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Based on multiple linear regression (MLR) models, we estimated the PM2.5 at Seoul using a number of aerosol optical depth (AOD) values obtained from ground-based and satellite remote sensing observations. To construct the MLR model, we consider various parameters related to the ambient meteorology and air quality. In general, all AOD values resulted in the high quality of PM2.5 estimation through the MLR method: mostly correlation coefficients >~0.8. Among various polar-orbit satellite AODs, AOD values from the MODIS measurement contribute to better PM2.5 estimation. We also found that the quality of estimated PM2.5 shows some seasonal variation; the estimated PM2.5 values consistently have the highest correlation with in situ PM2.5 in autumn, but are not well established in winter, probably due to the difficulty of AOD retrieval in the winter condition. MLR modeling using spectral AOD values from the ground-based measurements revealed that the accuracy of PM2.5 estimation does not depend on the selected wavelength. Although all AOD values used in this study resulted in a reasonable accuracy range of PM2.5 estimation, our analyses of the difference in estimated PM2.5 reveal the importance of utilizing the proper AOD for the best quality of PM2.5 estimation. [ABSTRACT FROM AUTHOR]

Cities represent a key space for our sustainable trajectory in a changing environment, and our society is steadily embracing urban green space for its role in mitigating heatwaves and anthropogenic CO2 emissions. This study reports two-year surface fluxes of energy and CO2 measured via the eddy covariance method in an artificially constructed urban forest to examine the impact of urban forests on air temperature and net CO2 exchange. The urban forest site shows typical seasonal patterns of forest canopies with the seasonal march of the East Asian summer monsoon. Our analysis indicates that the urban forest reduces both the warming trend and urban heat island intensity compared to the adjacent high-rise urban areas and that photosynthetic carbon uptake is large despite relatively small tree density and leaf area index. During the significant drought period in the second year, gross primary production and evapotranspiration decreased, but their reduction was not as significant as those in natural forest canopies. We speculate that forest management practices, such as artificial irrigation and fertilization, enhance vegetation activity. We also stipulate that ecosystem respiration in urban forests is more pronounced than typical natural forests in a similar climate zone. This can be attributed to the substantial amount of soil organic carbon available due to intensive historical soil use and soil transplantation during forest construction, as well as relatively warmer temperatures in urban heat domes. Our observational study also indicates the need for caution in soil management for less CO2 emissions in urban areas. [ABSTRACT FROM AUTHOR]

Accurate and consistent monitoring of anthropogenic combustion is imperative because of its significant health and environmental impacts, especially at city-to-regional scale. Here, we assess the performance of the Copernicus Atmosphere Monitoring Service (CAMS) global prediction system using measurements from aircraft, ground sites, and ships during the Korea-United States Air Quality (KORUS-AQ) field study in May to June 2016. Our evaluation focuses on CAMS CO and CO2 analyses as well as two higher-resolution forecasts (16 and 9 km horizontal resolution) to assess their capability in predicting combustion signatures over east Asia. Our results show a slight overestimation of CAMS CO2 with a mean bias against airborne CO2 measurements of 2.2, 0.7, and 0.3 ppmv for 16 and 9 km CO2 forecasts, and analyses, respectively. The positive CO2 mean bias in the 16 km forecast appears to be consistent across the vertical profile of the measurements. In contrast, we find a moderate underestimation of CAMS CO with an overall bias against airborne CO measurements of -19.2 (16 km), -16.7 (9 km), and -20.7 ppbv (analysis). This negative CO mean bias is mostly seen below 750 hPa for all three forecast/analysis configurations. Despite these biases, CAMS shows a remarkable agreement with observed enhancement ratios of CO with CO2 over the Seoul metropolitan area and over the West (Yellow) Sea, where east Asian outflows were sampled during the study period. More efficient combustion is observed over Seoul (dCO = dCO2 = 9 ppbv ppmv-1) compared to theWest Sea (dCO=dCO2 = 28 ppbv ppmv-1). This "combustion signature contrast" is consistent with previous studies in these two regions. CAMS captured this difference in enhancement ratios (Seoul: 8-12 ppbv ppmv-1, the West Sea: ~30 ppbv ppmv-1) regardless of forecast/analysis configurations. The correlation of CAMS CO bias with CO2 bias is relatively high over these two regions (Seoul: 0.64-0.90, the West Sea: ~0:80) suggesting that the contrast captured by CAMS may be dominated by anthropogenic emission ratios used in CAMS. However, CAMS shows poorer performance in terms of capturing local-to-urban CO and CO2 variability. Along with measurements at ground sites over the Korean Peninsula, CAMS produces too high CO and CO2 concentrations at the surface with steeper vertical gradients (~0:4 ppmv hPa-1 for CO2 and 3.5 ppbv hPa-1 for CO) in the morning samples than observed (0:25 ppmv hPa-1 for CO2 and 1.7 ppbv hPa-1 for CO), suggesting weaker boundary layer mixing in the model. Lastly, we find that the combination of CO analyses (i.e., improved initial condition) and use of finer resolution (9 km vs. 16 km) generally produces better forecasts. [ABSTRACT FROM AUTHOR]

Background: It is important to quantify changes in CO2 sources and sinks with land use and land cover change. In the last several decades, carbon sources and sinks in East Asia have been altered by intensive land cover changes due to rapid economic growth and related urbanization. To understand impact of urbanization on carbon cycle in the monsoon Asia, we analyze net CO2 exchanges for various land cover types across an urbanization gradient in Korea covering high-rise high-density residential, suburban, cropland, and subtropical forest areas. Results: Our analysis demonstrates that the urban residential and suburban areas are constant CO2 sources throughout the year (2.75 and 1.02 kg C m−2 year−1 at the urban and suburban sites), and the net CO2 emission indicate impacts of urban vegetation that responds to the seasonal progression of the monsoon. However, the total random uncertainties of measurement are much larger in the urban and suburban areas than at the nonurban sites, which can make it challenging to obtain accurate urban flux measurements. The cropland and forest sites are strong carbon sinks because of a double-cropping system and favorable climate conditions during the study period, respectively (− 0.73 and − 0.60 kg C m−2 year−1 at the cropland and forest sites, respectively). The urban area of high population density (15,000 persons km−2) shows a relatively weak CO2 emission rate per capita (0.7 t CO2 year−1 person−1), especially in winter because of a district heating system and smaller traffic volume. The suburban area shows larger net CO2 emissions per capita (4.9 t CO2 year−1 person−1) because of a high traffic volume, despite a smaller building fraction and population density (770 persons km−2). Conclusions: We show that in situ flux observation is challenging because of its larger random uncertainty and this larger uncertainty should be carefully considered in urban studies. Our findings indicate the important role of urban vegetation in the carbon balance and its interaction with the monsoon activity in East Asia. Urban planning in the monsoon Asia must consider interaction on change in the monsoon activity and urban structure and function for sustainable city in a changing climate. [ABSTRACT FROM AUTHOR]