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The isomorphic collapse of crystalline lattices under pressure is a rare and intriguing phenomenon–the most famous examples being samarium sulphide and cerium metal. Both lattices are cubic under ambient conditions and collapse isomorphically under pressure, remaining cubic with ∼15% volume reduction. In SmS the transition results from a change of the 4f chemical valence. The collapse in Ce is connected with the altering contributions of the 4f electrons to the chemical bonding, the details of which are currently much debated. In contrast, YCo5 is a hexagonal metallic compound with a stable valence and no 4f electrons. Here, we present a combination of high-pressure X-ray diffraction measurements and density functional electronic-structure calculations to demonstrate an entirely different type of isomorphic transition under hydrostatic pressure of 19 GPa. Our results suggest that the lattice collapse is driven by magnetic interactions and can be characterized as a first-order Lifshitz transition, where the Fermi surface changes topologically. These studies support the existence of a bistable bonding state due to the magneto-elastic interaction. [ABSTRACT FROM AUTHOR]

The isomorphic collapse of crystalline lattices under pressure is a rare and intriguing phenomenon–the most famous examples being samarium sulphide and cerium metal. Both lattices are cubic under ambient conditions and collapse isomorphically under pressure, remaining cubic with ∼15% volume reduction. In SmS the transition results from a change of the 4f chemical valence. The collapse in Ce is connected with the altering contributions of the 4f electrons to the chemical bonding, the details of which are currently much debated. In contrast, YCo5 is a hexagonal metallic compound with a stable valence and no 4f electrons. Here, we present a combination of high-pressure X-ray diffraction measurements and density functional electronic-structure calculations to demonstrate an entirely different type of isomorphic transition under hydrostatic pressure of 19 GPa. Our results suggest that the lattice collapse is driven by magnetic interactions and can be characterized as a first-order Lifshitz transition, where the Fermi surface changes topologically. These studies support the existence of a bistable bonding state due to the magneto-elastic interaction. [ABSTRACT FROM AUTHOR]