Jin, Xipeng, Cai, Xuhui, Huang, Qianqian, Wang, Xuesong, Song, Yu, Kang, Ling, and Zhang, Hongsheng
This study estimates long‐term PM2.5 exchange flux between the atmospheric boundary layer (ABL) and free troposphere (FT) in the North China Plain. The effect of PM2.5 long‐range transport (LRT) on air quality in downwind regions is also assessed. The PM2.5 exchange fluxes are calculated based on a mass budget method with data from WRF‐Chem simulations, during wintertime months (November, December, and January) in 2014, 2016, and 2017 (represent moderate, heavier, and less polluted years). The overall PM2.5 exchange exhibits clear topographical correlation and diurnal variation. The plain area is characterized by a considerable upward flux of −0.13 μg m−2 s−1 (in a 3‐year average), acting as an effective source for LRT. ABL height variation contributes significantly to the diurnal cycle of PM2.5 vertical exchange. Over the mountainside and ridge areas, the PM2.5 exchange flux is downward and its diurnal variation is weak, due to the dominant cross‐mountain descent flows. Four LRT patterns in the FT are identified, that is, eastward, southward, recirculation, and local stagnation. They can affect air quality in Northeast China, Yangtze River Delta, South Korea, and Japan. Indicating with averages and standard deviations, the PM2.5 concentration increases (relative contribution) for these four target regions over the 3‐year winter period are respectively 5.5 ± 4.8 μg m−3 (12.6 ± 10.9%), 4.6 ± 4.5 μg m−3 (8.4 ± 6.4%), 4.4 ± 3.9 μg m−3 (5.2 ± 4.4%), and 1.6 ± 0.9 μg m−3 (2.6 ± 1.6%). While the maximum impacts can be 36.7 μg m−3 (59%), 31.1 μg m−3 (41%), 25.7 μg m−3 (30%), and 7.2 μg m−3 (13%), respectively. Plain Language Summary: The PM2.5 exchange between the boundary layer and the free troposphere is a key process directly affecting air pollution transport and influence scale. This study estimates the PM2.5 vertical exchange flux over the North China Plain (NCP) during wintertime in 2014, 2016, and 2017, and quantifies the impact of the subsequent long‐range transport on air quality in downstream areas. The long‐term average PM2.5 exchange flux is closely related to the topographic distribution and has diurnal variation characteristics. The plain area is characterized by considerable PM2.5 vertical outflow, allowing the pollutants to be transported long distances in the free troposphere. There are four transport patterns with the main affected areas being the Yangtze River Delta, Northeast China, South Korea, and Japan, as well as the NCP itself. PM2.5 concentration increases due to the long‐range transport for these areas are quantified. These results provide a more solid understanding of atmospheric transport and large‐scale air pollution. Key Points: PM2.5 vertical exchange flux over the North China Plain is characterized by topographical distribution and diurnal variationThe plain area provides an effective PM2.5 source for long‐range transport in the free troposphere with a seasonal average upward flux of −0.13 μg m−2 s−1Four long‐range transport patterns are identified and PM2.5 concentration contributions to downstream regions are quantified [ABSTRACT FROM AUTHOR]