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We present a velocity-resolved reverberation mapping analysis of the hypervariable quasar RM160 (SDSS J141041.25+531849.0) at z = 0.359 with 153 spectroscopic epochs of data representing a ten-year baseline (2013-2023). We split the baseline into two regimes based on the 3x flux increase in the light curve: a 'low state' phase during the years 2013-2019 and a 'high state' phase during the years 2022-2023. The velocity-resolved lag profiles (VRLP) indicate that gas with different kinematics dominates the line emission in different states. The H\b{eta} VRLP begins with a signature of inflow onto the BLR in the 'low state', while in the 'high state' it is flatter with less signature of inflow. The H{\alpha} VRLP begins consistent with a virialized BLR in the 'low state', while in the 'high state' shows a signature of inflow. The differences in the kinematics between the Balmer lines and between the 'low state' and the 'high state' suggests complex BLR dynamics. We find that the BLR radius and velocity (both FWHM and {\sigma}) do not obey a constant virial product throughout the monitoring period. We find that BLR lags and continuum luminosity are correlated, consistent with rapid response of the BLR gas to the illuminating continuum. The BLR kinematic profile changes in unpredictable ways that are not related to continuum changes and reverberation lag. Our observations indicate that non-virial kinematics can significantly contribute to observed line profiles, suggesting caution for black-hole mass estimation in luminous and highly varying quasars like RM160., Comment: 23 pages, 17 figures

We present dynamical modeling of the broad-line region (BLR) for the highly variable AGN SDSS J141041.25+531849.0 ($z = 0.359$) using photometric and spectroscopic monitoring data from the Sloan Digital Sky Survey Reverberation Mapping project and the SDSS-V Black Hole Mapper program, spanning from early 2013 to early 2023. We model the geometry and kinematics of the BLR in the H$\beta$, H$\alpha$, and MgII, emission lines for three different time periods to measure the potential change of structure within the BLR across time and line species. We consistently find a moderately edge-on $(i_{\rm full-state} = 53.29^{\circ} \,{}^{+7.29}_{-6.55})$ thick-disk $(\theta_{\rm opn, \; full-state} = 54.86^{\circ} \,{}^{+5.83}_{-4.74})$ geometry for all BLRs, with a joint estimate for the mass of the supermassive black hole (SMBH) for each of three time periods, yielding $\log_{10}(M_{\rm BH} / M_{\odot}) = 7.66^{+0.12}_{-0.13}$ when using the full dataset. The inferred individual virial factor $f$ $\sim 1$ is significantly smaller than the average factor for a local sample of dynamically modeled AGNs. There is strong evidence for non-virial motion, with over $80\%$ of clouds on inflowing/outflowing orbits. We analyze the change in model parameters across emission lines, finding the radii of BLRs for the emission lines are consistent with the following relative sizes $R_{\rm H\beta} \lesssim R_{\rm MgII } \lesssim R_{\rm H\alpha}$. Comparing results across time, we find $R_{\rm low-state} \lesssim R_{\rm high-state}$, with the change in BLR size for H$\beta$, being more significant than for the other two lines. The data also reveal complex, time-evolving, and potentially transient dynamics of the BLR gas over decade-long timescales, encouraging for future dynamical modeling of fine-scale BLR kinematics., Comment: 32 pages, 16 figures, 4 tables. Submitted to ApJ

Over three decades of reverberation mapping (RM) studies on local broad-line active galactic nuclei (AGNs) have measured reliable black-hole (BH) masses for $> 100$ AGNs. These RM measurements reveal a significant correlation between the Balmer broad-line region size and the AGN optical luminosity (the $R-L$ relation). Recent RM studies for AGN samples with more diverse BH accretion parameters (e.g., mass and Eddington ratio) reveal a substantial intrinsic dispersion around the average $R-L$ relation, suggesting variations in the overall spectral energy distribution shape as functions of accretion parameters. Here we perform a detailed photoionization investigation of expected broad-line properties as functions of accretion parameters, using the latest models for the AGN continuum implemented in {\tt qsosed}. We compare theoretical predictions with observations of a sample of 67 $z\lesssim0.5$ reverberation-mapped AGNs with both rest-frame optical and UV spectra in the moderate-accretion regime (Eddington ratio $\lambda_{\rm Edd}\equiv L/L_{\rm Edd}<0.5$). The UV/optical line strengths and their dependences on accretion parameters can be reasonably well reproduced by the locally-optimally-emitting cloud (LOC) photoionization models. We provide quantitative recipes that use optical/UV line flux ratios to infer the ionizing continuum, which is not directly observable. In addition, photoionization models with universal values of ionization parameter ($\log U_{\rm H}=-2$) and hydrogen density ($\log n({\rm H})=12$) can qualitatively reproduce the observed global $R-L$ relation for the current AGN sample. However, such models fail to reproduce the observed trend of decreasing BLR size with $L/L_{\rm Edd}$ at fixed optical luminosity, which may imply that the gas density increases with the accretion rate., Comment: 23 pages, 15 figures. Submitted to ApJ. Comments welcome!

SDSS-V is carrying out a dedicated survey for white dwarfs, single and in binaries, and we report the analysis of the spectroscopy of 505 cataclysmic variables (CVs) and CV candidates obtained during the first 34 months of observations of SDSS-V. We developed a convolutional neural network (CNN) to aid with the identification of CV candidates among the over 2 million SDSS-V spectra obtained with the BOSS spectrograph. The CNN reduced the number of spectra that required visual inspection to $\simeq2$ per cent of the total. We identified 779 CV spectra among the CNN-selected candidates, plus an additional 37 CV spectra that the CNN misclassified, but that were found serendipitously by human inspection of the data. Analysing the SDSS-V spectroscopy and ancillary data of the 505 CVs in our sample, we report 62 new CVs, spectroscopically confirm 243 and refute 13 published CV candidates, and we report 68 new or improved orbital periods. We discuss the completeness and possible selection biases of the machine learning methodology, as well as the effectiveness of targeting CV candidates within SDSS-V. Finally, we re-assess the space density of CVs, and find $1.3\times 10^{-5}\,\mathrm{pc^{-3}}$., Comment: Submitted to MNRAS. 23 pages, 25 figures. Supplementary data contains details of 505 CVs including spectra and light curves

We present the results of an investigation of a highly variable CIV broad absorption-line feature in the quasar SBS 1408+544 (z=2.337) that shows a significant shift in velocity over time. This source was observed as a part of the Sloan Digital Sky Survey Reverberation Mapping Project and the SDSS-V Black Hole Mapper Reverberation Mapping Project, and has been included in two previous studies, both of which identified significant variability in a high-velocity CIV broad absorption line (BAL) on timescales of just a few days in the quasar rest frame. Using ~130 spectra acquired over eight years of spectroscopic monitoring with SDSS, we have determined that this BAL is not only varying in strength, but is also systematically shifting to higher velocities. Using cross-correlation methods, we measure the velocity shifts (and corresponding acceleration) of the BAL on a wide range of timescales, measuring an overall velocity shift of delta v = -683 (+89, -84) km s-1 over the 8-year monitoring period. This corresponds to an average rest-frame acceleration of a=1.04 (+0.14, -0.13) cm s-2, though the magnitude of the acceleration on shorter timescales is not constant throughout. We place our measurements in the context of BAL-acceleration models and examine various possible causes of the observed velocity shift., Comment: Published in the Astrophysical Journal

High-quality Extragalactic Legacy-field Monitoring (HELM) is a long-term observing program that photometrically monitors several well-studied extragalactic legacy fields with the Dark Energy Camera (DECam) imager on the CTIO 4m Blanco telescope. Since Feb 2019, HELM has been monitoring regions within COSMOS, XMM-LSS, CDF-S, S-CVZ, ELAIS-S1, and SDSS Stripe 82 with few-day cadences in the $(u)gri(z)$ bands, over a collective sky area of $\sim 38$ deg${\rm ^2}$. The main science goal of HELM is to provide high-quality optical light curves for a large sample of active galactic nuclei (AGNs), and to build decades-long time baselines when combining past and future optical light curves in these legacy fields. These optical images and light curves will facilitate the measurements of AGN reverberation mapping lags, as well as studies of AGN variability and its dependences on accretion properties. In addition, the time-resolved and coadded DECam photometry will enable a broad range of science applications from galaxy evolution to time-domain science. We describe the design and implementation of the program and present the first data release that includes source catalogs and the first $\sim 3.5$ years of light curves during 2019A--2022A., Comment: 11 pages, 8 figures, 4 tables, submitted to ApJS. Median source catalogs and light curves of individual objects are publicly available at https://ariel.astro.illinois.edu/helm/

"Changing-look" active galactic nuclei (CL-AGNs) challenge our basic ideas about the physics of accretion flows and circumnuclear gas around supermassive black holes. Using first-year Sloan Digital Sky Survey V (SDSS-V) repeated spectroscopy of nearly 29,000 previously known AGNs, combined with dedicated follow-up spectroscopy, and publicly available optical light curves, we have identified 116 CL-AGNs where (at least) one broad emission line has essentially (dis-)appeared, as well as 88 other extremely variable systems. Our CL-AGN sample, with 107 newly identified cases, is the largest reported to date, and includes $\sim0.4\%$ of the AGNs reobserved in first-year SDSS-V operations. Among our CL-AGNs, 67% exhibit dimming while 33% exhibit brightening. Our sample probes extreme AGN spectral variability on months to decades timescales, including some cases of recurring transitions on surprisingly short timescales ($\lesssim 2$ months in the rest frame). We find that CL events are preferentially found in lower-Eddington-ratio ($f_{Edd}$) systems: Our CL-AGNs have a $f_{Edd}$ distribution that significantly differs from that of a carefully constructed, redshift- and luminosity-matched control sample (Anderson-Darling test yielding $p_{\rm AD}\approx 6\times10^{-5}$; median $f_{Edd}\approx0.025$ vs. $0.043$). This preference for low $f_{Edd}$ strengthens previous findings of higher CL-AGN incidence at lower $f_{Edd}$, found in smaller samples. Finally, we show that the broad MgII emission line in our CL-AGN sample tends to vary significantly less than the broad H$\beta$ emission line. Our large CL-AGN sample demonstrates the advantages and challenges in using multi-epoch spectroscopy from large surveys to study extreme AGN variability and physics., Comment: Submitted to ApJ. Full tables and figure-sets will be published upon acceptance, and can be made available upon request$.$

This work studies the relationship between accretion-disk size and quasar properties, using a sample of 95 quasars from the SDSS-RM project with measured lags between the $g$ and $i$ photometric bands. Our sample includes disk lags that are both longer and shorter than predicted by the \citet{SS73} model, requiring explanations which satisfy both cases. Although our quasars each have one lag measurement, we explore the wavelength-dependent effects of diffuse broad line region (BLR) contamination through our sample's broad redshift range, $0.1

We present the final data from the Sloan Digital Sky Survey Reverberation Mapping (SDSS-RM) project, a precursor to the SDSS-V Black Hole Mapper Reverberation Mapping program. This data set includes 11-year photometric and 7-year spectroscopic light curves for 849 broad-line quasars over a redshift range of 0.1=0.62+-0.07 for the line dispersion measured from the RMS spectrum. The intrinsic scatter of individual virial factors is 0.31+-0.07 dex, indicating a factor of two systematic uncertainty in RM black hole masses. Our lag measurements reveal significant R-L relations for Hbeta and MgII at high redshift, consistent with the latest measurements based on heterogeneous samples. While we are unable to robustly constrain the slope of the R-L relation for CIV given the limited dynamical range in luminosity, we found substantially larger scatter in CIV lags at fixed L1350. Using the SDSS-RM lag sample, we derive improved single-epoch (SE) mass recipes for Hbeta, MgII and CIV, which are consistent with their respective RM masses as well as between the SE recipes from two different lines, over the luminosity range probed by our sample. The new Hbeta and MgII recipes are approximately unbiased estimators at given RM masses, but there are systematic biases in the CIV recipe. The intrinsic scatter of SE masses around RM masses is ~0.45 dex for Hbeta and MgII, increasing to ~0.58 dex for CIV., Comment: Replaced with accepted version (ApJS in press). All measurements remain unchanged from the previous version. 38 pages. Data products available at https://ariel.astro.illinois.edu/sdssrm/final result/ and ftp://quasar.astro.illinois.edu/public/sdssrm/final_result/

Weak emission-line quasars (WLQs) are a subset of Type 1 quasars that exhibit extremely weak Ly$\alpha +$N V $\lambda$1240 and/or C IV $\lambda$1549 emission lines. We investigate the relationship between emission-line properties and accretion rate for a sample of 230 `ordinary' Type 1 quasars and 18 WLQs at $z < 0.5$ and $1.5 < z < 3.5$ that have rest-frame ultraviolet and optical spectral measurements. We apply a correction to the H$\beta$-based black-hole mass ($M_{\rm BH}$) estimates of these quasars using the strength of the optical Fe II emission. We confirm previous findings that WLQs' $M_{\rm BH}$ values are overestimated by up to an order of magnitude using the traditional broad emission-line region size-luminosity relation. With this $M_{\rm BH}$ correction, we find a significant correlation between H$\beta$-based Eddington luminosity ratios and a combination of the rest-frame C IV equivalent width and C IV blueshift with respect to the systemic redshift. This correlation holds for both ordinary quasars and WLQs, which suggests that the two-dimensional C IV parameter space can serve as an indicator of accretion rate in all Type 1 quasars across a wide range of spectral properties., Comment: 17 pages (AASTeX 6.3.1), 5 figures, accepted for publication in ApJ

Extremely variable quasars can also show strong changes in broad-line emission strength and are known as changing-look quasars (CLQs). To study the CLQ transition mechanism, we present a pilot sample of CLQs with X-ray observations in both the bright and faint states. From a sample of quasars with bright-state archival SDSS spectra and (Chandra or XMM-Newton) X-ray data, we identified five new CLQs via optical spectroscopic follow-up, and then obtained new target-of-opportunity X-ray observations with Chandra. No strong absorption is detected in either the bright- or the faint-state X-ray spectra. The intrinsic X-ray flux generally changes along with the optical variability, and the X-ray power-law slope becomes harder in the faint state. Large amplitude mid-infrared variability is detected in all five CLQs, and the MIR variability echoes the variability in the optical with a time lag expected from the light-crossing time of the dusty torus for CLQs with robust lag measurements. The changing-obscuration model is not consistent with the observed X-ray spectra and spectral energy distribution changes seen in these CLQs. It is highly likely that the observed changes are due to the changing accretion rate of the supermassive black hole, so the multiwavelength emission varies accordingly, with promising analogies to the accretion states of X-ray binaries., Comment: Accepted for publication in ApJ; 30 pages, 12 figures

We present a high-cadence multi-epoch analysis of dramatic variability of three broad emission lines (MgII, H$\beta$, and H$\alpha$) in the spectra of the luminous quasar ($\lambda L_{\lambda}$(5100\r{A}) = $4.7 \times 10^{44}$ erg s$^{-1}$) SDSS J141041.25+531849.0 at $z = 0.359$ with 127 spectroscopic epochs over 9 years of monitoring (2013-2022). We observe anti-correlations between the broad emission-line widths and flux in all three emission lines, indicating that all three broad emission lines "breathe" in response to stochastic continuum variations. We also observe dramatic radial velocity shifts in all three broad emission lines, ranging from $\Delta{v}$ $\sim$400 km s$^{-1}$ to $\sim$800 km s$^{-1}$, that vary over the course of the monitoring period. Our preferred explanation for the broad-line variability is complex kinematics in the broad-line region gas. We suggest a model for the broad-line variability that includes a combination of gas inflow with a radial gradient, an azimuthal asymmetry (e.g., a hot spot), superimposed on the stochastic flux-driven changes to the optimal emission region ("line breathing"). Similar instances of line-profile variability due to complex gas kinematics around quasars are likely to represent an important source of false positives in radial velocity searches for binary black holes, which typically lack the kind of high-cadence data we analyze here. The long-duration, wide-field, and many-epoch spectroscopic monitoring of SDSS-V BHM-RM provides an excellent opportunity for identifying and characterizing broad emission-line variability, and the inferred nature of the inner gas environment, of luminous quasars.

The eighteenth data release of the Sloan Digital Sky Surveys (SDSS) is the first one for SDSS-V, the fifth generation of the survey. SDSS-V comprises three primary scientific programs, or "Mappers": Milky Way Mapper (MWM), Black Hole Mapper (BHM), and Local Volume Mapper (LVM). This data release contains extensive targeting information for the two multi-object spectroscopy programs (MWM and BHM), including input catalogs and selection functions for their numerous scientific objectives. We describe the production of the targeting databases and their calibration- and scientifically-focused components. DR18 also includes ~25,000 new SDSS spectra and supplemental information for X-ray sources identified by eROSITA in its eFEDS field. We present updates to some of the SDSS software pipelines and preview changes anticipated for DR19. We also describe three value-added catalogs (VACs) based on SDSS-IV data that have been published since DR17, and one VAC based on the SDSS-V data in the eFEDS field., Comment: Accepted to ApJS

Which galaxies in the general population turn into active galactic nuclei (AGNs) is a keystone of galaxy formation and evolution. Thanks to SRG/eROSITA's contiguous 140 square degree pilot survey field, we constructed a large, complete, and unbiased soft X-ray flux-limited ($F_X>6.5\times 10^{-15}$ erg s$^{-1}$ cm$^{-2}$) AGN sample at low redshift, $0.05

We report the discovery of a new ``changing-look'' active galactic nucleus (CLAGN) event, in the quasar SDSS J162829.17+432948.5 at z=0.2603, identified through repeat spectroscopy from the fifth Sloan Digital Sky Survey (SDSS-V). Optical photometry taken during 2020--2021 shows a dramatic dimming of ${\Delta}$g${\approx}$1 mag, followed by a rapid recovery on a timescale of several months, with the ${\lesssim}$2 month period of rebrightening captured in new SDSS-V and Las Cumbres Observatory spectroscopy. This is one of the fastest CLAGN transitions observed to date. Archival observations suggest that the object experienced a much more gradual dimming over the period of 2011--2013. Our spectroscopy shows that the photometric changes were accompanied by dramatic variations in the quasar-like continuum and broad-line emission. The excellent agreement between the pre- and postdip photometric and spectroscopic appearances of the source, as well as the fact that the dimmest spectra can be reproduced by applying a single extinction law to the brighter spectral states, favor a variable line-of-sight obscuration as the driver of the observed transitions. Such an interpretation faces several theoretical challenges, and thus an alternative accretion-driven scenario cannot be excluded. The recent events observed in this quasar highlight the importance of spectroscopic monitoring of large active galactic nucleus samples on weeks-to-months timescales, which the SDSS-V is designed to achieve., Comment: Published in ApJL

We present ultraviolet spectroscopy covering the Ly$\alpha$ + N V complex of six candidate low-redshift ($0.9 < z < 1.5$) weak emission-line quasars (WLQs) based on observations with the Hubble Space Telescope. The original systematic searches for these puzzling Type 1 quasars with intrinsically weak broad emission lines revealed an $N \approx 100$ WLQ population from optical spectroscopy of high-redshift ($z > 3$) quasars, defined by a Ly$\alpha$ + N V rest-frame equivalent width (EW) threshold $< 15.4$ \r{A}. Identification of lower-redshift ($z < 3$) WLQ candidates, however, has relied primarily on optical spectroscopy of weak broad emission lines at longer rest-frame wavelengths. With these new observations expanding existing optical coverage into the ultraviolet, we explore unifying the low- and high-$z$ WLQ populations via EW[Ly$\alpha$+NV]. Two objects in the sample unify with high-$z$ WLQs, three others appear consistent with the intermediate portion of the population connecting WLQs and normal quasars, and the final object is consistent with typical quasars. The expanded wavelength coverage improves the number of available line diagnostics for our individual targets, allowing a better understanding of the shapes of their ionizing continua. The ratio of EW[Ly$\alpha$+NV] to EW[MgII] in our sample is generally small but varied, favoring a soft ionizing continuum scenario for WLQs, and we find a lack of correlation between EW[Ly$\alpha$+NV] and the X-ray properties of our targets, consistent with a "slim-disk" shielding gas model. We also find indications that weak absorption may be a more significant contaminant in low-$z$ WLQ populations than previously thought., Comment: 20 pages, 6 figures, 3 tables. Accepted for publication in ApJ

Active galactic nuclei (AGN) can vary significantly in their rest-frame optical/UV continuum emission, and with strong associated changes in broad line emission, on much shorter timescales than predicted by standard models of accretion disks around supermassive black holes. Most such ``changing-look'' or "changing-state" AGN -- and at higher luminosities, changing-look quasars (CLQs) -- have been found via spectroscopic follow-up of known quasars showing strong photometric variability. The Time Domain Spectroscopic Survey of SDSS-IV includes repeat spectroscopy of large numbers of previously-known quasars, many selected irrespective of photometric variability, and with spectral epochs separated by months to decades. Our visual examination of these repeat spectra for strong broad line variability yielded 61 newly-discovered CLQ candidates. We quantitatively compare spectral epochs to measure changes in continuum and H$\beta$ broad line emission, finding 19 CLQs, of which 15 are newly-recognized. The parent sample includes only broad line quasars, so our study tends to find objects that have dimmed, i.e., turn-off CLQs. However, we nevertheless find 4 turn-on CLQs that meet our criteria, albeit with broad lines in both dim and bright states. We study the response of H$\beta$ and MgII emission lines to continuum changes. The Eddington ratios of CLQs are low, and/or their H$\beta$ broad line width is large relative to the overall quasar population. Repeat quasar spectroscopy in the upcoming SDSS-V Black Hole Mapper program will reveal significant numbers of CLQs, enhancing our understanding of the frequency and duty-cycle of such strong variability, and the physics and dynamics of the phenomenon., Comment: 37 pages, 14 figures, accepted by ApJ 23-May-2022

This paper documents the seventeenth data release (DR17) from the Sloan Digital Sky Surveys; the fifth and final release from the fourth phase (SDSS-IV). DR17 contains the complete release of the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey, which reached its goal of surveying over 10,000 nearby galaxies. The complete release of the MaNGA Stellar Library (MaStar) accompanies this data, providing observations of almost 30,000 stars through the MaNGA instrument during bright time. DR17 also contains the complete release of the Apache Point Observatory Galactic Evolution Experiment 2 (APOGEE-2) survey which publicly releases infra-red spectra of over 650,000 stars. The main sample from the Extended Baryon Oscillation Spectroscopic Survey (eBOSS), as well as the sub-survey Time Domain Spectroscopic Survey (TDSS) data were fully released in DR16. New single-fiber optical spectroscopy released in DR17 is from the SPectroscipic IDentification of ERosita Survey (SPIDERS) sub-survey and the eBOSS-RM program. Along with the primary data sets, DR17 includes 25 new or updated Value Added Catalogs (VACs). This paper concludes the release of SDSS-IV survey data. SDSS continues into its fifth phase with observations already underway for the Milky Way Mapper (MWM), Local Volume Mapper (LVM) and Black Hole Mapper (BHM) surveys., Comment: 40 pages, 8 figures, 6 tables. In press at ApJSS (arxiv v2 corrects some minor typos and updates references)

The eROSITA Final Equatorial-Depth Survey (eFEDS), executed during the performance verification phase of the Spectrum-Roentgen-Gamma (SRG)/eROSITA telescope, was completed in Nov. 2019. One of the science goals of this survey is to demonstrate the ability of eROSITA to detect samples of clusters and groups at the final depth of the eROSITA all-sky survey. Because of the sizeable point-spread function of eROSITA, high-redshift clusters of galaxies or compact nearby groups hosting bright active galactic nuclei (AGN) can be misclassified as point sources by the source detection algorithms. A total of 346 galaxy clusters and groups in the redshift range of 0.1

As main-sequence stars with C$>$O, dwarf carbon (dC) stars are never born alone but inherit carbon-enriched material from a former asymptotic giant branch (AGB) companion. In contrast to M dwarfs in post-mass transfer binaries, C$_2$ and/or CN molecular bands allow dCs to be identified with modest-resolution optical spectroscopy, even after the AGB remnant has cooled beyond detectability. Accretion of substantial material from the AGB stars should spin up the dCs, potentially causing a rejuvenation of activity detectable in X-rays. Indeed, a few dozen dCs have recently been found to have photometric variability with periods under a day. However, most of those are likely post-common-envelope binaries (PCEBs), spin-orbit locked by tidal forces, rather than solely spun-up by accretion. Here, we study the X-ray properties of a sample of the five nearest known dCs with $Chandra$. Two are detected in X-rays, the only two for which we also detected short-period photometric variability. We suggest that the coronal activity detected so far in dCs is attributable to rapid rotation due to tidal locking in short binary orbits after a common-envelope phase, late in the thermally pulsing (TP) phase of the former C-AGB primary (TP-AGB)., Comment: 18 pages, 9 figures, 4 tables, Accepted to ApJ, title changed based on referee recommendation

"Changing-look" quasars are a new class of highly variable active galactic nuclei that have changed their spectral type over surprisingly short timescales of just a few years. The origin of this phenomenon is debated, but is likely to reflect some change in the accretion flow. To investigate the disk-corona systems in these objects, we measure optical/UV-X-ray spectral indices ($\alpha_{\rm OX}$) and Eddington ratios ($\lambda_{\rm Edd}$) of ten previously-discovered changing-look quasars at two or more epochs. By comparing these data with simulated results based on the behavior of X-ray binaries, we find possible similarities in spectral indices below 1% Eddington ratio. We further investigate the Eddington ratios of changing-look quasars before and after their spectral type changes, and find that changing-look quasars cross the 1% Eddington ratio boundary when their broad emission lines disappear/emerge. This is consistent with the disk-wind model as the origin of broad emission lines., Comment: 31 pages, 9 figures, accepted for publication in ApJ

The kinetics for O2 oxidation of individual graphite and graphene platelet nanoparticles (NPs) were studied as a function of temperature (1200 to 2200 K) at varying oxygen partial pressures, using a single nanoparticle mass spectrometry method. NP temperature (TNP) was measured by measuring the NP thermal emission spectra during the kinetics studies. The initial oxidation efficiency is found to peak in the 1200 to 1500 K range, dropping by an order of magnitude as TNP was increased above 2000 K. There were large NP-to-NP variations in the oxidation rates, attributed to variations in the NP surface structure. In addition, the oxidation efficiencies decreased, non-monotonically, as the NPs reacted, by factors of between 10 and 300. This evolution of reactivity is attributed to changes in the NP surface structure due to the combination of oxidation and annealing. The optical properties, including wavelength dependence of the emissivity, and the absorption cross section for the 532 nm heating laser, also tend to evolve as the NPs oxidize, but differently for each individual NP, presumably reflecting differences in the initial structures, and how they evolve under different reaction conditions., Comment: Text with 9 figures, supporting information with 9 figures, tables of data for the 9 main text figures

We present the final Sloan Digital Sky Survey IV (SDSS-IV) quasar catalog from Data Release 16 of the extended Baryon Oscillation Spectroscopic Survey (eBOSS). This catalog comprises the largest selection of spectroscopically confirmed quasars to date. The full catalog includes two sub-catalogs: a "superset" of all SDSS-IV/eBOSS objects targeted as quasars containing 1,440,615 observations and a quasar-only catalog containing 750,414 quasars, including 225,082 new quasars appearing in an SDSS data release for the first time, as well as known quasars from SDSS-I/II/III. We present automated identification and redshift information for these quasars alongside data from visual inspections for 320,161 spectra. The quasar-only catalog is estimated to be 99.8% complete with 0.3% to 1.3% contamination. Automated and visual inspection redshifts are supplemented by redshifts derived via principal component analysis and emission lines. We include emission line redshifts for H$\alpha$, H$\beta$, Mg II, C III], C IV, and Ly$\alpha$. Identification and key characteristics generated by automated algorithms are presented for 99,856 Broad Absorption Line quasars and 35,686 Damped Lyman Alpha quasars. In addition to SDSS photometric data, we also present multi-wavelength data for quasars from GALEX, UKIDSS, WISE, FIRST, ROSAT/2RXS, XMM-Newton, and Gaia. Calibrated digital optical spectra for these quasars can be obtained from the SDSS Science Archive Server., Comment: 32 pages, 13 figures, 6 tables. Accepted to ApJS. Catalog files are available at https://data.sdss.org/sas/dr16/eboss/qso/DR16Q/ . A summary of all SDSS BAO and RSD measurements with legacy figures can be found at https://www.sdss.org/science/final-bao-and-rsd-measurements/ while full cosmological interpretation of these can be found at https://www.sdss.org/science/cosmology-results-from-eboss/

We present a combined experimental/theoretical study of Pt$_n$/SiO$_2$ and Pt$_n$Sn$_x$/SiO$_2$ (n = 4, 7) model catalysts for the endothermic dehydrogenation of hydrocarbons, using the ethylene intermediate as a model reactant. Supported pure Ptn clusters are found to be highly active toward dehydrogenation of C2D4, quickly deactivating due to a combination of carbon deposition and sintering, resulting in loss of accessible Pt sites. Addition of Sn to Ptn clusters results in the complete suppression of C2D4 dehydrogenation and carbon deposition, and also stabilizes the clusters against thermal sintering. Theory shows that both systems have thermal access to a multitude of cluster structures and adsorbate configurations that form a statistical ensemble. While Pt4/SiO2 clusters bind ethylene in both di-sigma and pi-bonded configurations, Pt$_4$Sn$_3$/SiO$_2$ binds C2H4 only in the pi-mode, with di-sigma bonding suppressed by a combination of electronic and geometric features of the PtSn clusters. Dehydrogenation reaction profiles on the accessible cluster isomers were calculated using the climbing image nudged elastic band (CI-NEB) method., Comment: manuscript, supporting information, and tables of all data and structures

A single nanoparticle (NP) mass spectrometry method was used to measure sublimation rates as a function of nanoparticle temperature (TNP) for a number of individual graphite and graphene NPs. Initially, the NP sublimation rates were ca. 400 times faster than that for bulk graphite, and there were large NP-to-NP variations. Over time, the rate slowed substantially, though remaining well above the bulk rate. The initial activation energies (Eas) were correspondingly low and doubled as a few monolayer's worth of material were sublimed from the surfaces. The high initial rates and low Eas are attributed to large numbers of edge and other low coordination sites on the NP surfaces, and the changes are attributed to atomic-scale "smoothing" of the surface by preferential sublimation of the less stable sites. The emissivity of the NPs also changed after heating, most frequently increasing. The emissivity and sublimation rates were anti-correlated, leading to the conclusion that high densities of low-coordination sites on the NP surfaces enhances sublimation but suppresses emissivity., Comment: Final version submitted to J. Am. Chem. Soc

Results are presented for thermal emission from individually trapped carbon nanoparticles (NPs) in the temperature range from 1000 to 2100 K. We explore the effects on the magnitude and wavelength dependency of the emissivity, epsilon (lambda), of the NP size and charge and of the type of carbon material, including graphite, graphene, diamond, carbon black, and carbon dots. In addition, it is found that heating the NPs, particularly to temperatures above 1900 K, results in significant changes in the emission properties, which is attributed to changes in the distribution of surface and defect sites caused by annealing and sublimation.

An atomic layer deposition process is used to modify size-selected Pt7/alumina model catalysts by Sn addition, both before and after Pt7 cluster deposition. Surface science methods are used to probe the effects of Sn-modification on the electronic properties, reactivity, and morphology of the clusters. Sn addition, either before or after cluster deposition, is found to strongly affect the binding properties of a model alkene, ethylene, changing the number and type of binding sites, and suppressing decomposition leading to carbon deposition and poisoning of the catalyst. Density functional theory on a model system, Pt4Sn3/alumina, shows that the Sn and Pt atoms are mixed, forming alloy clusters with substantial electron transfer from Sn to Pt. The presence of Sn also makes all the thermally accessible structures closed shell, such that ethylene binds only by {\pi}-bonding to a single Pt atom. The Sn-modified catalysts are quite stable in repeated ethylene temperature programmed reaction experiments, suggesting that the presence of Sn also reduces the tendency of the sub-nano-clusters to undergo thermal sintering.

This paper documents the sixteenth data release (DR16) from the Sloan Digital Sky Surveys; the fourth and penultimate from the fourth phase (SDSS-IV). This is the first release of data from the southern hemisphere survey of the Apache Point Observatory Galactic Evolution Experiment 2 (APOGEE-2); new data from APOGEE-2 North are also included. DR16 is also notable as the final data release for the main cosmological program of the Extended Baryon Oscillation Spectroscopic Survey (eBOSS), and all raw and reduced spectra from that project are released here. DR16 also includes all the data from the Time Domain Spectroscopic Survey (TDSS) and new data from the SPectroscopic IDentification of ERosita Survey (SPIDERS) programs, both of which were co-observed on eBOSS plates. DR16 has no new data from the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey (or the MaNGA Stellar Library "MaStar"). We also preview future SDSS-V operations (due to start in 2020), and summarize plans for the final SDSS-IV data release (DR17)., Comment: DR16 release: Monday Dec 9th 2019. This is the alphabetical order SDSS-IV collaboration data release paper. 25 pages, 6 figures, accepted by ApJS on 11th May 2020. Minor changes clarify or improve text and figures relative to v1

Physical models of X-ray binary outbursts can aid in understanding the origin of 'changing-look' active galactic nuclei (AGN), if we can establish that these two black hole accretion phenomena are analogous. Previously, studies of the correlation between the UV-to-X-ray spectral index alpha_OX and Eddington ratio using single-epoch observations of changing-look AGN samples have revealed possible similarities to the spectral evolution of outbursting X-ray binaries. However, direct comparisons using multi-epoch UV/X-ray light curves of individual changing-look AGN undergoing dramatic changes in Eddington ratio have been scarce. Here, we use published Swift UV/X-ray light curves of two changing-look AGN (NGC 2617 and ZTF18aajupnt) to examine the evolution of their alpha_OX values during outburst. We show that the combination of these two changing-look AGN can trace out the predicted spectral evolution from X-ray binary outbursts, including the inversion in the evolution of alpha_OX as a function of Eddington ratio. We suggest that the spectral softening that is observed to occur below a critical Eddington ratio in both AGN and X-ray binaries is due to reprocessing of Comptonized X-ray emission by the accretion disk, based on the X-ray to UV reverberation lags previously observed in NGC 2617. Our results suggest that the physical processes causing the changing-look AGN phenomenon are similar to those in X-ray binary outbursts., Comment: 14 pages, 5 figures. ApJ submitted