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Assessment of integrated personal exposure (PE) to airborne particulate matter (PM) across diverse microenvironments (MEs) over 24 hours under different exposure scenarios is necessary to identify appropriate strategies to improve urban air quality and mitigate the health effects of PM. We carried out a collaborative study in a densely populated city-state (Singapore) to assess the integrated PE to fine particles (PM2.5), ultrafine particles (UFPs) and black carbon (BC) across diverse indoor and outdoor urban MEs, estimate related health risks and make suitable recommendations for healthy living in cities. Two volunteers with different lifestyles participated in the study by tracking their PE to particulate air pollution and the time-activity patterns over 24 hours using portable PM monitoring devices and recording their whereabouts using GPS coordinates. Home, transport and recreation (i.e., food court) MEs represented pollution hotspots of PM2.5 (21.0 μg/m3), BC (3.4 μg/m3) and UFP (33.0 × 103 #/cm3), respectively. Among the different modes of transport used by the participants (walking, cycling, e-scooter, mass rapid transport (MRT), bus, car and taxi), the air pollutants had elevated concentrations while commuting by public transport (bus and MRT) as well as during active modes of transport (walking and cycling). Air-conditioned cars and taxis, equipped with air filtration systems, represented the lowest PE. The health risk assessment revealed that there are potential carcinogenic risks associated with the long-term exposure to elevated levels of PM2.5-bound toxic trace elements. These risks can be mitigated with the introduction of low-carbon and active modes of transport in place of internal combustion engines and the use of indoor air pollution exposure mitigation devices.

Laser printers are one of the common indoor equipment in schools, offices, and various other places. Laser printers have recently been identified as a potential source of indoor air pollution. This study examines the characteristics of ultrafine particles (UFPs, diameter

Spent lithium-ion batteries (LIBs) are increasingly generated due to their widespread use for various energy-related applications. Spent LIBs contain several valuable metals including cobalt (Co) and lithium (Li) whose supply cannot be sustained in the long-term in view of their increased demand. To avoid environmental pollution and recover valuable metals, recycling of spent LIBs is widely explored using different methods. Bioleaching (biohydrometallurgy), an environmentally benign process, is receiving increased attention in recent years since it utilizes suitable microorganisms for selective leaching of Co and Li from spent LIBs and is cost-effective. A comprehensive and critical analysis of recent studies on the performance of various microbial agents for the extraction of Co and Li from the solid matrix of spent LIBs would help for development of novel and practical strategies for effective extraction of precious metals from spent LIBs. Specifically, this review focuses on the current advancements in the application of microbial agents namely bacteria (e.g., Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans) and fungi (e.g., Aspergillus niger) for the recovery of Co and Li from spent LIBs. Both bacterial and fungal leaching are effective for metal dissolution from spent LIBs. Among the two valuable metals, the dissolution rate of Li is higher than Co. The key metabolites which drive the bacterial leaching include sulfuric acid, while citric acid, gluconic acid and oxalic acid are the dominant metabolites in fungal leaching. The bioleaching performance depends on both biotic (microbial agents) and abiotic factors (pH, pulp density, dissolved oxygen level and temperature). The major biochemical mechanisms which contribute to metal dissolution include acidolysis, redoxolysis and complexolysis. In most cases, the shrinking core model is suitable to describe the bioleaching kinetics. Biological-based methods (e.g., bioprecipitation) can be applied for metal recovery from the bioleaching solution. There are several potential operational challenges and knowledge gaps which should be addressed in future studies to scale-up the bioleaching process. Overall, this review is of importance from the perspective of development of highly efficient and sustainable bioleaching processes for optimum resource recovery of Co and Li from spent LIBs, and conservation of natural resources to achieve circular economy. [ABSTRACT FROM AUTHOR]