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1. Comment on the Use of Linear Free-Energy Slopes as Criteria for Distinguishing Hydride-Ion from Hydrogen-Atom Transfer in Reactions of Pyridine-Nucleotide Coenzymes.

Author

Kurz, Linda C. and Kurz, Joseph L.

Subjects
*CHEMICAL reactions, *PROTONS, *PYRIDINE nucleotides, *COENZYMES, *DEHYDROGENASES, *BIOCHEMISTRY
Abstract

For reductions by dihydropyridines, the slopes of plots of log k vs the standard reduction potential of the dihydropyridine are not direct indicators of whether the rate-determining step is hydride-ion or hydrogen-atom transfer. When there is no substituent effect on the reverse rate, those slopes are independent of mechanism and equal to about (30 mV)-1. [ABSTRACT FROM AUTHOR]

Published
1978
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