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The rational design of metal-nitrogen-doped carbons (M-N-C) from available and cost-effective sources featuring high electrocatalytic performance and stability is attractive for the development of viable low-temperature fuel cells. Herein, mimosa tannin, an abundant polyphenol easily extracted from the Mimosa plant, is used as a natural carbon source to produce a tannin-Fe(III) coordination complex. This process is assisted by Pluronic F127, which acts as both a surfactant and a promoter of Fe-N x active sites. After carbonization in the presence of urea as a nitrogen precursor, this organic tannin-Fe(III) framework produces Fe 3 C nanoparticles encapsulated on a Fe-N-C single-atom catalyst with hierarchical porosity. The optimal catalyst, with a Pluronic F127/mimosa tannin mass ratio of 0.5, exhibits high ORR performance in both alkaline and acidic electrolytes, with half-wave potentials of 0.87 and 0.74 V versus RHE, respectively. In addition, good performance is achieved in practical hydrogen polymer-electrolyte membrane fuel cells using OH - - or H + -conducting membranes with peak power densities of 242 and 200 mW cm -2 at cell voltages of 0.43 and 0.3 V, respectively. The synthetic approach can be explored to design new renewable M-N-C electrodes for electrochemical energy conversion or storage devices due to tannin's exceptional ability to coordinate metals., (© 2024 Wiley‐VCH GmbH.)

Lithium battery materials can be advantageously used for the selective sequestration of lithium ions from natural resources, which contain other cations in high excess. However, for practical applications, this new approach for lithium production requires the battery host materials to be stable over many cycles while retaining the high lithium selectivity. Here, a nearly symmetrical cell design was employed to show that LiFePO 4 shows good capacity retention with cycling in artificial lithium brines representative of brines from Chile, Bolivia and Argentina. A quantitative correlation was identified between brine viscosity and capacity degradation, and for the first time it was demonstrated that the dilution of viscous brines with water significantly enhanced capacity retention and rate capability. The electrochemical and X-ray diffraction characterisation of the cycled electrodes also showed that the high lithium selectivity was preserved with cycling. Raman spectra of the cycled electrodes showed no signs of degradation of the carbon coating of LiFePO 4 , while scanning electron microscopy images showed signs of particle cracking, thus pointing towards interfacial reactions as the cause of capacity degradation., (© 2021 The Authors. ChemSusChem published by Wiley-VCH GmbH.)

A facile and straightforward methodology for the preparation of monometallic (copper and palladium) and bimetallic nanocatalysts (NiCu and PdCu) stabilized by a N-heterocyclic carbene ligand is reported. Both colloidal and supported nanoparticles (NPs) on carbon nanotubes (CNTs) were prepared in a one-pot synthesis with outstanding control on their size, morphology and composition. These catalysts were evaluated in the selective hydrogenation of alkynes and alkynols. PdCu/CNTs revealed an efficient catalytic system providing high selectivity in the hydrogenation of terminal and internal alkynes. Moreover, this catalyst was tested in the semi-hydrogenation of acetylene in industrially relevant acetylene/ethylene-rich model gas feeds and showed excellent stability even after 40 h of reaction., (© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)