Search

Organic–inorganic hybrid perovskites (OHPs) with a rich reservoir of distinct physical attributes have been considered as promising resistive switching materials for next‐generation electronic devices, including resistive random‐access memory (RRAM) devices, artificial synapses, and logic operation. In this review, we first briefly introduce the structural and photoelectronic properties of OHPs materials, followed by elaborating the typical lateral/vertical device architectures and commonly‐used device fabrication technologies. Secondly, recent progress of OHPs in three categories of RRAM, artificial synapses, and logic operation, including various materials design, outstanding electrical behaviors, and multifunctional applications, are well discussed. Besides, the operational mechanisms and performance improvement strategies are summarized in a recapitulative way. Finally, current challenges and future development prospects of OHPs‐based devices are demonstrated to provide a better guideline for the next‐generation technical revolution. This review offers an encouraging recognition that OHPs hold immense expectation to keep up with the upcoming big‐data and artificial intelligence era.

Despite great progress in perovskite photovoltaics, it should be noted that the intrinsic disorder dipolar cations in organic-inorganic hybrid perovskites exert negative effects on the energy band structure as well as the carrier separation and transfer dynamics. However, oriented polarization achieved by applying an external electric field may cause irreversible damage to perovskites. Herein, a unique and efficient strategy is developed to modulate the intrinsic dipole arrangement in perovskite films for high-performance and stable perovskite solar cells (PSCs). The spontaneous reorientation of dipolar cation methylamine is triggered by a polar molecule, constructing a vertical polarization during crystallization regulation. The oriented dipole determines a gradient energy-level arrangement in PSCs and more favorable energetics at interfaces, effectively enhancing the built-in electric field and suppressing the nonradiative recombination. Besides, the dipole reorientation induces a local dielectric environment to remarkably reduce exciton binding energy, leading to an ultralong carrier diffusion length of up to 1708 nm. Accordingly, the n-i-p PSCs achieve a significant increase in power conversion efficiency, reaching 24.63% with negligible hysteresis and exhibiting outstanding stabilities. This strategy also provides a facile route to eliminate the mismatched energetics and enhance carrier dynamics for other novel photovoltaic devices., (© 2023 Wiley-VCH GmbH.)

A simple yet general swelling-deswelling microencapsulation strategy has been developed to achieve well dispersed and intimately passivated crystalline organic-inorganic perovskites nanoparticles within polymer matrixes and results in a series of highly luminescent CH 3 NH 3 PbBr 3 (MAPbBr 3 )-polymer composite films with unprecedented water and thermal stabilities and superior color purity., (© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)