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The transfer of chalcophile metals across the continental lithosphere has been traditionally modeled based on their chemical equilibrium partitioning in sulfide liquids and silicate magmas. Here, we report a suite of Ni-Fe-Cu sulfide droplets across a trans-lithospheric magmatic network linking the subcontinental lithospheric mantle to the overlying continental crust. Petrographic characteristics and numerical calculations both support that the sulfide droplets were mechanically scavenged from the mantle source during partial melting and transported upwards by alkaline magmas rising through the continental lithosphere. Nanoscale investigation by high-resolution transmission electron microscopy (HR-TEM) documents the presence of galena (PbS) nanoinclusions within the sulfide droplets that are involved in the mantle-to-crust magma route. The galena nanoinclusions show a range of microstructural features that are inconsistent with a derivation of PbS by exsolution from the solid products of the Ni-Fe-Cu sulfide liquid. It is argued that galena nanoinclusions crystallized from a precursor Pb(-Cu)-rich nanomelt, which was originally immiscible within the sulfide liquid even at Pb concentrations largely below those required for attaining galena saturation. We suggest that evidence of immiscibility between metal-rich nanomelts and sulfide liquids during magma transport would disrupt the classical way by which metal flux and ore genesis are interpreted, hinting for mechanical transfer of nanophases as a key mechanism for sourcing the amounts of mantle-derived metals that can be concentrated in the crust.

Positive Eu and Sr anomalies in primitive lavas and melt inclusions are commonly interpreted as reflecting the presence of plagioclase-bearing oceanic crust in their source. These “ghost plagioclase” signatures document the impact of subduction recycling on the heterogeneity of the convective mantle (marble-cake model). Yet, their interpretations rely on the paradigmatic assumption that partial melts are generated in chemical equilibrium with their source, which is questioned by theoretical and experimental considerations. Diffusion rates of trace elements in mantle minerals are relatively slow compared to melt transport rates, suggesting that disequilibrium is the rule rather than the exception during mantle melting. Nonetheless, in the absence of direct field evidence, the paradigm has remained. Here we report the first natural evidence of Eu anomalies developed kinetically in mantle peridotite clinopyroxene [1]. Extreme REE heterogeneity was observed in high-temperature (up to 1165°C) basalt-hosted xenoliths. Single <1-mm clinopyroxene crystals exhibit strong core-to-rim LREE fractionation accompanied by transient Eu anomalies [(Eu/Eu*)N = 0.8-1.8]. Eu anomalies first increase with LREE enrichment and then markedly decreases with further enrichment towards the rims, which cannot be explained by chromatographic re-equilibration and require a kinetic process. Numerical modelling shows that diffusional fractionation between clinopyroxene and melt both devoid of Eu anomalies can generate the observed Eu anomalies without requiring plagioclase. We demonstrate that such anomalies may develop where low-degree, LREE-enriched melts percolate in the presence of small amounts of fast-diffusing Eu2+, which is compatible with temperatures, redox conditions and transport timescales in MORB and OIB sources. We particularly envisage that this is likely to occur in the deep, volatile-induced melting regime beneath mid-ocean ridges. In the absence of converging lines of evidence

The formation of primary arc basalts during subduction is attributed to the high-pressure dehydration of serpentinite (deserpentinisation), which generates fluids that flux and melt the overlying mantle wedge. These basalts are more oxidised than their mid-ocean ridge counterparts. At the slab surface of current subduction zones, these deserpentinisation fluids are intrinsically oxidised but, owing to the low sulphur content of subducted serpentinite, they only result in a low mantle-wedge oxidation rate, which cannot account for the oxidised source of arc basalts. Through a combination of natural observations and thermodynamic modelling, we show that infiltration of sediment-derived fluids can alter the oxidation capacity of deserpentinisation slab fluids, providing an explanation for the oxidised nature of arc volcanism. The deserpentinisation oxidation capacity is mainly influenced by the stability and abundance of dissolved oxidised aqueous species of redox-sensitive elements, notably sulphate, rather than the oxidation state of the sediment. Infiltration of CH4-bearing fluids derived from graphite-bearing sediment reduces the oxidant capacity of deserpentinisation fluids, leading to a relatively low fO2 observed in natural metaperidotite. On the other hand, infiltration of sulphate-CO2-bearing, sediment-derived fluids results in a high oxidation capacity of deserpentinisation fluids in cold and hot subduction zones, leading to a global mantle-wedge oxidation rate of 3.5 km3·yr¿1. Therefore, these slab fluids can oxidize the mantle wedge at a rate similar to that of arc basalt generation, explaining the oxidised nature of arc volcanism. The findings suggest that sediment-derived fluids (and potentially also fluids derived from the Altered Oceanic Crust) can significantly modulate the oxidation capacity of deserpentinisation slab fluids, highlighting the importance of slab fluid-mixing in the volatile recycling in the subduction zone system.

The major apatite ores from the Central High-Atlas Mesozoic alkaline intrusive complexes (Morocco) have been investigated through integrated field, petrographic, and geochemical studies (Ouabid et al., 2021). The apatite deposits occur as veins ¿few mm to several cm thick¿, spatially associated with syenite bodies. Gem-quality crystals of apatite¿up to 15 cm in size (e.g., Ouabid and Raji, 2023)¿, are associated with albite, clinopyroxene (hedenbergite¿augite¿diopside), amphibole (hornblende¿edenite¿actinolite), K-feldspar, quartz, magnetite, titanite, epidote, prehnite, and calcite. Two types of apatite have been distinguished according to their halogen contents including F- and Cl-apatites. Both types are enriched in rare earth elements (0.5-2 wt.% ¿REE) and have major¿trace element contents consistent with a magmatic origin, corroborated by the chemical similarity with accessory apatite in the host alkaline intrusions, as well as with other reference igneous apatites. Though, hydrothermal fluids percolating through country sedimentary rocks were also implicated, as revealed by the striking Na enrichment observed in the Cl-rich apatites, likely inherited from Triassic evaporites, showing close spatial relationships with the alkaline intrusions.

Evidence of Paleogene subduction in the Western Mediterranean is scattered throughout high-pressure (HP) events in polymetamorphic basement terrains of disputed and differing provenance exposed along the margins of deep basins formed during Miocene to Quaternary slab retreat. The reconstruction of the original subduction geometry is often hindered by pervasive Miocene high-temperature (HT) ductile overprinting of earlier HP events. Here, we report rutile U¿Pb ages, EBSD-determined microstructures and thermodynamic modeling in eclogites from the upper-plate domain of the Betics (Ojén nappe, Alpujárride complex). These data show that the Ojén eclogite peak mineral assemblage formed during HP (1.3 ±0.15 GPa) and HT (700 ± 25 °C) ductile flow in the early Oligocene (30 ± 2.5 Ma). We interpret this event as a collisional phase linking Ojén eclogites to the Paleogene subduction of the western Tethys. Contrasting P¿T gradients of eclogites and arc volcanism between Corsica¿Calabria and Kabylies¿Betics point to a highly segmented orogenic system. NW¿SE-oriented transform faults separated a continental collision domain to the South from an oceanic subduction to the NE, with two subducting slabs ¿Calabrian and Algerian¿ retreating respectively towards the E and SE. Early Eocene inversion of the European and Maghrebian margins and ensuing early Oligocene collision resulted in (U)HP¿HT metamorphism in the Alpujárride and Kabylies. This orogen underwent extensional collapse in the late Oligocene-Aquitanian, before further shortening and the intracrustal emplacement of the Ronda peridotite. The upper plate Ojén eclogites and orogenic peridotites drifted westwards following the retreating Betics¿Rif Tethys slab in the early Miocene, after transform collapse that induced HP subduction of the SE Iberian margin below the Alpujárrides.

Crustal recycling in the Earth’s mantle is fingerprinted by trace-element and isotopic proxies in oceanic basalts. Positive Eu and Sr anomalies in primitive lavas and melt inclusions that are not otherwise enriched in AlO are often interpreted as reflecting the presence of recycled, plagioclase-rich oceanic crust in their mantle source – referred to as “ghost plagioclase” signatures. Here, we report natural evidence of Eu anomalies and extreme crystal-scale heterogeneity developed kinetically in mantle peridotite clinopyroxene. Numerical modelling shows that diffusional fractionation between clinopyroxene and melts can account for this intra-crystal heterogeneity and generate Eu anomalies without requiring plagioclase. We demonstrate that kinetically induced Eu anomalies are likely to develop at temperatures, redox conditions and transport timescales compatible with the genesis of mid-ocean ridge and ocean island basalts. Our results show that, in the absence of converging lines of evidence such as radiogenic isotope data, ghost plagioclase signatures are not an unequivocal proxy for the presence of recycled crust in oceanic basalt sources.

Cenozoic extension in the Western Mediterranean has been related to the dynamics of back-arc domains. Although, in most of its orogenic belts extension propagated into the fore-arc nappe domains. Here we revisit the structure, metamorphism and radiometric ages of the Tunisian Tell, where HP/LT rocks (350°C at 0.8 GPa), were exhumed by the sequential activity of extensional detachments after heating and decompression (410°C¿440°C at 0.6¿0.3 GPa) in a plate convergent setting. Normal faults thinning the Tunisian Tell detached at two different crustal levels. The shallower one cuts down into the Atlas Mesozoic sequence, involving Tellian Triassic evaporites in the hanging-wall forming halokinetic structures in the Mejerda basin late Miocene. The deeper-detachment bounds metamorphic domes formed by marbles and metapsammites from the Atlas domain. Illite crystallinity on Triassic rocks shows epizonal to anchizonal values, at deep and intermediate structural depths of the Tell-Atlas nappe belt, respectively. New U-Pb 49.78 ± 1.28 Ma rutile ages from Tellian metabasites, together with existing phlogopite 23¿17 Ma K-Ar ages in Atlas marbles from the footwall of the deepest detachment, indicate a polymetamorphic evolution. The Tell rocks underthrusted the Kabylian flysch in the early Eocene. Further, early Miocene shortening thrusted the metabasites over lower-grade sediments, producing HP/LT metamorphism and ductile stretching at the base of the Atlas belt. The exhumation of midcrustal roots of Western Mediterranean nappe belts after tectonic shortening is a common feature related to tearing at the edges of the subduction systems and inboard delamination of their subcontinental lithospheric mantle.

Paleogeographic reconstructions of the Western Mediterranean are often based on the present location of sedimentary outcrops. However, most geodynamic and biogeographic models for the region have highlighted the importance of up-to-hundreds of km of horizontal displacements of the terrains forming the western Mediterranean orogenic arcs since the early Miocene until the Pliocene. Here we update the known paleogeographic evolution for the westernmost Mediterranean, considering published biogeographic and recent new geological constraints, including paleontological, stratigraphic, tectonic kinematic data, seismic reflection lines, lowtemperature thermochronological dating, detrital zircon age populations, among others. During the Burdigalian to Langhian the rocks of the Betic hinterland, corresponding to the Alboran domain, where exhumed in a forearc setting as far East as Mallorca, now located 450 to 700 km of their present outcrops. Those exhuming rocks floored sedimentary basins among an island archipelago. The land connection between Mallorca and Alboran domains continued until the Serravallian as attested by the shared fossils of vertebrate insular fauna and biogeographic data of different taxa including trap-door spiders, beetles and fresh-water planarians. The westward migration of the Alboran forearc archipelago and its overlying basins (currently forming the Betic intramontane and western Alboran basins) was concomitant to the Langhian to Tortonian opening of the Algero-Balearic back-arc basin and the retreat of the Betic-Rif subducted slab. At a smaller scale, the Granada supra-detachment intramontane basin moved > 100 km between the Tortonian and Present, implying that previously interpreted, emerged domains, like the Sierra Nevada island where either inexistent or in a different location during the Tortonian. Sediment interpreted to represent marine gateways around and through the Alboran archipelago in the westernmost Mediterranean, may have being partial

Rodingites are formed through hydrothermal alteration of mafic and felsic lithologies induced by reactive fluids from serpentinization of enclosing peridotites in slow MOR, continental passive margins, or subduction zones. During rodingitization, highly reducing fluids promote metasomatic reactions that replace primary assemblage of oceanic crustal rocks with Ca-Al silicates, Ca-Mg silicates, and chlorite. Similar metasomatic reactions between metamafic layers and enclosing ultramafic rocks also contribute to the lithological and compositional heterogeneity of subduction mélanges, which can influence the composition of slab fluids and favor the deep transport of volatiles in subduction zones. Despite their possible contribution to mass exchanges in subduction zones and to the geochemical signature of arc magmas, metamafic rocks formed by Ca-Mg metasomatism are often disregarded in global geochemical balances. We report a detailed sulfur and selenium systematic in petrologically and geochemically well-characterized rodingites and reaction rims [1] in the Almirez massif (S Spain). The study aims to constrain the redox potential of meta-(ultra) mafic lithologies produced by Ca-Mg metasomatic processes compared to that of altered oceanic crust (AOC) and MORB-derived eclogites. Selenium is a redox-sensitive element that mobilizes when oxidative slab fluids dissolve sulfides. Subsequently, recrystallizing sulfides within the metamorphic assemblage scavenge reduced, isotopically lighter Se. As such, redistributed Se with a large isotopic range traces repeated cycles of sulfide reworking within the subducted crust by episodic, highly oxidized fluid pulses from underlying slab serpentinite [2]. Our preliminary results in Almirez show that metarodingites and associated metamorphic rocks are strongly depleted in Se-S relative to eclogites and MORBs, while reaction rims are commonly enriched in these elements. The Se-S systematic is in contrast to much higher Se-S contents prev

We report an integrated field, petrographic, and geochemical study of three major Cretaceous carbonatite annular occurrences from the Oulad Dlim massif (Adrar Souttouf, NW margin of the West African Craton, south Morocco): Twihinate, Lamlaga, and Lahjayra. These complexes are commonly considered isolated carbonatite structures partially to completely overlain by silica breccias and iron oxide rocks. The carbonatites include two calcio‑carbonatites facies with distinct textural features and bulk-rock and mineral geochemistry: the “white” facies present characteristics consistent with a primary magmatic stage, while the “grey” facies likely resulted from hydrothermal alteration of the white carbonatites. We provide evidence that the annular structures include ultrapotassic alkaline syenites, probably derived from the same primary carbonated/silicated melt as the carbonatites, after partial melting of a K-rich lithospheric mantle source. The overlying silica breccias retain sandstone/quartzite-like stratifications, whereas their trace element signature is analogous to those of the carbonatites, suggesting that they were subjected to intense hydrothermal activity during carbonatite magmas emplacement. The iron-oxide rocks are chemically comparable to worldwide references of carbonatite-related laterite profiles, indicating a similar origin. All subsolidus (hydrothermal and weathering) alteration stages were accompanied by significant REE-Nb concentration resulting in high-grade deposits of monazite, synchysite, apatite and pyrochlore. Like other peri-Atlantic alkaline occurrences, the investigated Cretaceous alkaline‑carbonatite occurrences are likely related to the Atlantic Ocean opening and reactivation of pre-existing Pan-African tectonic structures.

The Sabzevar ophiolite is the most extensive and best-exposed section of oceanic lithosphere in NE Iran. In this study, we examined the mantle section of the eastern part of the Sabzevar ophiolite, where mantle peridotites are the most widespread rock type and are crosscut by pyroxenite veins and mafic dykes. Major and trace element compositions (minerals and whole-rock) of lherzolites are akin to those of abyssal peridotites from mid-ocean ridges (MOR), whereas those of harzburgites evidence formation in a supra-subduction zone (SSZ) setting. Rare-earth element (REE) patterns of whole-rock and clinopyroxene of lherzolites and harzburgites suggest polybaric melting, with initial melting in the garnet peridotite field (~5–6%), followed by ~5–15% melting for lherzolites and ~10–20% for harzburgites in the spinel peridotite field. Harzburgites show LREE enrichment incompatible with partial melting models, indicating significant interaction with SSZ-related melts, whereas analysed lherzolites experienced limited melt-rock interaction. Pyroxene dissolution and olivine precipitation in residual peridotites resulting from reaction with island arc tholeiite and/or boninite melts led to the formation of dunites. These melts eventually intruded as dykes and veins in the mantle and crustal sections of the ophiolite. In addition, boninite melts are inferred to be responsible for forming olivine pyroxenite veins within the harzburgites. We conclude that the mantle section of the Sabzevar ophiolite formed in an intra-oceanic arc setting and experienced a geochemical evolution from a MOR-like to SSZ setting. The intra-oceanic subduction of the Neotethys oceanic lithosphere and shifting conditions of melting during the development of subduction beneath the incipient island arc were responsible for the geochemical heterogeneity of mantle peridotites and the generation of SSZ-related magmas within the Sabzevar oceanic lithosphere.

High-pressure dehydration of serpentinite during subduction generates fluids that flux and melt the overlying mantle wedge, forming primary arc basalts. These basalts are substantially more oxidized than their mid-ocean ridge counterparts. At the slab surface of current subduction zones, these deserpentinization fluids are intrinsically oxidized, but, owing to the low sulfur content of subducted serpentinite, they only result in a low mantle wedge oxidation rate, which cannot account for the oxidized source of arc basalts. Here we show that infiltration of sediment-derived fluids modulates and can drastically change the oxidation capacity of deserpentinization slab fluids. The modulation of the deserpentinization oxidation capacity mostly depends on the stability and abundance of dissolved oxidized aqueous species of redox-sensitive elements—notably sulfate—and not solely on the oxidation state of the sediment. Infiltration of CH-bearing fluids derived from graphite-bearing sediment reduces the intrinsically high oxidant capacity of deserpentinization fluids, explaining the relatively low fO observed in natural metaperidotite. Infiltration of sulfate-CO-bearing, sediment-derived fluids—prevalent in modern subduction zones—generates deserpentinization fluids with a high oxidation capacity in cold and hot subduction zones, resulting in a global mantle wedge oxidation rate of 3.5 km yr. Such slab fluids will oxidize the mantle wedge at a rate similar to that of arc-basalt generation and thus account for the oxidized nature of arc volcanism.

The transfer of chalcophile metals across the continental lithosphere has been traditionally modeled based on their chemical equilibrium partitioning in sulfide liquids and silicate magmas. Here, we report a suite of Ni-Fe-Cu sulfide droplets across a trans-lithospheric magmatic network linking the subcontinental lithospheric mantle to the overlying continental crust. Petrographic characteristics and numerical calculations both support that the sulfide droplets were mechanically scavenged from the mantle source during partial melting and transported upwards by alkaline magmas rising through the continental lithosphere. Nanoscale investigation by high-resolution transmission electron microscopy (HR-TEM) documents the presence of galena (PbS) nanoinclusions within the sulfide droplets that are involved in the mantle-to-crust magma route. The galena nanoinclusions show a range of microstructural features that are inconsistent with a derivation of PbS by exsolution from the solid products of the Ni-Fe-Cu sulfide liquid. It is argued that galena nanoinclusions crystallized from a precursor Pb(-Cu)-rich nanomelt, which was originally immiscible within the sulfide liquid even at Pb concentrations largely below those required for attaining galena saturation. We suggest that evidence of immiscibility between metal-rich nanomelts and sulfide liquids during magma transport would disrupt the classical way by which metal flux and ore genesis are interpreted, hinting for mechanical transfer of nanophases as a key mechanism for sourcing the amounts of mantle-derived metals that can be concentrated in the crust.

The Moroccan Meseta constitutes a key peri-Gondwanan and Variscan terranes linking the branches between the SW European Cadomian and the north West African Craton (WAC), anti-Atlas metacratonic Pan-African terranes. While the Paleozoic sedimentary and tectono-magmatic record of the different blocks of the Moroccan Meseta is well documented, there is still a lack of systematic absolute ages and geochemical isotopic data of putative Precambrian basement rocks from different Meseta blocks. Here we present new U–Pb zircon ages, petrological, and whole-rock major, trace, and Sr–Nd–Pb isotope geochemical data of (meta)igneous rocks from the Bou-Acila, Jbel-Hadid, Goaïda, Midelt and El Jadida, constituting the basement of two main Moroccan Meseta blocks. Basaltic rocks, unconformably overlain by Cambrian platform sediments, in the Western Meseta Bou-Acila basement yield U–Pb zircon age of c. 581 ± 9 Ma that unveils the existence of Ediacaran magmatism in the Moroccan basement of this area. Alleged early Paleozoic mafic sills in the metasedimentary series of the Midelt Sidi-Saïd yield U–Pb zircon ages of c. 554 ± 12 Ma reveals, for the first time, the presence of Ediacaran magmatism in the basement of the Moroccan Eastern Meseta. U–Pb zircon ages in the Jbel-Hadid and El Jadida rhyolitic basement rocks (c. 604–543 Ma and c. 575–559 Ma, respectively), as well as granitic pebbles (c. 573 Ma) in the Goaïda Cambrian limestone series, further attest for coeval Ediacaran magmatism in the basement of Western Meseta. The geochemical affinity of the investigated Moroccan Meseta Ediacaran magmatic rocks is mainly metaluminous, low-K tholeiites for mafic rocks, and peraluminous, high-K calc-alkaline for the felsic rocks, consistent with a back-arc tectonic setting. Geochemical and Sr–Nd–Pb isotopic data indicate that the source of the Moroccan Meseta Ediacaran magmatism involved sources from the depleted mantle and old WAC crustal basement. Altogether, these data show widespread Ediac

[EN] Spinel peridotite xenoliths (one plagioclase-bearing) hosted in alkaline basalts from Tallante (southeast Spain) record the mineralogical and geochemical fingerprint of the subcontinental lithospheric mantle (SCLM) evolution beneath the southern Iberian margin. Mantle metasomatism in fertile lherzolites caused the crystallization of clinopyroxene + orthopyroxene + spinel clusters through the percolation of Miocene subalkaline melts during the westward migration of the subduction front in the western Mediterranean. In the Pliocene, heat and volatiles provided by alkaline host-magmas triggered very low melting degrees of metasomatic pyroxene-spinel assemblages, producing melt quenched to silicate glass and reactive spongy coronae around clinopyroxene and spinel. Refertilization of the Tallante peridotites induced the precipitation of base-metal sulfides (BMS) included in metasomatic clino and orthopyroxene. These sulfides consist of pentlandite ± chalcopyrite ± bornite aggregates with homogeneous composition in terms of major elements (Ni, Fe, Cu) and semi-metals (Se, As, Te, Sb, Bi), but with wide variability of platinum-group elements (PGE) fractionation (0.14 < PdN/IrN < 30.74). Heterogeneous PGE signatures, as well as the presence of euhedral Pt-Pd-Sn-rich platinum-group minerals (PGM) and/or Auparticles within BMS, cannot be explained by conventional models of chalcophile partitioning from sulfide melt. Alternatively, we suggest that they reflect the incorporation of distinct populations of BMS, PGM, and metal nanoparticles (especially of Pt, Pd, and Au) during mantle melting and/or melt percolation. Therefore, we conclude that Miocene subalkaline melts released by asthenosphere upwelling upon slab tearing of the Iberian continental margin effectively stored metals in metasomatized domains of this sector of the SCLM. Remarkably high Au concentrations in Tallante BMS (median 1.78 ppm) support that these metasomatized domains provided a fertile source of metal

Field observations within the Atg-serpentinite domain of the subducted ultramafic massif from Cerro del Almirez (SE Spain) reveal the existence of two generations of abundant olivine-rich veins formed as open, mixed mode and shear fractures during prograde metamorphism. Type I veins were synchronous with the development of the serpentinite main foliation (S) and shearing, whereas Type II veins post-date the S surfaces. These structural relationships indicate that, while the Atg-serpentinites underwent ductile plastic deformation at temperatures of 450°-600 °C and pressures of 0.7–1.7 GPa, they also experienced punctuated brittle behaviour events. The brittle fractures were most likely due to fluid overpressures formed by release of HO during the brucite breakdown reaction for the case of Type I veins (2 vol % HO) and due to a combination of minor dehydration reactions related to continuous compositional and structural changes in antigorite (0.3 vol % HO) for Type II veins. Type II olivine-rich veins were formed by brittle failure in a well-defined paleo-stress field and were not significantly deformed after their formation. Comparison of the principal paleo-stress orientation inferred from Type II veins with those formed at peak metamorphic conditions in the ultramafic rocks at Cerro del Almirez shows a relative switch in the orientation of the maximum and minimum principal paleo-stress axes. These relative changes can be attributed to the cyclic evolution of shear stress, fluid pressure and fault-fracture permeability allowing for stress reversal.

Single-lithology and composite xenoliths from Mindszentkálla (Bakony-Balaton Highland Volcanic Field) in the Carpathian-Pannonian region record geochemical evolution of the subcontinental lithospheric mantle. The dominant single-lithology xenoliths are orthopyroxene-rich (22 vol% on average) harzburgites. Three composite xenoliths contain either two or more domains including dunite, olivine-orthopyroxenite, orthopyroxenite, apatite-bearing websterite and amphibole-phlogopite-bearing vein. The presence of different lithologies is a result of at least two metasomatic events that affected the lithospheric mantle. The first event resulted in orthopyroxene enrichment thus formed harzburgitic mantle volumes (Group I xenoliths). Major- and trace element distributions of the bulk harzburgites differ from the geochemical trends expected in residues of mantle melting. In contrast, petrographic and geochemical attributes suggest that the harzburgite was formed by silica-rich melt - peridotitic wall rock interactions in a supra-subduction zone. Within the Group I xenoliths, two subgroups were identified based on the presence or lack of enrichment in U, Pb and Sr. Since these elements are fluid mobile, their enrichment in certain Group I xenoliths indicate reaction with a subduction-related fluid, subsequent to the harzburgite formation. The effect of a second event overprints the features of the Group I xenoliths and is evidenced in all domains of two composite xenoliths (Group II xenoliths). The general geochemical character involves enrichment of basaltic major and minor elements (Fe, Mn, Ti, Ca) in the rock-forming minerals and convex-upward rare earth element (REE) patterns in clinopyroxenes. We suggest that the different domains represent reaction products with variably evolved basaltic melts of a single magmatic event. The tectonic background to the formation of Group I xenoliths is likely linked to the subduction of oceanic crust during the Mesozoic–Paleogene. This happe

Interactions between meteoric water and ultramafic rocks in the Oman Ophiolite generate waters of variable physicochemical characteristics. The discharge of these waters forms complex alkaline pool networks, in which mineral precipitation is triggered by mixing, evaporation, and uptake of atmospheric CO2. A systematic and co-localized sampling of waters and solids in two individual spring sites allowed us to determine the saturation state of a range of minerals and correlate them to the different water and precipitate types. We subdivided the waters of the spring sites into three distinctive types: i) Mg-type; moderately alkaline (7.911.6), Ca2+–OH−-rich waters, and iii) Mix-type; alkaline to hyperalkaline (9.6 < pH < 11.5) waters with intermediate chemical composition. We first report the occurrence of hydrated magnesium (hydroxy-) carbonate phases in Mg-type waters. Nesquehonite forms in these waters via evaporation and transforms into dypingite and hydromagnesite under CO2-rich conditions. In Ca-type waters, the coupling of atmospheric CO2 uptake with evaporation leads to the formation of a calcitic crystalline crust on the air-water interface. The crusts are aragonite- and brucite-bearing, where Mg-type and Ca-type waters discharge and vigorously mix at the same pool. Unlike the Mg-type and Ca-type waters, the pools of Mix-type waters host massive aragonite-dominated deposits due to high Mg/Ca ratio that favors the growth of aragonite over calcite. The hydrodynamics during mixing spatially control brucite precipitation and restrict its formation and accumulation around specific mixing zones, where a continuous supply of Mg of inflowing Mg-type waters takes place. Crystal morphologies record the effect on the values of supersaturation and supersaturation rates in the pools due to mixing processes, evaporation and CO2 uptake. In Ca-type waters, CO2 uptake and evaporation dictate the textural charact

The Egéré terrane (Central Hoggar, South Algeria) includes mafic eclogite lenses boudinaged in metapelitic rocks with high-pressure relicts. These metapelites show textural records of partial melting, mainly primary melt inclusions enclosed in garnet crystals and later crystallized as "nanogranitoids."Garnet porphyroblasts also contain inclusions of quartz, kyanite, phengite, biotite, staurolite, and rutile and show a smoothed prograde zoning with a Mn bell-shaped profile. The peak high-pressure metamorphic assemblage consists of garnet, kyanite, phengite (Si up to 6.36), quartz, rutile, ±ilmenite, ±feldspars, and melt. Phengite has partially transformed into fine-grained aggregates of biotite, plagioclase, and K-feldspar, a microstructure interpreted as resulting from a dehydration melting during exhumation. Phengite breakdown, along with other retrograde reactions, produced a late paragenesis with biotite, plagioclase, K-feldspar, quartz, almandine-rich garnet, ±sillimanite, ±staurolite, ±muscovite, and ilmenite. The thermodynamic modeling of P-T pseudosections allows us to constrain various steps of the metamorphic history: beginning of the garnet growth at 4.0 kbar and ~600 °C during prograde metamorphism; pressure peak at 14-20 kbar; temperature peak at 800-820 °C; formation of the last assemblage at 6.0-5.5 kbar and 725-685 °C. Partial melting likely started during the prograde path when crossing the H2O-saturated solidus, at T ≥ 650-670 °C and P ≥ 10 kbar, continued upon heating, up to the peak conditions, as well as during decompression. This evolution is interpreted in terms of subduction of the continental crust to mantle depths, followed by an exhumation through a clockwise P-T path during the Pan-African orogeny. The Egéré metapelites are relatively well-preserved eclogite-facies rocks, contain inclusions of "nanogranitoids"hitherto very little known in eclogite-facies metamorphic rocks, and represent an unusual trace of subduction within a Neoproterozoi

The composition of the intrusive gabbroic lower oceanic crust remains poorly characterized in comparison to the extrusive portion of the oceanic crust, especially for intermediate-fast spreading mid-ocean ridges. This is a consequence of limited exposures of extant lower oceanic crust or ophiolites similar to mid-ocean ridge crust. One of the best analogues for mid-ocean ridge crust is the southern Samail ophiolite that formed during a period of rapid seafloor spreading above a nascent subduction zone. Here, we focus on the geochemical stratigraphy (whole rock and mineral major and trace element compositions) of the 5,200 m-thick, lower crustal, Wadi Khafifah section of the Wadin Tayin massif in the southern Samail (Oman) ophiolite. Gabbros from the lowermost 3,700 m of this section (the “lower gabbros”) show no systematic changes in composition with height above the Mantle Transition Zone. In contrast, gabbros from the uppermost 1,500 m (the “upper gabbros”) display marked increases in incompatible trace element concentration with increasing height. Liquids in equilibrium with the lower gabbros have major and trace element compositions that overlap with those measured in the upper gabbros and sheeted dikes. Upper gabbros preserve mineral cores with primitive major element compositions that overlap with the range of lower gabbros; however, upper gabbro whole rock compositions are significantly more enriched in incompatible trace elements relative to the lower gabbros. Our data reveal that the upper gabbros are a composite of accumulated minerals derived from primitive melts and a large fraction of evolved melts derived from the fractionation of the lower gabbros. We propose a new “Full Sheeted Sills” model for the lower oceanic crust in which primitive magmas from the mantle are emplaced throughout the lower crust and crystallized in situ. After diking events, evolved magmas leave the lower gabbros and replenish the upper gabbros, thereby contributing to the higher

We study the structure of the Llevant ranges in Mallorca with special emphasis on the Cenozoic extensional evolution of the island, which we integrate in a new geodynamic model for the Westernmost Mediterranean. Mallorca underwent two Cenozoic rifting phases in the Oligocene and Serravallian, before and after the development of its Foreland Thrust Belt (FTB). The first extensional event produced Oligocene semigrabens (≈29–23 Ma) that were inverted during the Early-Middle Miocene (19–14 Ma) WNW-directed FTB development. The second rifting event produced the extensional collapse of the Mallorca FTB during the Serravallian (≈14–11 Ma). This later rifting was polyphasic, with two orthogonal extensional systems, producing first NE-SW, and then NW-SE extension. The Oligocene extension affected a major part of the Western Mediterranean, opening the Liguro-Provençal and other basins after the collapse of the Palaeogene AlKaPeCa orogen, and Mallorca, its former hinterland. Continued plate convergence nucleated a new subduction system in the Early Miocene that initiated along the Ibiza transform, producing the Mallorca WNW-directed FTB and subduction of the South-East Iberian passive margin. This process individualized the Betic-Rif slab and initiated its westward retreat. Serravallian extension occurred at the northern edge of the subduction system coeval to the Algero-Balearic basin opening. Extension initiated toward the SW direction of slab tearing and later rotated to a NW-SE direction, probably in response to flexural and isostatic rebound. Through these processes the Alboran domain archipelago was driven toward the southwest until the Late Miocene, contributing to the present isolation of Mallorca from its Betic hinterland.