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For a reliable and risk-free power source, dye-sensitized solar cells (DSSCs) have been the subject of much research. The method is very attractive because of its cheap manufacturing cost, environmentally friendly manufacture, and competitive efficiency. This study constructed a heterojunction as a photoanode for DSSCs using a combination of TiO2 and graphene using a wet chemical technique. According to the XRD and TEM findings, the graphene sheets consist of evenly wrapped spherical nanoparticles with diameters ranging from 30 to 40 nm, and the TiO2 exhibits a tetragonal (anatase) phase. It is common for anatase to have a bandgap energy of 3.15 eV for TiO2, whereas graphene/TiO2 has a bandgap energy of 2.77 eV. With a power conversion efficiency (PCE) of 7.2%, graphene/TiO2 DSSCs outperform cells based on pure TiO2 electrodes by a margin of 2.22%. In particular, graphene's ability to absorb solar light has the potential to improve the power conversion efficiency of DSSCs by increasing the light harvest of dye molecules. In addition, graphene/TiO2 had an average electron transit time of 1.765 ms while TiO2 had an average of 2.981 ms. The research shows that DSSCs' power conversion efficiency may be greatly improved by strategically adding graphene, which can be affordably synthesized, to certain layers of the photoanode. [ABSTRACT FROM AUTHOR]

In this paper, we obtain the generalized distance spectra of the graphs constructed by 19 unary and 21 binary graph operations of M-join type when the constituting graphs satisfy some conditions. Also, we deduce a result on the generalized distance spectrum of the double graph of a connected regular graph in the literature. As applications, we construct infinite families of generalized distance cospectral graphs. Also, we construct infinite families of distance (distance Laplacian, distance signless Laplacian) integral graphs. [ABSTRACT FROM AUTHOR]

In the field of modern dentistry, ideal three-dimensional positioning of dental implant with optimal prosthetic fit offers successful long-term outcomes. To achieve such accurate implant placement, presurgical evaluation of hard and soft tissue matters the most. Their efforts can be attained using various application programs such as digital imaging, implant planning software, laboratory- or computer-assisted surgical guides, and dynamic navigation approach. To overcome different opinions and choices regarding guided surgery, this article explains an evidence-based literature review to assess its various outcomes and allowing informed choices before using various guided surgical techniques based on its expectation and reality outcomes. This highlights a clinician's choice to guide his successful implant surgery without causing distress in the midway of treatment. An online search was done on PubMed/Medline database to bring in accuracy to the expertise. This review includes reference of publications from 2000 to 2019, which is related to promising outcomes using computer-assisted static or dynamic navigation system for the placement of implant. Out of these, 809 were related to the computer-guided implant placement. Relevant papers were chosen in accordance with the inclusion and exclusion criteria. This review article contemplates to reflect the fact that computer-guided approach is considered to offer more predictable, safer, and faster implant placement with the predetermined final prosthetic outfit. Thus, digital planning and placing of dental implants in the correct position keep escalating to a higher achievement levels than a classical freehand approach. Nevertheless, this guided surgical approach also holds some errors and risks, which must be identified and rectified., Competing Interests: There are no conflicts of interest., (Copyright: © 2020 Indian Society of Periodontology.)

Microperoxidase-11 (MP-11), a heme undecapeptide obtained by proteolytic digestion of cytochrome c, resembles peroxidase enzyme when its heme center is 5-coordinated with a vacant sixth coordination site. However, MP-11 always tends to aggregate in both solution and on surface and eventually forms the 6-coordinated heme. Thus, the present study investigates the immobilization strategy of MP-11 on nanoparticle surface in order to generate monomeric 5-coordinated MP-11 and make them as an efficient biocatalyst. The powerful surface-enhanced resonance Raman scattering (SERRS) technique is being employed to attain the detailed structural information of the catalytic site i.e., the heme center. The localized surface plasmon resonance (LSPR) tuned and 6-mercaptohexanoic acid (MHA) functionalized silver nanoparticles (Ag@MHA NPs) are used as Raman signal amplifier. The outcome of the SERRS study unambiguously portrays the existence of monomeric 5-coordinated MP-11 on Ag@MHA NPs surface. Here, Ag@MHA NPs plays a dual role of providing a platform to create monomeric 5-coordinated MP-11 and to load large number of MP-11 due to its high surface to volume ratio. Further, the electrostatic interaction between Ag@MHA NPs and MP-11 leads to instantaneous SERRS signal enhancement with a Raman enhancement factor (EFSERS) of 2.36×10(6). Langmuir adsorption isotherm has been employed for the adsorption of MP-11 on Ag@MHA NPs surface, which provides the real surface coverage (ΓS(*)) and equilibrium constant (K) value of 1.54nm and 5×10(11)M(-1). Furthermore, the peroxidase activity of MP-11 has been demonstrated through electrocatalytic oxygen reduction reaction., (Copyright © 2016 Elsevier B.V. All rights reserved.)