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[Objective] The dispute in the paleogeographic pattern of the carbonate platform and distribution of reservoir facies during the deposition of the Dengying Formation in the middle-upper area, hinders the expansion of the exploration domain from the Mianyang-Changning intracratonic sag to other areas. [Methods] Detailed lithofacies and facies analysis was conducted on more than 30 sections (wells), [Results] further confirming that the mound-shoal is marked by massive peloidal/ooidal dolograinstone and columnar, domal dolostromatolite, which were deposited around the platform (or inner ramp) margin of the Middle-Upper Yangtze Platform gradually shifting outward into tempestite of the middle-outer ramp or slump dolobreccia, argillaceous dolomite and chert of slope-basin facies. Owing to the mound-shoal barrier, its back was dominated by tidal flat and lagoon. Of these, the tidal flat facies were marked by microbial dololaminite, domal dolostromatolite, dolothrombolite with minor peloidal dolograinstone, and dolomudstone, which are commonly arranged into meter-centimeter scale cycles. The lagoon facies were composed mainly of dolomudstone and peloidal dolowackestone. In general, the mound-shoal facies is present in the lower Dengying Formation along the platform to slope transition (or inner ramp to middle ramp transition) . In the Upper Yangtze Platform, it occurs in the Deng 1 (e.g., wells Pengtan 1, Ziyang 1, and sections Qingping, Beidoushan) or Deng 2 members at the Baijiaba, Yulin, and Meiziwan sections, or in both the Deng 1 and Deng 2 members at the Songlin-Yankong areas. On Middle Yangtze Platform, it occurs in the Hamajing (e. g., sections Sancha, Bailuya, and Tianping) or Baimatuo members of the upper Dengying Formation at the Miaohe section. Specifically, the mound- shoal facies shows repeated transgressions and regressions and occurs in different stratigraphic position of the Dengying Formation at many sections (Baiguoping, Xiaofenghe, Dengyingxia, Wushan, Xuejiadian, and Dengjiaya) . In contrast, the tidal flat and lagoon facies are widely present on the whole Middle-Upper Yangtze Platform, commonly associated with the grape-like dolomite at the lower-middle part of the Deng 2 member (or correlated stratigraphy) . The spatiotemporal distributions of these facies show a progradational trend of the Dengying Formation on the Middle- Upper Yangtze Platform, which consists of 2.5 depositional sequences with three progradations (shallowing) and two retrogradations (deepening) . The regressive system tract of Sequence 1 is formed by the lower Dengying Formation (the Deng 1 to middle Deng 2 or Hamajing members), characterized by the upward evolution of lagoon or moundshoal facies into tidal flat facies. On the Upper Yangtze Platform, Sequence 2 occurs in the upper Deng 2 member, marked by the regression of mound-shoal facies and the presence of more lagoonal dolomudstone, followed by the reoccurrence of tidal flat facies. On the Middle Yangtze Platform, Sequence 2 is present in the Shibantan member, represented by the deepening into middle ramp limestone or lagoonal dolomudstone and then shallowing into moundshoal or tidal flat facies. Sequence 3 on the Middle Yangtze Platform shows a similar deepening (transgression) and shallowing (regression) cycle. On the Upper Yangtze Platform, the transgressive systems tract of Sequence 3 is located in the siliciclastic rock of the Deng 3 member and the following transgressive systems tract is marked by the transition of lagoonal dolomudstone to tidal flat dolomicrobialite. [Conclusions] Owing to the denudation of the Dengying Formation at the platform margin-slope area and Upper Yangtze Platform beyond the current plate boundary, the platform marginal mound-shoal facies are locally present in the Deng 4 member. In this case, certain areas (e.g., the Songlin-Yankong area and periphery of the Middle Yangtze Platform) with platform marginal mound-shoal facies in the lower-middle Dengying Formation (Deng 1 to 2 or Hamajing to Shibantan members) are important exploration targets. Moreover, the lower Deng 2 and upper Deng 4 members (or coeval strata) formed during progradations composed of microbial dolomite throughout the Middle-Upper Yangtze Platform (or inner ramp) interior are also important exploration targets. Because the microbial dolomite was widely developed throughout the Middle-Upper Yangtze Platform interior, decoding the formation mechanism and distribution pattern of high-quality reservoir is the key to finding new hydrocarbon provinces. [ABSTRACT FROM AUTHOR]

Alkaline lakes (pH > 9) are among the few modern sedimentary environments that are hydrochemically favourable for low‐temperature dolomite formation. While Mg‐clays and Mg‐evaporites also form more easily in alkaline environments, few studies have focused on how the kinetically inhibited dolomite wins the competition for Mg2+. Here, a basin‐wide survey of the distribution, paragenesis and stable C, O and Mg isotopes of main Mg‐rich minerals in the Late Palaeozoic saline alkaline lake deposit of the north‐west Junggar Basin, north‐west China, is conducted to study the influence of the formation and diagenesis of eitelite, northupite and Mg‐clays on dolomite formation. Large, isolated dolomite crystals (20 to 70 μm in diameter), show positive δ13C values (ranging from +1 to +7‰) and a restricted distribution in the mudstones of the lake‐transitional zone. These crystals have been interpreted as organogenic dolomite driven by methanogenesis via fermentation of organic substrates. The δ18O values of dolomitic mudstones (from −7.4 to +3.4‰), calcitic mudstones (from −15.1 to −3.3‰) and bedded Na‐carbonate evaporites (from +0.08 to +3.7‰), together with their Mg isotopic compositions, suggest that dolomite was not enriched in the most concentrated environments or during stages with most Mg sources, but in the organic‐rich deposits containing few other authigenic Mg‐rich minerals. Dolomite is at a competitive disadvantage for Mg2+ ions compared to Mg‐evaporite and Mg‐clay minerals due to its slow crystallization rates and the deficiency of micritic calcium carbonate precursors. However, it can nucleate and progressively grow into large crystals (>20 μm) if bacterial methanogenesis could effectively lower porewater pH (<8.5) and induce the dissolution of generated eitelite, northupite or Mg‐clays. These findings suggest that high salinity and/or high alkalinity are not always favourable conditions for dolomite formation and highlight the active role of pH fluctuations in inducing low‐temperature dolomite formation. [ABSTRACT FROM AUTHOR]

Palustrine‐lacustrine carbonates of the well‐dated Xichagou section (ca. 43 to ca. 13 Ma) next to the active Altyn Tagh Fault (ATF) are investigated in terms of abundance, lithofacies, strontium, carbon and oxygen isotopes, to differentiate tectonic and climatic controls on the evolution of intermontane lakes in the Tibetan Plateau. Volumetrically dominant siliciclastic strata document five depositional stages: mid‐Eocene alluvial fan (onshore), late Eocene fan delta (nearshore), Oligocene semi‐deep lake (offshore), early Miocene braided fluvial delta (nearshore) and mid‐Miocene fluvial plain (onshore). Carbonates are most abundant in the middle three lacustrine stages and contain various lithofacies, including calcretes, microbialites, grainstones and marlstones. Oxygen isotopes show two positive excursions (−1.17‰ and −2.59‰) at the first nearshore and late offshore stages, indicating two relatively saline stages linked to the Eocene and late Oligocene global warming climates. Carbon isotopes show a positive excursion (from −4.0‰ to +2.9‰) at the middle semi‐deep lake stage and meanwhile strontium isotopes of carbonates show a large negative excursion (from 0.7120‰ to 0.7113‰), both in response to the early Oligocene global humid and cooling climate and resultant lake expansion at the Qaidam Basin. Except for this lake expansion event, the first‐order lake transgressing, shallowing and regressing evolution at the Xichagou section were not consistent with Cenozoic global climatic change trends. Instead, the two‐stage strike‐slip faulting of the ATF probably induced the northeastward and eastward migration of basin depocenter and resulted in the lake transgression‐regression at the Xichagou section. The widespread presence and relatively minor variation in oxygen isotopes (from −7.5‰ to −7.0‰) of early Miocene microbialites in the northern Tibetan Plateau suggest a warm climate and a low relief before ca. 15 Ma. [ABSTRACT FROM AUTHOR]

Travertines formed of crystalline crust have been widely reported, but there has not been focus on their geochemical characteristics. We therefore carefully conducted a series of geochemical investigations and U-Th dating on a travertine mound mainly composed of crystalline crust from Sobcha (southwest China) to determine their geochemical features and geological implications. The Sobcha travertines dominantly consist of granular crystals and fan crystals and show δ13C from 3.4‰ to 4.9‰ V-PDB, δ18O from −26.7‰ to −23.7‰ V-PDB, and 87Sr/86Sr from 0.712458 to 0.712951. When normalized to PASS, the Sobcha travertines exhibit MREE enrichment relative to HREE and LREE, HREE enrichment relative to LREE, and positive Eu anomalies. The δ13C signatures and mother CO2 evaluation of the Sobcha travertines show that the Sobcha travertines were thermogene travertines largely receiving mother CO2 from (upper) mantle (i.e., magmatic CO2) or a mixture of soil-derived CO2 and CO2 related to carbonate decarbonation. The 87Sr/86Sr of the Sobcha travertines is out of the 87Sr/86Sr ranges of local deposits exposed at Sobcha and surrounding areas but is well matched with the mean 87Sr/86Sr of Nadi Kangri volcanic rocks which cropped out to the northeast of the studied travertines (over 20 km away). This might indicate the important role of the Nadi Kangri volcanic rocks in suppling Sr to the studied travertines, but more studies are required. The LREE depletion compared to MREE and HREE in the Sobcha travertines was interpreted to be caused by the difference in geochemical mobility between LREEs and HREEs during water–rock interaction at depth, while the MREE enrichment compared to HREE was considered to be most likely inherited from reservoir/aquifer rocks. The positive Eu anomalies of the Sobcha travertines may result from very high reservoir temperatures and/or preferential dissolution of Eu-rich minerals/rocks (especially plagioclase). The Sobcha travertine mounds displays no or very slight vertical variations in δ13C, 87Sr/86Sr, and REE patterns, indicating the compositional stability of mother CO2 and paleo-fluids. However, a significant vertical increase in δ18O was observed and was explained as the result of gradual water temperature decrease related to climate cooling, self-closure of the vents, or mound vertical growth. The findings in this study might help us better understand the deposition of crystalline crust in Ca2+-deficient hot spring systems. [ABSTRACT FROM AUTHOR]

Banded travertines are important parts of fissure ridge systems, but studies on geochemical characterization of banded travertines are limited. This study investigated the lithofacies and stable carbon and oxygen isotopic features of banded travertines from Xiagei (southwestern China) to examine their formation mechanisms. Petrographic analyses of the banded travertines revealed two lithotypes: thick-laminated palisade crystalline crust and thin-laminated composite crystalline crust. δ13C and δ18O of the Xiagei banded travertines range from 2.82‰ to 4.50‰ V-PDB, and from −25.86‰ to −20.90‰ V-PDB. Parent CO2 evaluation shows that the Xiagei banded travertines mainly received CO2 from the decarbonation of marine carbonates, but the contributions of magmatic CO2 and the dissolution of marine carbonates are also unneglectable. Significantly, the magmatic-derived CO2 might indicate that the delamination of the lithosphere along with the asthenosphere upwelling could be taking place in the eastern Tibetan plateau. Paleotemperature calculation shows that the Xiagei travertines were precipitated from moderate- to high-temperature hot springs (44.3 to 86.8 °C). Interestingly, the thick-laminated palisade crystalline crust and thin-laminated composite crystalline crust display calculated paleotemperature between 66.6 and 86.8 °C and between 56.6 and 77.7 °C, respectively, reflecting the great role of water temperature in controlling the lithofacies of banded travertines. A comparison between the banded travertines at Xiagei and other areas also shows temperature is a non-negligible factor controlling banded travertine precipitation. However, this does not mean that water temperature is the decisive controlling factor and more studies on banded travertines are still indispensable to disclose the potential factors controlling the factors/processes affecting banded travertine lithofacies. This study provides a good example for understanding the relationship between lithofacies and stable isotopic geochemical characteristics of travertine deposits. [ABSTRACT FROM AUTHOR]

The identification markers of paleokarst have been described in detail and include a combination of surface geology, drilling data and the isotopic characteristics of carbon, oxygen and strontium. The relationships between the vertical zoning, plane distribution and karstification degree of paleokarst and the reservoir development were further analyzed. The study shows that karstic breccias are the most direct sign of paleokarst features. Karsts of different genetic types and the intensity of dissolution have different stable isotopic characteristics from the surrounding cements, and their formation and evolution are significantly influenced by fluid sources, fluid nature and isotopic fractionation. The identification markers of small scale pinholes are quite different from that of large scale holes. The development and evolution of palaeokarsts are mainly controlled by structure, palaeoclimate and lithology. The best lithology for the development of reservoirs is dolomite in the C2hl2 formation. The best zones for the development of the reservoir is located in the upper and lower dissolution intervals of the C2hl2 formation and the best position for the development of reservoir is located in the karst highlands, remnant hills and sloping fields in the karst slope. Key words: eastern Sichuan, Huanglong Formation, palaeokarst reservoir, geochemistry, karst topography, karst cycle

The Middle-Upper Cambrian Xixiangchi Formation in the Sichuan Basin is regarded as an important reservoir with great potential for hydrocarbon exploration. It is previously indicated that the Xixiangchi carbonates have experienced extensive dolomitization, however, the origin of dolomitizing fluids and the dolomitization mechanism still remain uncertain. In this study, a set of petrographic and geochemical examinations, including rare earth elements (REE) and isotopic (C, O, and Sr) compositions were used to trace the origins of dolomitizing fluids and associated diagenetic processes. The petrographic examination revealed three types of matrix dolomites (D1, D2, D3) and one cement saddle dolomite (SD). These phases have crystal size ranges of less than 30 μm (very fine to fine crystals, D1), 30–100 μm (fine to medium crystals, D2), 100–300 μm (medium to coarsely crystalline dolomite, D3), and 0.3–4 mm (fracture filling cements, SD), respectively. D1 is characterized by non to very weak luminescence, weakly negative Ce anomalies (Ce/Ce* = 0.84 ± 0.02), strongly negative Eu anomalies (Eu/Eu* = 0.65 ± 0.03), and high 87Sr/86Sr ratios (0.71062 ± 0.00122). In combination with δ13C (−1.5‰ ± 0.2‰) and δ18O (−9.7‰ ± 0.5‰) compositions, D1 is interpreted to be formed by penecontemporaneous dolomitization in the near-surface environment with seawater as the dolomitizing fluid. In contrast, D2 is characterized by intercrystalline pores, dirty crystal surfaces, similar δ13C (−1.4‰ ± 0.4‰) compositions but higher δ18O (−8.9‰ ± 0.7‰) compositions, and lower 87Sr/86Sr ratios (0.70992 ± 0.00035), similar Ce anomalies (Ce/Ce* = 0.87 ± 0.04) and higher Eu anomalies (Eu/Eu* = 0.85 ± 0.04). The coarser D2 is regarded to be formed by the post-penecontemporaneous seepage-reflux dolomitization or by recrystallization of D1 dolomite in a near-surface or shallow burial environment. D3 is distinguished by a cloudy core with clear rims, showing slightly higher Eu anomalies (Eu/Eu* = 0.88 ± 0.02) and similar Ce anomalies (Ce/Ce* = 0.88 ± 0.02) than those of D1 and D2. Combined with the δ18O compositions (−10.4‰ ± 0.4‰) and 87Sr/86Sr ratios (0.70989 ± 0.00048), D3 is thought to be formed by the overgrowth or recrystallization of D1 and D2 dolomites in a shallow to moderate burial environment. The fractures filling SD dolomite consists of nonplanar and much coarser crystals with undulatory extinctions and brighter red luminescence. The lower δ18O (−11.1‰ ± 0.3‰) compositions, lower negative Eu anomalies (Eu/Eu* = 0.70 ± 0.01) of SD than the matrix dolomites, and similar Ce anomalies (Ce/Ce* = 0.83 ± 0.01) are indicative of hydrothermal dolomitization, with possible fluids associated with the magma during the period of Emei taphrogenic movement. In addition, the 87Sr/86Sr ratios (0.70941 ± 0.00003) of SD suggest probable origin from the coeval seawater partially. Therefore, SD dolomite is interpreted to be formed by hydrothermal dolomitization with mixed dolomitizing fluid of seawater and hydrothermal fluids. In summary, all the matrix dolomites have almost the same ΣREE concentrations and exhibit similar near-flat REE partition patterns with weak LREE enrichments, weakly negative Ce anomalies, and negative Eu anomalies. Such characteristics of REE compositions are indicative of similar evolved dolomitizing fluid, such as seawater or seawater- derived fluids. By contrast, SD dolomites have a different REE partition pattern with left-leaning characteristics, LREE depletions, and negative Eu anomalies, thus suggesting a different dolomitizing fluid source from the matrix dolomites. In addition, the development of intercrystalline pores associated with D2 dolomite makes it more likely to be a potential reservoir, indicating that the dolomitizing history of carbonate has a strong influence on the quality of potential dolomite reservoirs. [ABSTRACT FROM AUTHOR]

Travertine mounds are common spring‐constructed landforms with highly variable geometries, but factors controlling their development have not yet been fully understood. To investigate processes linked with their lateral and vertical growth, this study investigated travertine mounds at Heinitang (China) and compared them with typical mounds around the world. Calcium concentration variation modelling and height evaluation of travertine mounds were also performed. The lateral extent of travertine mounds was found to be mainly controlled by Ca2+ and HCO3‐ concentrations and water discharge: relatively small metre‐scale mounds, like those from Heinitang, are largely the products of Ca2+‐deficiency (<150 mg L−1, commonly <100 mg L−1) or HCO3‐‐deficiency (<500 mg L−1) springs with low discharges (<0.1 L s−1), whereas springs with higher Ca2+ and HCO3‐ concentrations and discharges give rise to the formation of wider mounds. Additional factors affecting mound lateral development include infiltration, evaporation, micro‐organisms, water cooling, CO2 degassing and flow paths. Height of travertine mounds cannot be simply considered to represent the piezometric surface, because the vertical growth of travertine mounds is also influenced by the water table change triggered by tectonic pulses and climate fluctuations, and the closing of conduits induced by self‐sealing. The extinction of travertine mounds at Heinitang is, for example, probably caused by the water table lowering triggered by earthquakes or climate drying after 4 kyr bp. These findings offer new inputs for the better understanding of factors controlling travertine mound development and might assist in the reconstruction of fluid properties, hydrodynamics, tectonics and climate fluctuations in fossil geothermal systems with travertine mounds. [ABSTRACT FROM AUTHOR]

Magnesium (Mg) is a major rock-forming element and biological nutrient element, and is thus an important link between continents, oceans and the Earth' s interior. Marine carbonates are a major reservoir of Mg and an important component of the global Mg cycle. Using Mg isotopes to trace the deposition-diagenesis process of marine carbonate formation is the prerequisite for reconstructing the deep-time seawater Mg isotopic composition (δ26MgSW) and quantifying the Earth' s historical marine Mg cycle. Studies using this approach have made considerable progress in the past two decades; for example: (1) investigation of Mg isotope fractionation during the formation of different carbonate minerals has been enhanced; (2) numerical models of Mg isotopic behavior have been established, providing constraints on the dolomitization process; and (3) the use of Mg isotopes to trace the early diagenetic fluid system has been explored. These have provided a theoretical base for using marine carbonate data to reconstruct δ26MgSW. The deposition-diagenesis process and its effects on Mg isotopic composition should be considered when selecting information from marine carbonate archives to reconstruct the marine Mg cycle. Critical evaluation combined with geochemi-cal models are necessary when choosing an archive for reconstructing deep-time <526MgSW. [ABSTRACT FROM AUTHOR]

Studies of the sedimentary facies and sequence stratigraphy have indicated that the main depositional environments of the Lower Triassic Jialingjiang Formation in the eastern Sichuan Basin were a restricted platforms and evaporite platforms. Two third-order sequences (SQ1, SQ2) and five fourth-order sequences (SSQ1-SSQ5) were recognized. Sediments in the Jialingjiang strata evolved from a restricted platform to an evaporite platform, then to restricted platform again, and finally to an evaporite platform. The main hydrocarbon reservoirs and producing layers appear in the SSQ1-SSQ2 sequence. Sequences SSQ1-SSQ5 are further subdivided into transgressive systems tracts (TST) and highstand systems tracts (HST). Taking these sequences as mapping units, lithofacies paleogeographic maps were prepared for each of the fourth-order tracts. Evidence from the study of the distribution of favorable reservoirs indicates that the restricted platform-to-platform shoal in the SSQ1 and SSQ2 sequences are key areas for future exploration. [ABSTRACT FROM AUTHOR]

Dolostone-evaporite paragenesis systems (DEPS) have been widely found in Precambrian to Quaternary strata worldwide. However' despite its wide spatio-temporal distribution' the formation mechanism and controlling factors of DEPS remain poorly studied. By reference to copious literature from China and elsewhere combined with previous knowledge of DEPS in China' this study comprehensively summarizes the development characteristics' combination patterns and formation mechanism of DEPS. Firstly' its spatio-temporal distribution is clarified based on published studies: laterally' DEPS is known to be widely distributed in 51 regions globally' mainly in the northern hemisphere (mostly in Asia' followed by Europe and North America). Comparatively' it is found less often in Africa and is only scattered in South America and Oceania. Stratigraphically' although DEPS is found in many Precambrian to Quaternary strata' it appears mostly in the Permian. The combination patterns of evaporite and dolostone in DEPS include the interbedding of dolostone and evaporite' with thick dolostone overlying thick evaporite' thick evaporite overlying thick dolostone' thick dolostone mixed with thin evaporite' and thick evaporite mixed with thin dolostone. The formation process' distribution and main controlling factors of symbiotic differences as well as the particularity and universality of the paragenetic system development are discussed. Secondly' based on macro- to microscale characterization of mineral types in DEPS' six types of evaporites and five types of dolostones have been found and their genesis is discussed. Finally' the properties' characteristics' sources and evolution paths of diagenetic fluids in DEPS are summarized. DEPS studies provide new concepts for solving the "dolostone (or dolomite?) " question' and promote the understanding of the important basic geological problems associated with DEPS. Such studies also provide theoretical guidance for the exploration of oil and gas resources in the paragenetic system. [ABSTRACT FROM AUTHOR]

The Lower Permian Fengcheng Formation in the Mahu Sag of the Junggar Basin was developed in a volcanic-induced alkaline saline lacustrine environment, with deposition of thick-bedded sodium carbonates and high-quality source rocks, as well as the borosilicate reedmergnerite, which is a rare mineral globally but is very rich in the Fengcheng Formation. Based on petrography, fluid inclusion and boron isotope studies, the aim of this study was to discover the origin of the reedmergnerite which, in the Fengcheng Formation, often replaces carbonate minerals, including shortite, eitelite, northupite, calcite, trona, and even barytocalcite. The homogenization temperature of the primary inclusions in the reedmergnerite ranged from 100 to 116°C. Previous synthetic experimental studies have found that the δ11B values of reedmergnerite are 0.33-2.13‰. It is proposed here that, due to the limitations of temperature and pressure in surface or shallow burial processes, the source of boron in reedmergnerite was deep hydrothermal fluid in the original sedimentary environment, mainly in deep diagenetic environments (>3000 m). Therefore, the enrichment of reedmergnerite in the Fengcheng Formation is interpreted as the result of intense magmatic hydrothermal activity and a long diagenetic history. [ABSTRACT FROM AUTHOR]

Siliceous-sulphate rock coatings were observed at Zhenzhu Spring, an acid sulphate hot spring in the Tengchong volcanic field, China. These rock coatings are mainly formed of gypsum and amorphous silica. Some alum-(K), voltaite, α-quartz and muscovite were also found. Four different laminae are developed in the rock coatings: gypsum layer, tight siliceous layer, tabular siliceous layer and siliceous debris layer. The gypsum layer is located at the top of the rock coatings, while other siliceous layers appear below the gypsum layer. Geochemical modelling of the fluids was performed to identify the mechanisms responsible for the formation of gypsum and amorphous silica. The results indicated that the occurrence of gypsum is related to the acid-fog deposition and amorphous silica mainly originates from spring water. Fog deposition provided the rock coatings with abundant SO42− and Ca, and the subsequent complete evaporation of the condensed fluids produced gypsum. Seasonal climate change (especially variation in rainfall) determines the fluctuations of capillary action and dissolution. Rainfall events in the wet season led to periods of non-precipitating gypsum and promoted the capillary rise of the spring water. Slightly diluted capillary water (a small amount of rainwater) covered the rock coatings, formed a tight siliceous layer on the rock-coating surface and/or filled the pores among the gypsum crystals forming many tabular siliceous aggregates. Heavy rainfall (high dilution), however, resulted in non-precipitating amorphous silica and accelerated the gypsum dissolution, leaving tabular pores around tabular siliceous aggregates and forming a tabular siliceous layer. [ABSTRACT FROM AUTHOR]

The Zhenzhu Spring, located in the Tengchong volcanic field, Yunnan, China, is an acid hot spring with high SO42− concentrations and intense acid aerosol generation. In order to understand the formation mechanism of sulfate minerals at the Zhenzhu Spring and provide a better insight into the sulfur isotope geochemistry of the associated Rehai hydrothermal system, we investigated the spring water hydrochemistry, mineralogy and major-element geochemistry of sulfate minerals at the Zhenzhu Spring together with the sulfur-oxygen isotope geochemistry of sulfur-containing materials at the Rehai geothermal field and compared the isotope results with those in other steam-heated environments. Subaerial minerals include a wide variety of sulfate minerals (gypsum, alunogen, pickeringite, tamarugite, magnesiovoltaite and a minor Mg–S–O phase) and amorphous SiO2. The δ34S values of the subaerial sulfate minerals at the Zhenzhu Spring varied subtly from –0.33 to 1.88‰ and were almost consistent with the δ34S values of local H2S (–2.6 to 0.6‰) and dissolved SO42− (–0.2 to 5.8‰), while the δ18O values (–8.94 to 20.1‰) were between that of the spring waters (–10.19 to –6.7‰) and atmospheric O2 (~23.88‰). The results suggest that most of the sulfate minerals are derived from the oxidation of H2S, similar to many sulfate minerals from modern steam-heated environments. However, the rapid environmental change (different ratio of atmospheric and water oxygen) at the Zhenzhu Spring accounts for the large variation of δ18O. The formation of subaerial sulfate minerals around the Zhenzhu Spring is related to acid aerosols (vapour and acid water droplets). The intense activity of spring water around vents supply the aerosol with H2SO4 (H2S oxidation and acid water droplets formed by bubble bursting) and few cations. Deposition of the acid sulfate aerosol forms the acid condensate, which attacks the underlying rocks and releases many cations and anions to form subaerial sulfate minerals at the Zhenzhu Spring. [ABSTRACT FROM AUTHOR]

The Calloviane-Oxfordian carbonates in the northeastern Amu Darya Basin of southeastern Turkmenistan are composed of medium- to thick-bedded, mostly grainy limestones with various skeletal (bivalves, brachiopods, echinoderms, foraminifera, corals, and sponge) and non-skeletal grains (intraclasts, ooids and peloids). Two facies zones, six standard facies belts and some microfacies types were recognized, and sedimentary model "carbonate ramp-rimmed platform" was proposed and established that can be compared with the classical carbonate sedimentary models. In this model, favorable reservoirs not only developed in the intraplatform shoal of open platform, or reef and shoal on the platform margin, but also in the patch reefs, shoal and mound facies on the upper slope. The reservoir's pore space is dominated by intergranular and intragranular pores and fissure-pore reservoirs exist with medium porosity and medium to low permeability. Sedimentary facies and diagenetic dissolution are the key controlling factors for the development of high-quality reservoirs. [ABSTRACT FROM AUTHOR]