data globally. Including the GRACE‐FO mission, it is expected that there will be two polar pairs of gravity satellites (i.e., dual GRACE‐like polar satellite constellation) simultaneously within the next few years. What can we expect from the dual GRACE‐like polar satellite constellation? In this study, we introduce an optimization algorithm (i.e., differential evolution algorithm) to carefully choose the initial orbit parameters of the Chinese future gravimetry mission. The dual GRACE‐like polar satellite constellation has been demonstrated to have the potential to mitigate the temporal aliasing effects of time‐variable gravity solutions. It is found that the dual GRACE‐like polar satellite constellation can improve accuracy by about 36.96%, 25.85%, and 33.16% with respect to GRACE‐FO for signals in the subhumid basin, signals of ice‐sheet mass balance over Greenland, and coseismic displacement of the fault zone, respectively. The temporal improvement of Earth's mass transport estimated by coupling GRACE‐FO with a Chinese polar gravity satellite mission would facilitate contributions of satellite gravimetry to geosciences. Key Points: This paper introduces the differential evolution algorithm into the design of the dual Gravity Recovery And Climate Experiment (GRACE)‐like polar satellite constellationImproving the temporal resolution of time‐variable gravity solutions can potentially contribute to mitigating the temporal aliasing effectsThe dual GRACE‐like polar satellite constellation has high‐frequency signal recovery capabilities and stimulates potential contributions to geosciences [ABSTRACT FROM AUTHOR]

The inorganic perovskite solar cells (IPSC) are promising in the context of simultaneously delivering high efficiency and good stability. Developing a high‐performance and larger band gap IPSC is particularly in demand for commercialization due to their suitability to match with the prevailing silicon solar cells for tandem devices, while this is hindered by the poor morphology and phase stability of inorganic perovskite films. To address this issue, this work develops a combined method of nonstoichiometric composition and post‐cation exchange to improve the morphology and phase stability of the CsPbI2Br IPSCs, and achieves a record efficiency of 17.80%. This work finds that excessive PbI2 regulates the CsPbI2Br film crystallization, and thus, a high‐quality perovskite film with enlarged grains is obtained. Further depositing the formamidinium iodide on top of the CsPbI2Br perovskite induces cation exchange during the post‐annealing process, which increases the phase stability of the perovskite film and significantly improves the device efficiency and stability. Therefore, this work provides an avenue toward high‐performance IPSCs, via the nonstoichiometric and ion exchange method. [ABSTRACT FROM AUTHOR]

In this paper, we prove a quantitative version of the isoperimetric inequality involving the second non‐trivial eigenvalue of the Laplacian with Neumann boundary condition established by Bucur and Henrot [5]. [ABSTRACT FROM AUTHOR]

Comprehensive Summary: The surface properties and chemical interactions are critical for perovskite solar cells (PVSCs). In this work, we show that the polypropylene glycol (PPG) can simultaneously passivate the NiOx surface and grain boundaries of perovskite films, allowing more efficient charge transfer at the anode interface and reducing the recombination of PVSCs. As a result, the open‐circuit voltage (Voc) of MAPbI3 based inverted PVSCs increases from 1.087 V to 1.127 V, and the short‐circuit current density (Jsc) is increased from 20.87 mA·cm–2 to 22.32 mA·cm–2, thereby realizing the improvement of the device power conversion efficiency (PCE) from 18.34% to 20.12%. Moreover, the steady‐state output of the PVSCs is remarkably improved by incorporating PPG. Further analysis of surface properties suggests that part of the PPG at the interface can permeate into the precursor solution with the help of DMF solvent and remain in the perovskite layer to form a concentration gradient. The ether bond of PPG and the uncoordinated Pb2+ in the perovskite are coordinated to achieve passivation effects and improve device performance. Our work provides a rational strategy for the preparation of high‐performance PVSCs. [ABSTRACT FROM AUTHOR]

Lysosomes are degradative organelles and play vital roles in a variety of cellular processes. Ion channels on the lysosomal membrane are key regulators of lysosomal function. TMEM175 has been identified as a lysosomal potassium channel, but its modulation and physiological functions remain unclear. Here, we show that the apoptotic regulator Bcl‐2 binds to and inhibits TMEM175 activity. Accordingly, Bcl‐2 inhibitors activate the channel in a caspase‐independent way. Increased TMEM175 function inhibits mitophagy, disrupts mitochondrial homeostasis, and increases production of reactive oxygen species (ROS). ROS further activates TMEM175 and thus forms a positive feedback loop to augment apoptosis. In a 1‐methyl‐4‐phenyl‐1,2,3,6‐tetrahydropyridine (MPTP) mouse model of Parkinson's disease (PD), knockout (KO) of TMEM175 mitigated motor impairment and dopaminergic (DA) neuron loss, suggesting that TMEM175‐mediated apoptosis plays an important role in Parkinson's disease (PD). Overall, our study reveals that TMEM175 is an important regulatory site in the apoptotic signaling pathway and a potential therapeutic target for Parkinson's disease (PD). Synopsis: The anti‐apoptotic mitochondrial protein Bcl‐2 regulates lysosomal K+ channel TMEM175. TMEM175 forms a positive feedback loop with ROS to augment apoptosis and promote the death of DA neurons in Parkinson's disease. Anti‐apoptotic mitochondrial protein Bcl‐2 binds to and regulates lysosomal potassium channel TMEM175.TMEM175 inhibits mitophagy, impairs mitochondrial function, and consequently increases ROS production.ROS activates TMEM175 through a positive feedback loop to augment apoptosis.TMEM175‐mediated apoptosis promotes the death of dopaminergic neurons in Parkinson's disease. [ABSTRACT FROM AUTHOR]

Topological effects have endowed brand new properties to electronic and photonic systems, including the unidirectional propagating edge states and the associated intrinsic robustness. Recent progress in topological photonics has explored novel optical effects and motivated the related photonic devices. Here, a new mechanism for controlling the electromagnetic wave flow based on spatiotemporal metasurface assisted with parity‐time (PT) symmetric modulations is proposed, and a proof‐in‐principle experiment is conducted in the microwave regime for verification. It is shown that the spatiotemporal metasurface can provide a powerful platform for realizing robust spin‐momentum coupled surface states, in which the induced effects are similar to those discovered in the topological insulators and quantum spin‐Hall systems. With the aid of programmable control unit, the generated spin‐momentum coupling can be flexibly switched in real time. The proposed scheme is expected to construct a novel system for controlling the evanescent light flows and facilitate the investigation of physical effects that are hard to realize in the traditional photonic topological systems. [ABSTRACT FROM AUTHOR]

Network traffic security inspection is vital in today's network. However, due to the increasing user demand, security inspection resources are becoming a bottleneck of the network, therefore bringing down network throughput. In this paper, we proposed an OpenFlow‐based flow management prototype, which can properly allocate limited security resources in order to achieve the objective of making the best use of security resources without compromising network throughput. We introduced a capacity reservation scheme to enforce network security and avoid security devices becoming congested. In order to optimize utilization of security devices, we formulated the resource‐constrained problem as an integer linear programming problem and solved it. Extensive experiments were performed to attest to the effectiveness of our prototype. Finally, we analyzed results of the experiment, including the impact on network performance of two parameters in the optimization formulations. Compared to other works, we have the following strengths: our model was implemented on a general network topology with distributed security devices; we formulated the flow allocation problem into a linear programming problem and performed the optimization in the controller in real time; and no pre‐knowledge about the network, hosts, or traffic was needed. [ABSTRACT FROM AUTHOR]

Although the 2D spacer modification is widely studied in perovskite solar cells (PVSCs), the energy level alignment between the 2D/3D interfaces makes it unfavorable for top surface passivation in the inverted p‐i‐n device structure. To address this issue, the effect of bottom interface modification is studied with three representative 2D spacers, i.e., the Ruddlesden‐Popper 2D spacer, Dion‐Jacobson 2D spacer, and strong passivation 2D spacer, in inverted p‐i‐n PVSCs. After optimization, the PVSCs with these 2D spacer modifications universally exhibit the best efficiencies of ≈21.6%, which constitutes dramatic improvement compared to the control device (20.7%). By lifting off the perovskite layer, the optoelectronic properties of the bottom surface are studied, and the mechanism underlying the improved device performance is unveiled to be uniformly originated from the formation of 2D/3D heterojunction, where the cascade valence band facilitates the hole collection and electron back scattering field suppresses the charge recombination at the anode interface. Besides, the unencapsulated device retains 90% of initial efficiency after 30 days of storage in ambient air with a relative humidity of 30 ± 5%, indicating excellent stability against moisture and oxygen. This study provides insight into the bottom interface modification with diverse 2D spacers for high‐performance p‐i‐n structured PVSC devices. [ABSTRACT FROM AUTHOR]

Controlling the crystallization of perovskite film is critical for high‐performance perovskite solar cells (PVSCs), and temperature is the key factor dominating the nucleation and crystal growth. Herein, it is demonstrated that the inconspicuous ambient temperature plays an important role in reaching high‐quality perovskite film and high‐performance PVSCs. It is observed that the ambient temperature greatly affects the composition of as‐prepared perovskite film, which dramatically influences the perovskite film morphology during the subsequent annealing process. Remarkably, the device prepared at the optimal ambient temperature of 29 °C exhibits the best power conversion efficiency of 20.91% with little hysteresis. This represents one of the best results for inverted PVSCs based on pristine MAPbI3 system. In addition, the PVSC prepared at 29 °C shows good stability with 80% of its initial efficiency after 30d in air with a humidity of 45%. Overall, the importance of ambient temperature for crystallization of the perovskite film is emphasized, and this work should have implications for controlling the morphology for high‐performance PVSCs. [ABSTRACT FROM AUTHOR]

2D Dion–Jacobson (DJ) perovskites show structural stability and tunability and are regarded as promising photovoltaic materials. The spacer cations play an important impact on exciton separation and charge transport of 2D perovskites. Herein, a novel spacer with thiazole as core, 2‐thiazolemethanammonium (AMT), owning characters of small molecular size, delocalized π‐electrons, and strong electron‐withdrawing ability, is introduced to construct 2D DJ perovskites. Owing to the strong orbital coupling between AMT spacer and inorganic layers, the AMT‐based perovskite exhibits type II quantum well structure, which is favorable for exciton separation. On contrary, such interaction does not appear in the DJ perovskite when aliphatic propyldiammonium (PDA), with a similar length, is used as spacer. The AMT spacer can also induce better crystallinity, resulting in reduced defect density and improved charge transport ability. The optimized device based on (AMT)MA3Pb4I13 exhibits a power conversion efficiency (PCE) of 19.69%, which is a record for 2D DJ perovskite solar cells (PSCs) (n ≤ 4). This work provides deep understanding of the impact of aromatic spacer on the electronic structure of 2D DJ perovskites and the corresponding photovoltaic performance and provides a new opportunity toward highly efficient and stable PSCs. [ABSTRACT FROM AUTHOR]

Paraneoplastic autoimmune encephalitis (PAE) represents a group of rare neurological syndromes associated with neoplastic diseases. Here, we report a case that multiple anti‐neuronal antibodies were present in a patient with PAE who developed both small cell lung cancer and colorectal adenocarcinoma. Furthermore, the immunopathological investigation of the colorectal adenocarcinoma revealed the formation of abnormal neuronal antigens and a massive infiltration of plasma cells in the tumor tissue. These findings support the hypothesis that expression of neuronal antigens in neoplasm initiates autoimmune responses in PAE. [ABSTRACT FROM AUTHOR]

2D perovskite solar cells (2D PVSCs) show good stability for commercialization. However, their power conversion efficiency (PCE) is relatively low. In this work, a post‐treatment strategy by simultaneously applying light and heat to quasi‐2D PVSCs, obtaining a record PCE of 18.24% is developed. It is found that heat‐treating PVSCs in the dark slightly increases the device performance over time at temperatures below 75 °C, whereas the performance deteriorates rapidly at temperatures above 100 °C. Upon illumination, the device efficiency is significantly improved, particularly when the thermal‐treatment temperature is increased to 100 °C. A comprehensive carrier dynamic study reveals that the enhanced performance can be attributed to the reduced quasi‐2D perovskite defect states and improved charge collection. In addition, this strategy enables better stability, and an unencapsulated device can retain 90% of its original PCE after 1340 h of direct exposure to air with a humidity of 50 ± 5%. Thus, the strategy paves the way for the commercialization of quasi‐2D PVSCs. [ABSTRACT FROM AUTHOR]

2D Dion–Jacobson (DJ) perovskite solar cells (PVSCs) with a high power conversion efficiency (PCE) are currently predominately fabricated via a hot‐casting process. The reason lies in the difficulty in preparing high‐quality perovskite films under mild conditions when the application of divalent ammonium removes the weak interaction from the spacer cation layer. Herein, the morphology of the 2D DJ perovskite film with a rigid piperidinium ring is tuned through a room‐temperature spin‐coating method, with the aid of a methylammonium thiocyanate (MASCN) additive. With the optimized amount of MASCN addition, the perovskite films deposited on the poly[bis(4‐phenyl)(2,4,6‐trimethylphenyl)amine] (PTAA)/poly[(9,9‐bis(30‐(N,N‐dimethylamino)propyl)‐2,7‐uorene)‐alt‐2,7‐(9,9‐dioctylfuorene)] (PFN) substrate exhibit fine crystallinity, preferred orientation, decreased defects, and better energy‐level alignment with the hole transport layer. The device with the inverted planar structure presents a JSC of 17.91 mA cm−2, VOC of 1.19 V, fill factor of 0.76, with a maximum PCE of 16.25%, which is the highest PCE for 2D DJ PVSCs free of hot casting. The unsealed device maintains around 80% of its initial efficiency after 35 days of exposure to air (Hr = 45 ± 5%). A potential route toward high‐performance 2D DJ PVSCs is provided. [ABSTRACT FROM AUTHOR]

CoS2 has been studied as a promising anode for lithium ion batteries (LIBs) due to its large capacity and high electrical conductivity. However, CoS2 anodes generally suffer from rapid capacity fading, especially at high rate. Rationally designed morphologies and component tunability offer appropriate approaches to improve its lithium storage performances. Herein, Cu0.33Co0.67S2 ultrathin hexagonal sheets with two‐dimensional (2D) hierarchical structure were firstly prepared through a facile and controllable sulfuration strategy from Cu‐doped cobalt hydroxide sheet precursor. The as‐prepared Cu0.33Co0.67S2 anode delivers a high reversible capacity of 960 mAh g−1 over 200 cycles at a current density of 1 A g−1 and a stable cycling capacity of 550 mAh g−1 even after 2000 cycles at 10 A g−1. The excellent electrochemical performances can mainly be attributed to the special 2D hierarchical structure and the synergistic enhancement effect of copper and cobalt ions, which induces reversible decomposition of partial SEI, high pseudocapacitive contributions and fast faradic reaction kinetics. Binary metal sulfide materials combined with a rational hierarchical structure design could provide a promising method to construct high‐performance anodes for applications in electrochemical energy storage. Sheet storage: Cu0.33Co0.67S2 hexagonal sheets with two‐dimensional (2D) hierarchical structure are prepared through homogeneous precipitation and low temperature sulfuration. The product shows excellent lithium storage properties and long‐term cyclability at high rate, maintaining a stable reversible capacity of 550 mAh g−1 even after 2000 cycles at 10 A g−1. [ABSTRACT FROM AUTHOR]

Metamaterials are artificial structures composed of subwavelength unit cells to control electromagnetic (EM) waves. The spatial coding representation of metamaterial has the ability to describe the material in a digital way. The spatial coding metamaterials are typically constructed by unit cells that have similar shapes with fixed functionality. Here, the concept of frequency coding metamaterial is proposed, which achieves different controls of EM energy radiations with a fixed spatial coding pattern when the frequency changes. In this case, not only different phase responses of the unit cells are considered, but also different phase sensitivities are also required. Due to different frequency sensitivities of unit cells, two units with the same phase response at the initial frequency may have different phase responses at higher frequency. To describe the frequency coding property of unit cell, digitalized frequency sensitivity is proposed, in which the units are encoded with digits “0” and “1” to represent the low and high phase sensitivities, respectively. By this merit, two degrees of freedom, spatial coding and frequency coding, are obtained to control the EM energy radiations by a new class of frequency‐spatial coding metamaterials. The above concepts and physical phenomena are confirmed by numerical simulations and experiments. [ABSTRACT FROM AUTHOR]

Animal models are of importance to investigate basic mechanisms for ischemic heart failure ( HF). The objective of the study was to create a rabbit model through multiple coronary artery ligations to investigate the postoperative structure-function remodeling of the left ventricle ( LV) and coronary arterial trees. Here, we hypothesize that the interplay of the degenerated coronary vasculature and increased ventricle wall stress relevant to cardiac fibrosis in vicinity of myocardial infarction ( MI) precipitates the incidence and progression of ischemic HF. Echocardiographic measurements showed an approximately monotonic drop of fractional shortening and ejection fraction from 40% and 73% down to 28% and 58% as well as persistent enlargement of LV cavity and slight mitral regurgitation at postoperative 12 weeks. Micro- CT and histological measurements showed that coronary vascular rarefaction and cardiac fibrosis relevant to inflammation occurred concurrently in vicinity of MI at postoperative 12 weeks albeit there was compensatory vascular growth at postoperative 6 weeks. These findings validate the proposed rabbit model and prove the hypothesis. The post- MI rabbit model can serve as a reference to test various drugs for treatment of ischemic HF. [ABSTRACT FROM AUTHOR]

Herein we report the organoplatinum-mediated bottom-up synthesis, characterization, and properties of a novel large π-extended carbon nanoring based on a nanographene hexa- peri-hexabenzocoronene (HBC) building unit. This tubular structure can be considered as an example of the longitudinal extension of the cycloparaphenylene scaffold to form a large π-extended carbon nanotube (CNT) segment. The cyclic tetramer of a tetramesityl HBC ([4]CHBC) was synthesized by the reaction of a 2,11-diborylated hexa- peri-hexabenzocoronene with a platinum complex, followed by reductive elimination. The structure of this tubular molecule was further confirmed by physical characterization. Theoretical calculations indicate that the strain energy of this nanoring is as high as 49.18 kcal mol−1. The selective supramolecular host-guest interaction between [4]CHBC and C70 was also investigated. [ABSTRACT FROM AUTHOR]

Herein we report the organoplatinum-mediated bottom-up synthesis, characterization, and properties of a novel large π-extended carbon nanoring based on a nanographene hexa- peri-hexabenzocoronene (HBC) building unit. This tubular structure can be considered as an example of the longitudinal extension of the cycloparaphenylene scaffold to form a large π-extended carbon nanotube (CNT) segment. The cyclic tetramer of a tetramesityl HBC ([4]CHBC) was synthesized by the reaction of a 2,11-diborylated hexa- peri-hexabenzocoronene with a platinum complex, followed by reductive elimination. The structure of this tubular molecule was further confirmed by physical characterization. Theoretical calculations indicate that the strain energy of this nanoring is as high as 49.18 kcal mol−1. The selective supramolecular host-guest interaction between [4]CHBC and C70 was also investigated. [ABSTRACT FROM AUTHOR]

ABSTRACT A series of new functional poly(ethylene- co-vinyl alcohol)- g-polystyrene graft copolymers (EVAL- g-PS) with controlled molecular weight ( Mn = 38,000-94,000 g mol−1) and molecular weight distribution ( Mw/ Mn = 2.31-3.49) were synthesized via a grafting from methodology. The molecular structure and component of EVAL- g-PS graft copolymers were confirmed by the analysis of their 1H NMR spectra and GPC curves. The porous films of such copolymers were fabricated via a static breath-figure (BF) process. The influencing factors on the morphology of such porous films, such as solvent, temperature, polymer concentration, and molecular weight of polymer were investigated. Ordered porous film and better regularity was fabricated through a static BF process using EVAL- g-PS solution in CHCl3. Scanning electron microscopy observation reveals that the EVAL- g-PS graft copolymer is an efficient compatibilizer for the blend system of low-density polyethylene/polystyrene. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 516-524 [ABSTRACT FROM AUTHOR]

Comprehensive Summary: The surface properties and chemical interactions are critical for perovskite solar cells (PVSCs). In this work, we show that the polypropylene glycol (PPG) can simultaneously passivate the NiOx surface and grain boundaries of perovskite films, allowing more efficient charge transfer at the anode interface and reducing the recombination of PVSCs. As a result, the open‐circuit voltage (Voc) of MAPbI3 based inverted PVSCs increases from 1.087 V to 1.127 V, and the short‐circuit current density (Jsc) is increased from 20.87 mA·cm–2 to 22.32 mA·cm–2, thereby realizing the improvement of the device power conversion efficiency (PCE) from 18.34% to 20.12%. Moreover, the steady‐state output of the PVSCs is remarkably improved by incorporating PPG. Further analysis of surface properties suggests that part of the PPG at the interface can permeate into the precursor solution with the help of DMF solvent and remain in the perovskite layer to form a concentration gradient. The ether bond of PPG and the uncoordinated Pb2+ in the perovskite are coordinated to achieve passivation effects and improve device performance. Our work provides a rational strategy for the preparation of high‐performance PVSCs. [ABSTRACT FROM AUTHOR]

2D Dion–Jacobson (2D DJ) perovskites are considered as promising photovoltaic materials due to their structural stability and spacer designability. Here, a spacer cation with an aromatic imidazole ring, 2‐(1H‐imidazol‐2‐yl)ethylammonium (HE), is successfully applied to construct 2D DJ perovskite. It's found that the high polarity of the HE spacer strengthens the interaction between organic and inorganic layers and reduces the exciton binding energy to 67.8 meV, resulting in promoted charge dissociation, compared with the aliphatic 1,4‐butanediammonium (BDA) spacer with a similar length. The HE spacer enlarges the micelle size in precursor solution and suppresses the formation of low‐n value phases. In consequence, the HE‐based perovskite film exhibits better quality than the BDA‐based one, with lower defect density and longer carrier lifetime. The optimized device based on (HE)(MA0.75FA0.25)4Pb5I16 film achieves a champion power conversion efficiency up to 18.40%, much higher than that of the BDA‐based device (15.03%). Besides, the unencapsulated device based HE exhibits improved moisture and thermal stability. [ABSTRACT FROM AUTHOR]

Abstract: Particle trajectories in an incompressible cavity flow are investigated experimentally. The flow is driven by two facing walls moving with same speed in opposite directions. When the flow is steady and three‐dimensional, finite‐size and neutrally‐buoyant particles are rapidly attracted to periodic orbits. Three‐dimensional particle tracking is used to reconstruct single particle trajectories. Experimental results are presented and compared with numerical simulations. (© 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim) [ABSTRACT FROM AUTHOR]

Herein we report the organoplatinum-mediated bottom-up synthesis, characterization, and properties of a novel large π-extended carbon nanoring based on a nanographene hexa- peri-hexabenzocoronene (HBC) building unit. This tubular structure can be considered as an example of the longitudinal extension of the cycloparaphenylene scaffold to form a large π-extended carbon nanotube (CNT) segment. The cyclic tetramer of a tetramesityl HBC ([4]CHBC) was synthesized by the reaction of a 2,11-diborylated hexa- peri-hexabenzocoronene with a platinum complex, followed by reductive elimination. The structure of this tubular molecule was further confirmed by physical characterization. Theoretical calculations indicate that the strain energy of this nanoring is as high as 49.18 kcal mol−1. The selective supramolecular host-guest interaction between [4]CHBC and C70 was also investigated. [ABSTRACT FROM AUTHOR]

Herein we report the organoplatinum-mediated bottom-up synthesis, characterization, and properties of a novel large π-extended carbon nanoring based on a nanographene hexa- peri-hexabenzocoronene (HBC) building unit. This tubular structure can be considered as an example of the longitudinal extension of the cycloparaphenylene scaffold to form a large π-extended carbon nanotube (CNT) segment. The cyclic tetramer of a tetramesityl HBC ([4]CHBC) was synthesized by the reaction of a 2,11-diborylated hexa- peri-hexabenzocoronene with a platinum complex, followed by reductive elimination. The structure of this tubular molecule was further confirmed by physical characterization. Theoretical calculations indicate that the strain energy of this nanoring is as high as 49.18 kcal mol−1. The selective supramolecular host-guest interaction between [4]CHBC and C70 was also investigated. [ABSTRACT FROM AUTHOR]