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The generation of hot carriers by Landau damping or chemical interface damping of plasmons is of particular interest to the fundamental aspects of extreme light-matter interactions. Hot charge carriers can be transferred to an attached acceptor for photochemical or photovoltaic energy conversion. However, these lose their excess energy and relax to thermal equilibrium within picoseconds and it is difficult to extract useful work thereof with thermodynamic efficiencies that are of interest for practical devices. Without a detailed understanding of the underlying plasmon decay processes and transfer mechanisms, proper material matching and design considerations for novel plasmonic devices are extremely challenging. Here, a multifunctional AlSiAl heterostructure device with tunable Schottky barriers is presented to control plasmon-induced hot carrier injection at an abrupt metal-semiconductor interface. Light absorption, surface plasmon generation, and separation of hot carriers arising from the non-radiative decay of surface plasmons are realized in a monolithic Schottky barrier field effect transistor. Aside from barrier modulation, a virtual p-n junction can be emulated in the semiconductor channel with the distinct merit that carrier concentration and polarity are tunable by electrostatic gating. The investigations are carried out with a view to possible use for CMOS-compatible plasmonic photovoltaics, with versatile implementations for autonomous nanosystems., (© 2023 The Authors. Small published by Wiley-VCH GmbH.)

Perovskite photodetectors (PDs) with tunable detection wavelength have attracted extensive attention due to the potential application in the field of imaging, machine vision, and artificial intelligence. Most of the perovskite PDs focus on I- or Br-based materials due to their easy preparation techniques. However, their main photodetection capacity is situated in the visible region because of their narrower bandgap. Cl-based wide bandgap perovskites, such as CsPbCl 3 , are scarcely reported because of the bad film quality of the spin-coated Cl-based perovskite, due to the poor solubility of the precursor. Therefore, ultraviolet detection using high-quality full inorganic perovskite films, especially with high thermal stability of materials and devices, is still a big challenge. In this work, high-quality single crystal CsPbCl 3 microplatelets (MPs) synthesized by a simple space-confined growth method at low temperature for near-ultraviolet (NUV) PDs are reported. The single CsPbCl 3 MP PDs demonstrate a decent response to NUV light with a high on/off ratio of 5.6 × 10 3 and a responsivity of 0.45 A W -1 at 5 V. In addition, the dark current is as low as pA level, leading to detectivity up to 10 11 Jones. Moreover, PDs possess good stability and repeatability., (© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Broadband transparent electrodes based on a two-dimensional grid of topological insulator Bi2Se3 are synthesized by a facile selective-area van der Waals epitaxy method. These two-dimensional grid electrodes exhibit high uniformity over large area, outstanding mechanical durability, and excellent chemical resistance to environmental perturbations. Remarkably, the topological grid electrode has high transmittance of more than 85% from the visible to the near-infrared region., (© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Covalent grafting of methyl groups onto the basal plane of graphene is achieved through a photochemical reaction between graphene and di-tert-butyl peroxide. The methylation of graphene is found to be reversible. The edge of single-layer graphene shows the largest methylation reactivity, which provides a route to tailor the edge state of graphene., (Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)