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Sm:YAlO 3 (Sm:YAP) crystal with size of Φ28 × 80 mm3 was grown by Czochralski (Cz) method. Polarized absorption spectra and fluorescence spectra of Sm:YAP crystal were discussed for the first time. The peak emission cross-sections were calculated to be 0.80 × 10−21 cm2 (604 nm for a-polarization), 1.82 × 10−21 cm2 (604 nm for b-polarization) and 1.63 × 10−21 cm2 (610 nm for c-polarization), respectively. The Judd-Ofelt (JO) intensity parameters were calculated to be Ω 2 = 2.59 × 10−20 cm2, Ω 4 = 1.78 × 10−20 cm2 and Ω 6 = 2.98 × 10−20 cm2, respectively. The decay lifetime of 4G 5/2 energy level was measured to be 2.51 ms. All above results indicate the Sm:YAP crystal may be a potential candidate of reddish-orange laser pumped directly by the GaN/InGaN laser diode. • Sm:YAlO 3 crystal was grown by Cz method. • Polarized optical spectra of Sm:YAlO 3 crystal were investigated. • The transitions of 4G 5/2 → 6H 7/2 have the highest branching ratio value, which is suitable for reddish-orange laser. [ABSTRACT FROM AUTHOR]

Tb 3+ -doped YAlO 3 (YAP) single crystal was grown by Czochralski (Cz) method. Based on the polarized absorption spectra, the spectroscopic parameters were calculated to be Ω 2 = 3.49 × 10 −20 cm 2 , Ω 4 = 5.87 × 10 −20 cm 2 and Ω 6 = 2.55 × 10 −20 cm 2 , and then the spontaneous transition rate, fluorescent branching ratio and radiative lifetime of 5 D 4 multiplet were obtained. The yellow emission cross sections of 5 D 4 → 7 F 4 transition were calculated to be 1.72 × 10 −22 cm 2 , 2.73 × 10 −22 cm 2 and 2.65 × 10 −22 cm 2 for a, b and c polarization, respectively. The fluorescence lifetime of the 5 D 4 multiplet was fitted to be 1.72 ms. All the data indicate that Tb:YAP crystal is a promising candidate for yellow laser operation. [ABSTRACT FROM AUTHOR]

Pr 3+ -doped YAlO 3 (YAP) single crystal was successfully grown by the Czochralski (Cz) method. Polarized absorption and polarized fluorescence spectra were measured at the room temperature. The spectroscopic parameters based on the polarized absorption spectra were calculated by Judd-Ofelt (J-O) theory for the first time. The fluorescence lifetime of 3 P 0 energy level was fitted to be 19.16 μs with the quantum efficiency of 95.8%. Through the analyzing of the spectroscopic properties, Pr:YAP crystal was demonstrated to be a promising candidate for solid state laser operation. [ABSTRACT FROM AUTHOR]

Dy 3+ -doped YAlO 3 single crystal has been successfully grown by Czochralski technique. The spectroscopic parameters were determined by Judd-Ofelt theory based on the measured polarized absorption spectra. Dy:YAP crystal exhibits a yellow emission centered at 574 nm which can be used for pumping of the forbidden 1 S 0 - 3 P 0 ytterbium clock transition. The decay lifetime of the 4 F 9/2 level was measured to be 185 μs. [ABSTRACT FROM AUTHOR]

LaMgAl 11 O 19 (LMA) crystal with nominal Sm3+ concentrations of 8 at.% was grown by the Czochralski method. Polarized absorption spectra, polarized emission spectra and fluorescence decay curve of Sm:LMA crystal were recorded at room temperature. The absorption cross-sections at 404 nm were calculated to be 2.33 × 10−20 cm2 and 0.86 × 10−20 cm2 for σ and π polarization, respectively. The spontaneous transition rates, branching ratios and the radiative lifetime of the 4G 5/2 multiplet, were calculated. The Judd-Ofelt theory has been applied to evaluate the Ω t (t = 2, 4, 6) intensity parameters. The highest stimulated emission cross-sections for the 4G 5/2 → 6H 7/2 transition around 594 nm were calculated to be 1.67 × 10−21 cm2 for σ polarization and 1.15 × 10−21 cm2 for π polarization, with full width at half maximum (FWHM) of 7.68 nm and 7.27 nm, respectively. The fluorescence lifetime of the 4G 5/2 manifold was 1.84 ms. All the results show that Sm:LMA crystal would be a promising orange-red solid state laser material. • The most intensive absorption line of Sm3+ ion, suitable for 405 nm InGaN laser diode. • The rigidity of Sm:LMA crystal is higher than some host crystals. • The value Ω 2 of Sm:LMA crystal is comparable to Sm:LiYF 4. • The large parameter σ em τ of Sm3+ in LMA is beneficial for the solid state laser. [ABSTRACT FROM AUTHOR]