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In conjunction with global warming, the frequency and intensity of typhoons in the Pearl River Estuary region are increasing annually, and coastal cities are becoming more vulnerable to compound disasters triggered by upstream flooding, typhoons, and astronomical tide surges, seriously threatening the lives and properties of people in the delta region. Quantitative analysis of the degree of variability of each factor associated with a compound flood event and accurate assessment of the magnitude of the compound flood event strongly impact the efficacy of coastal city responses aimed at disaster prevention and damage mitigation. In this study, focused on the Pearl River Estuary area, the tide levels at Sanzao station, wind speeds at Macao station, and daily maximum the maximum daily flow at Sanshui and Makou stations spanning 30 years from 1988 to 2017 were used to characterize the flood magnitude, typhoon magnitude, and astronomical tide magnitude of compound flood events in the Pearl River Estuary area. Data were screened using the annual maximum method. Based on the generalized additive model (GAMLSS) and the time-varying copula function, the encounter combinations of composite flood events of different levels and their main controlling factors were investigated. The results show that: 1) the main factors influencing initiation and magnitude of composite flood events in the Pearl River estuary area are non-consistent sequences that display interdependence. The time-varying copula model constructed in this study is more suitable for studies of composite floods than the traditional constant parameter copula model. Copula models are most applicable to studies of the encountered characteristics of multiple elements contributing to compound flood events and are most in line with actual situations. 2) Compared with the joint return period of traditional constant copula parameters, the period of occurrence of typical compound flood events in the Pearl River Estuary from 1988 to 2017 continuously shortens with time, the probability of occurrence increases, and the probability of future occurrence of extreme compound flood events is strengthening. The trend in which the return period of compound flood events is shortening with higher grades is accelerating. 3) Compound flood events throughout the Pearl River estuary area are more affected by typhoons and astronomical tides and less affected by water flow. When the return period of the three factors is one in 5 years, water flow causes the smallest increase in the co-occurrence return period; i.e., the influence of astronomical tide and typhoon on the scale of upstream flooding, composite flood events of typhoon, and astronomical tide is proportionately larger. Thus, composite flood events in the Pearl River estuary area are mainly impacted by typhoons with higher wind speeds. When the return period of the three factors is one in 10, 20, and 50 years, the increase in the co-occurrence return period caused by flow changes the most; and when the return period of the three factors is one in 10, 20, and 50 years, the acceleration of the co-occurrence return period caused by flow is the largest. When the three factors have a larger return period, astronomical tide exerts proportionately greater influence on the scale of the composite flood event of upstream flood, typhoon, and astronomical tide.

Submarine groundwater discharge (SGD) contributes to the physical and chemical characters of coastal waters by discharging nutrients and contaminants, significantly impacting regional marine ecosystems and contributing to ocean chemical budgets. However, such groundwater discharge varies dramatically across scales and is often not comparable due to different model assumptions and field designs. We used a hydrologic model with integration of fundamental surface and subsurface processes to simulate the coastline level fresh SGD for the Crete Island in the Mediterranean Sea. The modeled hydrological processes suggested that fresh SGD substantially contributes to water flow entering the Mediterranean Sea (2.3 × 108 m3/yr), amounting to 31% of river discharge and 14% of precipitation. Spatially, fresh SGD varied from 2.4 m3/yr/m to 13.4 × 104 m3/yr/m, with an average of 2.6 × 103 m3/yr/m. The local maxima were commonly associated with river mouths reflecting larger hydraulic gradients and higher permeable structures. Temporally, fresh SGD was impacted by episodic precipitation in a delayed and prolonged pattern. We found that fresh SGD variability at the coastline segment level was compared to point measurements and fresh SGD magnitudes summered up to the catchment level were consistent with global products. Our results suggest the coupled surface–subsurface hydrologic modeling approach is a promising strategy to quantify and partition large-scale water budgets down to point observations that typically do not capture the full range of fresh SGD dynamics.

Sustainable management of blue and green water resources is vital for the stability and sustainability of watershed ecosystems. Although there has been extensive attention to blue water (BW) which is closely related to human beings, the relevance of green water (GW) for ecosystem security is typically disregarded in water resource evaluations. Specifically, there is a scarcity of comprehensive study on the detection and attribution of variation of blue and green water in the Dongjiang River Basin (DRB), an important source for regional water supply in the Guangdong-Hong Kong-Macao Greater Bay Area (GBA) of China. Here we assess the variations of BW and GW scarcity, quantify the impacts of climate change and land use change on BW and GW in DRB using a multi-water-flux calibrated Soil and Water Assessment Tool (SWAT). Results show that BW and green water storage (GWS) in DRB increased slowly with a rate of 0.14 and 0.015 mm a-1, respectively, while green water flow (GWF) decreased significantly at a rate of -0.21 mm a-1. The degree of BW and GW scarcity in DRB is low, and the per capita water resources in more than 80 % of DRB exceed 1700 m3 capita-1 a-1. Attribution results show that 88.0 %, 88.5 %, and 39.4 % of changes in BW , GWF , and GW S results from climate change, respectively. Both climate change and land use change have decrease BW , while climate change (land use change) decrease (increase) GW F in DRB. These findings can guide to optimize the allocation of blue and green water resources between upper reach and lower reach areas in DRB and further improve the understanding of blue and green water evolution patterns in humid regions. [ABSTRACT FROM AUTHOR]

Due to the excellent infrared transparency, low phonon energy, and high rare‐earth solubility, germanate laser glass has attracted much attention in mid‐infrared fiber lasers for potential coherent laser radar systems, optical detection, remote sensing, and laser surgery. However, radiation‐induce darkening often occurs in fiber lasers that operate in radiation environment. Here, we report a useful strategy to improve the radiation resistance by adding multivalence Bi ions and discuss its radiation resistance mechanism. In order to study the effect of valence states on the radiation resistance of barium gallo‐germanate glass, we adjust the valence states of Bi ions by heat treatment, the potential mechanism of which is discussed in detail based on the absorption, photoluminescence (PL), and Raman spectra. The absorption, electron paramagnetic resonance, and photoluminescence spectra have proved the interconversion of Bi ions between low and high valence, which inhibits the formation of Ge‐related electron center (GEC) and non‐bridging oxygen hole center defects in the irradiation process. In addition, the Bi3+ content increased by heat treatment is beneficial to serve as electron‐trapping centers in γ‐ray irradiation, thus further reducing the formation of GEC. This study provides a simple method to achieve Bi valence regulation, so as to improve the radiation resistance. [ABSTRACT FROM AUTHOR]