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1. Sedimentary Organics in Glen Torridon, Gale Crater, Mars: Results from the SAM Instrument Suite and Supporting Laboratory Analyses

Author

Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences, Millan, M, Williams, AJ, McAdam, AC, Eigenbrode, JL, Steele, A, Freissinet, C, Glavin, DP, Szopa, C, Buch, A, Summons, RE, Lewis, JMT, Wong, GM, House, CH, Sutter, B, McIntosh, O, Bryk, AB, Franz, HB, Pozarycki, C, Stern, JC, Navarro-Gonzalez, R, Archer, DP, Fox, V, Bennett, K, Teinturier, S, Malespin, C, Johnson, SS, Mahaffy, PR, Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences, Millan, M, Williams, AJ, McAdam, AC, Eigenbrode, JL, Steele, A, Freissinet, C, Glavin, DP, Szopa, C, Buch, A, Summons, RE, Lewis, JMT, Wong, GM, House, CH, Sutter, B, McIntosh, O, Bryk, AB, Franz, HB, Pozarycki, C, Stern, JC, Navarro-Gonzalez, R, Archer, DP, Fox, V, Bennett, K, Teinturier, S, Malespin, C, Johnson, SS, and Mahaffy, PR

Published
2023

2. Influence of Calcium Perchlorate on Organics under SAM‐like Pyrolysis Conditions: Constraints on the Nature of Martian Organics

Author

Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences, Millan, M, Szopa, C, Buch, A, Summons, RE, Navarro-Gonzalez, R, Mahaffy, PR, Johnson, SS, Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences, Millan, M, Szopa, C, Buch, A, Summons, RE, Navarro-Gonzalez, R, Mahaffy, PR, and Johnson, SS

Abstract

©2020. American Geophysical Union. All Rights Reserved. Most of the organics detected on Mars so far are aliphatic and aromatic organo-chlorine compounds. The smallest were first identified by the thermal treatment of the solid samples by Viking in 1976; although at the time, they were attributed to contamination. Since 2012, a larger variety of structures have been identified by the Sample Analysis at Mars experiment aboard the Curiosity rover. Evidence suggests that the chlorohydrocarbons formed during pyrolysis of sedimentary materials. Laboratory experiments show that heating of samples containing oxychlorines, such as chlorates (ClO3−) and perchlorates (ClO4−), along with organic matter present at Mars' surface is the logical source of these compounds. Nevertheless, this discovery of indigenous organic matter in the Mars regolith raises important questions: How do the oxychlorines influence the pyrolysis of organics? What are the organics precursors of the organo-chlorinated molecules detected on Mars? Is there a way to identify the parent molecules in a sample after pyrolysis? This paper presents the results of systematic laboratory experiments of the products formed during the pyrolysis of organic compounds from three chemical families—polycyclic aromatic hydrocarbons, amino acids, and carboxylic acids—in presence of calcium perchlorates. Results show that the polycyclic aromatic hydrocarbon parent molecules and most of the carboxylic acids are still detectable after pyrolysis in presence of calcium perchlorate and that the degradation and/or evolution of all parent molecules mostly depends on their chemical nature. In addition, we demonstrate that the chlorohydrocarbons detected on Mars by the Sample Analysis at Mars instrument could come from the three chemical families studied.

Published
2022

5. Influence of Calcium Perchlorate on Organics under SAM‐like Pyrolysis Conditions: Constraints on the Nature of Martian Organics

Author

Millan, M, Szopa, C, Buch, A, Summons, RE, Navarro-Gonzalez, R, Mahaffy, PR, Johnson, SS, Millan, M, Szopa, C, Buch, A, Summons, RE, Navarro-Gonzalez, R, Mahaffy, PR, and Johnson, SS

Abstract

©2020. American Geophysical Union. All Rights Reserved. Most of the organics detected on Mars so far are aliphatic and aromatic organo-chlorine compounds. The smallest were first identified by the thermal treatment of the solid samples by Viking in 1976; although at the time, they were attributed to contamination. Since 2012, a larger variety of structures have been identified by the Sample Analysis at Mars experiment aboard the Curiosity rover. Evidence suggests that the chlorohydrocarbons formed during pyrolysis of sedimentary materials. Laboratory experiments show that heating of samples containing oxychlorines, such as chlorates (ClO3−) and perchlorates (ClO4−), along with organic matter present at Mars' surface is the logical source of these compounds. Nevertheless, this discovery of indigenous organic matter in the Mars regolith raises important questions: How do the oxychlorines influence the pyrolysis of organics? What are the organics precursors of the organo-chlorinated molecules detected on Mars? Is there a way to identify the parent molecules in a sample after pyrolysis? This paper presents the results of systematic laboratory experiments of the products formed during the pyrolysis of organic compounds from three chemical families—polycyclic aromatic hydrocarbons, amino acids, and carboxylic acids—in presence of calcium perchlorates. Results show that the polycyclic aromatic hydrocarbon parent molecules and most of the carboxylic acids are still detectable after pyrolysis in presence of calcium perchlorate and that the degradation and/or evolution of all parent molecules mostly depends on their chemical nature. In addition, we demonstrate that the chlorohydrocarbons detected on Mars by the Sample Analysis at Mars instrument could come from the three chemical families studied.

Published
2021

15. The imprint of atmospheric evolution in the D/H of Hesperian clay minerals on Mars

Author

Mahaffy, P. R., Webster, C. R., Stern, J. C., Brunner, A. E., Atreya, S. K., Conrad, P. G., Domagal-Goldman, S., Eigenbrode, J. L., Flesch, G. J., Christensen, L. E., Franz, H. B., Freissinet, C., Glavin, D. P., Grotzinger, J. P., Jones, J. H., Leshin, L. A., Malespin, C., McAdam, A. C., Ming, D. W., Navarro-Gonzalez, R., Niles, P. B., Owen, T., Pavlov, A. A., Steele, A., Trainer, M. G., Williford, K. H., Wray, J. J., Stipp, Susan Louise Svane, Mahaffy, P. R., Webster, C. R., Stern, J. C., Brunner, A. E., Atreya, S. K., Conrad, P. G., Domagal-Goldman, S., Eigenbrode, J. L., Flesch, G. J., Christensen, L. E., Franz, H. B., Freissinet, C., Glavin, D. P., Grotzinger, J. P., Jones, J. H., Leshin, L. A., Malespin, C., McAdam, A. C., Ming, D. W., Navarro-Gonzalez, R., Niles, P. B., Owen, T., Pavlov, A. A., Steele, A., Trainer, M. G., Williford, K. H., Wray, J. J., and Stipp, Susan Louise Svane

Published
2015

16. Abundance and isotopic composition of gases in the martian atmosphere from the Curiosity rover

Author

Mahaffy, P. R., Webster, C. R., Atreya, S. K., Franz, H., Wong, M., Conrad, P. G., Harpold, D., Jones, J. J., Leshin, L. A., Manning, H., Owen, T., Pepin, R. O., Squyres, S., Trainer, M., Kemppinen, O., Bridges, N., Johnson, J. R., Minitti, M., Cremers, D., Bell, J. F., Edgar, L., Farmer, J., Godber, A., Wadhwa, M., Wellington, D., McEwan, I., Newman, C., Richardson, M., Charpentier, A., Peret, L., King, P., Blank, J., Weigle, G., Schmidt, M., Li, S., Milliken, R., Robertson, K., Sun, V., Baker, M., Edwards, C., Ehlmann, B., Farley, K., Griffes, J., Grotzinger, J., Miller, H., Newcombe, M., Pilorget, C., Rice, M., Siebach, K., Stack, K., Stolper, E., Brunet, C., Hipkin, V., Leveille, R., Marchand, G., Sanchez, P. S., Favot, L., Cody, G., Steele, A., Fluckiger, L., Lees, D., Nefian, A., Martin, M., Gailhanou, M., Westall, F., Israel, G., Agard, C., Baroukh, J., Donny, C., Gaboriaud, A., Guillemot, P., Lafaille, V., Lorigny, E., Paillet, A., Perez, R., Saccoccio, M., Yana, C., Armiens-Aparicio, C., Rodriguez, J. C., Blazquez, I. C., Gomez, F. G., Gomez-Elvira, J., Hettrich, S., Malvitte, A. L., Jimenez, M. M., Martinez-Frias, J., Martin-Soler, J., Martin-Torres, F. J., Jurado, A. M., Mora-Sotomayor, L., Caro, G. M., Lopez, S. N., Peinado-Gonzalez, V., Pla-Garcia, J., Manfredi, J. A. R., Romeral-Planello, J. J., Fuentes, S. A. S., Martinez, E. S., Redondo, J. T., Urqui-O'Callaghan, R., Mier, M.-P. Z., Chipera, S., Lacour, J.-L., Mauchien, P., Sirven, J.-B., Fairen, A., Hayes, A., Joseph, J., Sullivan, R., Thomas, P., Dupont, A., Lundberg, A., Melikechi, N., Mezzacappa, A., DeMarines, J., Grinspoon, D., Reitz, G., Prats, B., Atlaskin, E., Genzer, M., Harri, A.-M., Haukka, H., Kahanpaa, H., Kauhanen, J., Paton, M., Polkko, J., Schmidt, W., Siili, T., Fabre, C., Wray, J., Wilhelm, M. B., Poitrasson, F., Patel, K., Gorevan, S., Indyk, S., Paulsen, G., Gupta, S., Bish, D., Schieber, J., Gondet, B., Langevin, Y., Geffroy, C., Baratoux, D., Berger, G., Cros, A., d'Uston, C., Forni, O., Gasnault, O., Lasue, J., Lee, Q.-M., Maurice, S., Meslin, P.-Y., Pallier, E., Parot, Y., Pinet, P., Schroder, S., Toplis, M., Lewin, E., Brunner, W., Heydari, E., Achilles, C., Oehler, D., Sutter, B., Cabane, M., Coscia, D., Szopa, C., Dromart, G., Robert, F., Sautter, V., Le Mouelic, S., Mangold, N., Nachon, M., Buch, A., Stalport, F., Coll, P., Francois, P., Raulin, F., Teinturier, S., Cameron, J., Clegg, S., Cousin, A., DeLapp, D., Dingler, R., Jackson, R. S., Johnstone, S., Lanza, N., Little, C., Nelson, T., Wiens, R. C., Williams, R. B., Jones, A., Kirkland, L., Treiman, A., Baker, B., Cantor, B., Caplinger, M., Davis, S., Duston, B., Edgett, K., Fay, D., Hardgrove, C., Harker, D., Herrera, P., Jensen, E., Kennedy, M. R., Krezoski, G., Krysak, D., Lipkaman, L., Malin, M., McCartney, E., McNair, S., Nixon, B., Posiolova, L., Ravine, M., Salamon, A., Saper, L., Stoiber, K., Supulver, K., Van Beek, J., Van Beek, T., Zimdar, R., French, K. L., Iagnemma, K., Miller, K., Summons, R., Goesmann, F., Goetz, W., Hviid, S., Johnson, M., Lefavor, M., Lyness, E., Breves, E., Dyar, M. D., Fassett, C., Blake, D. F., Bristow, T., DesMarais, D., Edwards, L., Haberle, R., Hoehler, T., Hollingsworth, J., Kahre, M., Keely, L., McKay, C., Bleacher, L., Brinckerhoff, W., Choi, D., Dworkin, J. P., Eigenbrode, J., Floyd, M., Freissinet, C., Garvin, J., Glavin, D., Martin, D. K., McAdam, A., Pavlov, A., Raaen, E., Smith, M. D., Stern, J., Tan, F., Meyer, M., Posner, A., Voytek, M., Anderson, R. C., Aubrey, A., Beegle, L. W., Behar, A., Blaney, D., Brinza, D., Calef, F., Christensen, L., Crisp, J. A., DeFlores, L., Feldman, J., Feldman, S., Flesch, G., Hurowitz, J., Jun, I., Keymeulen, D., Maki, J., Mischna, M., Morookian, J. M., Parker, T., Pavri, B., Schoppers, M., Sengstacken, A., Simmonds, J. J., Spanovich, N., Juarez, M. d. l. T., Vasavada, A. R., Yen, A., Archer, P. D., Cucinotta, F., Ming, D., Morris, R. V., Niles, P., Rampe, E., Nolan, T., Fisk, M., Radziemski, L., Barraclough, B., Bender, S., Berman, D., Dobrea, E. N., Tokar, R., Vaniman, D., Williams, R. M. E., Yingst, A., Lewis, K., Cleghorn, T., Huntress, W., Manhes, G., Hudgins, J., Olson, T., Stewart, N., Sarrazin, P., Grant, J., Vicenzi, E., Wilson, S. A., Bullock, M., Ehresmann, B., Hamilton, V., Hassler, D., Peterson, J., Rafkin, S., Zeitlin, C., Fedosov, F., Golovin, D., Karpushkina, N., Kozyrev, A., Litvak, M., Malakhov, A., Mitrofanov, I., Mokrousov, M., Nikiforov, S., Prokhorov, V., Sanin, A., Tretyakov, V., Varenikov, A., Vostrukhin, A., Kuzmin, R., Clark, B., Wolff, M., McLennan, S., Botta, O., Drake, D., Bean, K., Lemmon, M., Schwenzer, S. P., Anderson, R. B., Herkenhoff, K., Lee, E. M., Sucharski, R., Hernandez, M. A. d. P., Avalos, J. J. B., Ramos, M., Kim, M.-H., Malespin, C., Plante, I., Muller, J.-P., Navarro-Gonzalez, R., Ewing, R., Boynton, W., Downs, R., Fitzgibbon, M., Harshman, K., Morrison, S., Dietrich, W., Kortmann, O., Palucis, M., Sumner, D. Y., Williams, A., Lugmair, G., Wilson, M. A., Rubin, D., Jakosky, B., Balic-Zunic, T., Frydenvang, J., Jensen, J. K., Kinch, K., Koefoed, A., Madsen, M. B., Stipp, S. L. S., Boyd, N., Campbell, J. L., Gellert, R., Perrett, G., Pradler, I., VanBommel, S., Jacob, S., Rowland, S., Savijarvi, H., Boehm, E., Bottcher, S., Burmeister, S., Guo, J., Kohler, J., Garcia, C. M., Mueller-Mellin, R., Wimmer-Schweingruber, R., Bridges, J. C., McConnochie, T., Benna, M., Bower, H., Brunner, A., Blau, H., Boucher, T., Carmosino, M., Elliott, H., Halleaux, D., Renno, N., Elliott, B., Spray, J., Thompson, L., Gordon, S., Newsom, H., Ollila, A., Williams, J., Vasconcelos, P., Bentz, J., Nealson, K., Popa, R., Kah, L. C., Moersch, J., Tate, C., Day, M., Kocurek, G., Hallet, B., Sletten, R., Francis, R., McCullough, E., Cloutis, E., ten Kate, I. L., Arvidson, R., Fraeman, A., Scholes, D., Slavney, S., Stein, T., Ward, J., Berger, J., Moores, J. E., GeoRessources, Institut national des sciences de l'Univers (INSU - CNRS)-Centre de recherches sur la géologie des matières premières minérales et énergétiques (CREGU)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS), MSL Science Team, NWO-NSO: The role of perchlorates in the preservation of organic compounds on Mars, and Petrology

Subjects
010504 meteorology & atmospheric sciences, Curiosity rover, chemistry.chemical_element, [SDU.STU]Sciences of the Universe [physics]/Earth Sciences, Mars, MSL Mars Atmosphere Isotopis Composition, martian atmosphere, 01 natural sciences, Astrobiology, Isotopic signature, chemistry.chemical_compound, 0103 physical sciences, MSL, 010303 astronomy & astrophysics, 0105 earth and related environmental sciences, Martian, Multidisciplinary, δ13C, Atmosphere of Mars, Nitrogen, chemistry, 13. Climate action, Sample Analysis at Mars, Carbon dioxide, Environmental science, Carbon monoxide
Abstract

Mars' Atmosphere from Curiosity The Sample Analysis at Mars (SAM) instrument on the Curiosity rover that landed on Mars in August last year is designed to study the chemical and isotopic composition of the martian atmosphere. Mahaffy et al. (p. 263 ) present volume-mixing ratios of Mars' five major atmospheric constituents (CO 2 , Ar, N 2 , O 2 , and CO) and isotope measurements of 40 Ar/ 36 Ar and C and O in CO 2 , based on data from one of SAM's instruments, obtained between 31 August and 21 November 2012. Webster et al. (p. 260 ) used data from another of SAM's instruments obtained around the same period to determine isotope ratios of H, C, and O in atmospheric CO 2 and H 2 O. Agreement between the isotopic ratios measured by SAM with those of martian meteorites, measured in laboratories on Earth, confirms the origin of these meteorites and implies that the current atmospheric reservoirs of CO 2 and H 2 O were largely established after the period of early atmospheric loss some 4 billion years ago.

Published
2013
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17. Curiosity at Gale Crater, Mars: Characterization and analysis of the rocknest sand shadow

Author

Blake, D. F., Morris, R. V., Kocurek, G., Morrison, S. M., Downs, R. T., Bish, D., Ming, D. W., Edgett, K. S., Rubin, D., Goetz, W., Madsen, M. B., Sullivan, R., Gellert, R., Campbell, I., Treiman, A. H., McLennan, S. M., Yen, A. S., Grotzinger, J., Vaniman, D. T., Chipera, S. J., Achilles, C. N., Rampe, E. B., Sumner, D., Meslin, P.- Y., Maurice, S., Forni, O., Gasnault, O., Fisk, M., Schmidt, M., Mahaffy, P., Leshin, L. A., Glavin, D., Steele, A., Freissinet, C., Navarro-Gonzalez, R., Yingst, R. A., Kah, L. C., Bridges, N., Lewis, K. W., Bristow, T. F., Farmer, J. D., Crisp, J. A., Stolper, E. M., Des Marais, D. J., Sarrazin, P., Agard, C., Alves Verdasca, J. A., Anderson, R., Archer, D., Armiens-Aparicio, C., Arvidson, R., Atlaskin, E., Atreya, S., Aubrey, A., Baker, B., Baker, M., Balic-Zunic, T., Baratoux, D., Baroukh, J., Barraclough, B., Bean, K., Beegle, L., Behar, A., Bell, J., Bender, S., Benna, M., Bentz, J., Berger, G., Berger, J., Berman, D., Blanco Avalos, J. J., Blaney, D., Blank, J., Blau, H., Bleacher, L., Boehm, E., Botta, O., Bottcher, S., Boucher, T., Bower, H., Boyd, N., Boynton, B., Breves, E., Bridges, J., Brinckerhoff, W., Brinza, D., Brunet, C., Brunner, A., Brunner, W., Buch, A., Bullock, M., Burmeister, S., Cabane, M., Calef, F., Cameron, J., Cantor, B., Caplinger, M., Rodriguez, J. C., Carmosino, M., Blazquez, I. C., Charpentier, A., Choi, D., Clark, B., Clegg, S., Cleghorn, T., Cloutis, E., Cody, G., Coll, P., Conrad, P., Coscia, D., Cousin, A., Cremers, D., Cros, A., Cucinotta, F., d'Uston, C., Davis, S., Day, M., Juarez, M. d. l. T., DeFlores, L., DeLapp, D., DeMarines, J., Dietrich, W., Dingler, R., Donny, C., Drake, D., Dromart, G., Dupont, A., Duston, B., Dworkin, J., Dyar, M. D., Edgar, L., Edwards, C., Edwards, L., Ehlmann, B., Ehresmann, B., Eigenbrode, J., Elliott, B., Elliott, H., Ewing, R., Fabre, C., Fairen, A., Farley, K., Fassett, C., Favot, L., Fay, D., Fedosov, F., Feldman, J., Feldman, S., Fitzgibbon, M., Flesch, G., Floyd, M., Fluckiger, L., Fraeman, A., Francis, R., Francois, P., Franz, H., French, K. L., Frydenvang, J., Gaboriaud, A., Gailhanou, M., Garvin, J., Geffroy, C., Genzer, M., Godber, A., Goesmann, F., Golovin, D., Gomez, F. G., Gomez-Elvira, J., Gondet, B., Gordon, S., Gorevan, S., Grant, J., Griffes, J., Grinspoon, D., Guillemot, P., Guo, J., Gupta, S., Guzewich, S., Haberle, R., Halleaux, D., Hallet, B., Hamilton, V., Hardgrove, C., Harker, D., Harpold, D., Harri, A.-M., Harshman, K., Hassler, D., Haukka, H., Hayes, A., Herkenhoff, K., Herrera, P., Hettrich, S., Heydari, E., Hipkin, V., Hoehler, T., Hollingsworth, J., Hudgins, J., Huntress, W., Hurowitz, J., Hviid, S., Iagnemma, K., Indyk, S., Israel, G., Jackson, R., Jacob, S., Jakosky, B., Jensen, E., Jensen, J. K., Johnson, J., Johnson, M., Johnstone, S., Jones, A., Jones, J., Joseph, J., Jun, I., Kahanpaa, H., Kahre, M., Karpushkina, N., Kasprzak, W., Kauhanen, J., Keely, L., Kemppinen, O., Keymeulen, D., Kim, M.-H., Kinch, K., King, P., Kirkland, L., Koefoed, A., Kohler, J., Kortmann, O., Kozyrev, A., Krezoski, J., Krysak, D., Kuzmin, R., Lacour, J. L., Lafaille, V., Langevin, Y., Lanza, N., Lasue, J., Le Mouelic, S., Lee, E. M., Lee, Q.-M., Lees, D., Lefavor, M., Lemmon, M., Lepinette Malvitte, A., Leveille, R., Lewin-Carpintier, E., Li, S., Lipkaman, L., Little, C., Litvak, M., Lorigny, E., Lugmair, G., Lundberg, A., Lyness, E., Maki, J., Malakhov, A., Malespin, C., Malin, M., Mangold, N., Manning, H., Marchand, G., Marin Jimenez, M., Martin Garcia, C., Martin, D., Martin, M., Martinez-Frias, J., Martin-Soler, J., Martin-Torres, F. J., Mauchien, P., McAdam, A., McCartney, E., McConnochie, T., McCullough, E., McEwan, I., McKay, C., McNair, S., Melikechi, N., Meyer, M., Mezzacappa, A., Miller, H., Miller, K., Milliken, R., Minitti, M., Mischna, M., Mitrofanov, I., Moersch, J., Mokrousov, M., Molina Jurado, A., Moores, J., Mora-Sotomayor, L., Morookian, J. M., Mueller-Mellin, R., Muller, J.-P., Munoz Caro, G., Nachon, M., Navarro Lopez, S., Nealson, K., Nefian, A., Nelson, T., Newcombe, M., Newman, C., Newsom, H., Nikiforov, S., Niles, P., Nixon, B., Dobrea, E. N., Nolan, T., Oehler, D., Ollila, A., Olson, T., Owen, T., Pablo, H., Paillet, A., Pallier, E., Palucis, M., Parker, T., Parot, Y., Patel, K., Paton, M., Paulsen, G., Pavlov, A., Pavri, B., Peinado-Gonzalez, V., Pepin, R., Peret, L., Perez, R., Perrett, G., Peterson, J., Pilorget, C., Pinet, P., Pla-Garcia, J., Plante, I., Poitrasson, F., Polkko, J., Popa, R., Posiolova, L., Pradler, I., Prats, B., Prokhorov, V., Purdy, S. W., Raaen, E., Radziemski, L., Rafkin, S., Ramos, M., Raulin, F., Ravine, M., Reitz, G., Renno, N., Rice, M., Richardson, M., Robert, F., Rodriguez Manfredi, J. A., Romeral-Planello, J. J., Rowland, S., Saccoccio, M., Salamon, A., Sandoval, J., Sanin, A., Sans Fuentes, S. A., Saper, L., Sautter, V., Savijarvi, H., Schieber, J., Schmidt, W., Scholes, D., Schoppers, M., Schroder, S., Sebastian Martinez, E., Sengstacken, A., Shterts, R., Siebach, K., Siili, T., Simmonds, J., Sirven, J.-B., Slavney, S., Sletten, R., Smith, M., Sobron Sanchez, P., Spanovich, N., Spray, J., Squyres, S., Stack, K., Stalport, F., Stein, T., Stern, J., Stewart, N., Stipp, S. L. S., Stoiber, K., Sucharski, B., Summons, R., Sun, V., Supulver, K., Sutter, B., Szopa, C., Tate, C., Teinturier, S., ten Kate, I. L., Thomas, P., Thompson, L., Tokar, R., Toplis, M., Torres Redondo, J., Trainer, M., Tretyakov, V., Urqui-O'Callaghan, R., Van Beek, J., Van Beek, T., VanBommel, S., Varenikov, A., Vasavada, A., Vasconcelos, P., Vicenzi, E., Vostrukhin, A., Voytek, M., Wadhwa, M., Ward, J., Webster, C., Weigle, E., Wellington, D., Westall, F., Wiens, R. C., Wilhelm, M. B., Williams, A., Williams, J., Williams, R., Williams, R. B., Wilson, M., Wimmer-Schweingruber, R., Wolff, M., Wong, M., Wray, J., Wu, M., Yana, C., Zeitlin, C., Zimdar, R., Zorzano Mier, M.-P., GeoRessources, Institut national des sciences de l'Univers (INSU - CNRS)-Centre de recherches sur la géologie des matières premières minérales et énergétiques (CREGU)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS), NASA Ames Research Center (ARC), NASA Johnson Space Center (JSC), NASA, Department of Geological Sciences [Austin], Jackson School of Geosciences (JSG), University of Texas at Austin [Austin]-University of Texas at Austin [Austin], Department of Geology [Tucson], University of Arizona, Department of Geological Sciences [Bloomington], Indiana University [Bloomington], Indiana University System-Indiana University System, Malin Space Science Systems (MSSS), NASA Goddard Space Flight Center (GSFC), NWO-NSO: The role of perchlorates in the preservation of organic compounds on Mars, and Petrology

Subjects
Basalt, Meridiani Planum, Multidisciplinary, 010504 meteorology & atmospheric sciences, Curiosity rover, Geochemistry, Mars, [SDU.STU]Sciences of the Universe [physics]/Earth Sciences, Mars Exploration Program, Exploration of Mars, 01 natural sciences, Astrobiology, Impact crater, 13. Climate action, MSL Mars Gale Crater Rocknest, Rocknest, 0103 physical sciences, Sample Analysis at Mars, Aeolian processes, MSL, Rocknest aeolian deposit, 010303 astronomy & astrophysics, Geology, 0105 earth and related environmental sciences
Abstract

The Rocknest aeolian deposit is similar to aeolian features analyzed by the Mars Exploration Rovers (MERs) Spirit and Opportunity. The fraction of sand

Published
2013
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18. The Petrochemistry of Jake_M: A Martian Mugearite

Author

Stolper, E. M., Baker, M. B., Newcombe, M. E., Schmidt, M. E., Treiman, A. H., Cousin, A., Dyar, M. D., Fisk, M. R., Gellert, R., King, P. L., Leshin, L., Maurice, S., McLennan, S. M., Minitti, M. E., Perrett, G., Rowland, S., Sautter, V., Wiens, R. C., Kemppinen, O., Bridges, N., Johnson, J. R., Cremers, D., Bell, J. F., Edgar, L., Farmer, J., Godber, A., Wadhwa, M., Wellington, D., McEwan, I., Newman, C., Richardson, M., Charpentier, A., Peret, L., Blank, J., Weigle, G., Li, S., Milliken, R., Robertson, K., Sun, V., Edwards, C., Ehlmann, B., Farley, K., Griffes, J., Grotzinger, J., Miller, H., Pilorget, C., Rice, M., Siebach, K., Stack, K., Brunet, C., Hipkin, V., Leveille, R., Marchand, G., Sanchez, P. S., Favot, L., Cody, G., Steele, A., Fluckiger, L., Lees, D., Nefian, A., Martin, M., Gailhanou, M., Westall, F., Israel, G., Agard, C., Baroukh, J., Donny, C., Gaboriaud, A., Guillemot, P., Lafaille, V., Lorigny, E., Paillet, A., Perez, R., Saccoccio, M., Yana, C., Armiens-Aparicio, C., Rodriguez, J. C., Blazquez, I. C., Gomez, F. G., Gomez-Elvira, J., Hettrich, S., Malvitte, A. L., Jimenez, M. M., Martinez-Frias, J., Martin-Soler, J., Martin-Torres, F. J., Jurado, A. M., Mora-Sotomayor, L., Caro, G. M., Lopez, S. N., Peinado-Gonzalez, V., Pla-Garcia, J., Manfredi, J. A. R., Romeral-Planello, J. J., Fuentes, S. A. S., Martinez, E. S., Redondo, J. T., Urqui-O'Callaghan, R., Mier, M.-P. Z., Chipera, S., Lacour, J.-L., Mauchien, P., Sirven, J.-B., Manning, H., Fairen, A., Hayes, A., Joseph, J., Squyres, S., Sullivan, R., Thomas, P., Dupont, A., Lundberg, A., Melikechi, N., Mezzacappa, A., DeMarines, J., Grinspoon, D., Reitz, G., Prats, B., Atlaskin, E., Genzer, M., Harri, A.-M., Haukka, H., Kahanpaa, H., Kauhanen, J., Paton, M., Polkko, J., Schmidt, W., Siili, T., Fabre, C., Wray, J., Wilhelm, M. B., Poitrasson, F., Patel, K., Gorevan, S., Indyk, S., Paulsen, G., Gupta, S., Bish, D., Schieber, J., Gondet, B., Langevin, Y., Geffroy, C., Baratoux, D., Berger, G., Cros, A., d'Uston, C., Forni, O., Gasnault, O., Lasue, J., Lee, Q.-M., Meslin, P.-Y., Pallier, E., Parot, Y., Pinet, P., Schroder, S., Toplis, M., Lewin, E., Brunner, W., Heydari, E., Achilles, C., Oehler, D., Sutter, B., Cabane, M., Coscia, D., Szopa, C., Teinturier, S., Dromart, G., Robert, F., Le Mouelic, S., Mangold, N., Nachon, M., Buch, A., Stalport, F., Coll, P., Francois, P., Raulin, F., Cameron, J., Clegg, S., DeLapp, D., Dingler, R., Jackson, R. S., Johnstone, S., Lanza, N., Little, C., Nelson, T., Williams, R. B., Kirkland, L., Baker, B., Cantor, B., Caplinger, M., Davis, S., Duston, B., Edgett, K., Fay, D., Hardgrove, C., Harker, D., Herrera, P., Jensen, E., Kennedy, M. R., Krezoski, G., Krysak, D., Lipkaman, L., Malin, M., McCartney, E., McNair, S., Nixon, B., Posiolova, L., Ravine, M., Salamon, A., Saper, L., Stoiber, K., Supulver, K., Van Beek, J., Van Beek, T., Zimdar, R., French, K. L., Iagnemma, K., Miller, K., Summons, R., Goesmann, F., Goetz, W., Hviid, S., Johnson, M., Lefavor, M., Lyness, E., Breves, E., Fassett, C., Blake, D. F., Bristow, T., DesMarais, D., Edwards, L., Haberle, R., Hoehler, T., Hollingsworth, J., Kahre, M., Keely, L., McKay, C., Bleacher, L., Brinckerhoff, W., Choi, D., Conrad, P., Dworkin, J. P., Eigenbrode, J., Floyd, M., Freissinet, C., Garvin, J., Glavin, D., Harpold, D., Mahaffy, P., Martin, D. K., McAdam, A., Pavlov, A., Raaen, E., Smith, M. D., Stern, J., Tan, F., Trainer, M., Meyer, M., Posner, A., Voytek, M., Anderson, R. C., Aubrey, A., Beegle, L. W., Behar, A., Blaney, D., Brinza, D., Calef, F., Christensen, L., Crisp, J., DeFlores, L., Feldman, J., Feldman, S., Flesch, G., Hurowitz, J., Jun, I., Keymeulen, D., Maki, J., Mischna, M., Morookian, J. M., Parker, T., Pavri, B., Schoppers, M., Sengstacken, A., Simmonds, J. J., Spanovich, N., Juarez, M. d. l. T., Vasavada, A., Webster, C. R., Yen, A., Archer, P. D., Cucinotta, F., Jones, J. H., Ming, D., Morris, R. V., Niles, P., Rampe, E., Nolan, T., Radziemski, L., Barraclough, B., Bender, S., Berman, D., Dobrea, E. N., Tokar, R., Vaniman, D., Williams, R. M. E., Yingst, A., Lewis, K., Cleghorn, T., Huntress, W., Manhes, G., Hudgins, J., Olson, T., Stewart, N., Sarrazin, P., Grant, J., Vicenzi, E., Wilson, S. A., Bullock, M., Ehresmann, B., Hamilton, V., Hassler, D., Peterson, J., Rafkin, S., Zeitlin, C., Fedosov, F., Golovin, D., Karpushkina, N., Kozyrev, A., Litvak, M., Malakhov, A., Mitrofanov, I., Mokrousov, M., Nikiforov, S., Prokhorov, V., Sanin, A., Tretyakov, V., Varenikov, A., Vostrukhin, A., Kuzmin, R., Clark, B., Wolff, M., Botta, O., Drake, D., Bean, K., Lemmon, M., Schwenzer, S. P., Anderson, R. B., Herkenhoff, K., Lee, E. M., Sucharski, R., Hernandez, M. A. d. P., Avalos, J. J. B., Ramos, M., Jones, A., Kim, M.-H., Malespin, C., Plante, I., Muller, J.-P., Navarro-Gonzalez, R., Ewing, R., Boynton, W., Downs, R., Fitzgibbon, M., Harshman, K., Morrison, S., Dietrich, W., Kortmann, O., Palucis, M., Sumner, D. Y., Williams, A., Lugmair, G., Wilson, M. A., Rubin, D., Jakosky, B., Balic-Zunic, T., Frydenvang, J., Jensen, J. K., Kinch, K., Koefoed, A., Madsen, M. B., Stipp, S. L. S., Boyd, N., Campbell, J. L., Pradler, I., VanBommel, S., Jacob, S., Owen, T., Savijarvi, H., Boehm, E., Bottcher, S., Burmeister, S., Guo, J., Kohler, J., Garcia, C. M., Mueller-Mellin, R., Wimmer-Schweingruber, R., Bridges, J. C., McConnochie, T., Benna, M., Franz, H., Bower, H., Brunner, A., Blau, H., Boucher, T., Carmosino, M., Atreya, S., Elliott, H., Halleaux, D., Renno, N., Wong, M., Pepin, R., Elliott, B., Spray, J., Thompson, L., Gordon, S., Newsom, H., Ollila, A., Williams, J., Vasconcelos, P., Bentz, J., Nealson, K., Popa, R., Kah, L. C., Moersch, J., Tate, C., Day, M., Kocurek, G., Hallet, B., Sletten, R., Francis, R., McCullough, E., Cloutis, E., ten Kate, I. L., Arvidson, R., Fraeman, A., Scholes, D., Slavney, S., Stein, T., Ward, J., Berger, J., Moores, J. E., GeoRessources, Centre National de la Recherche Scientifique (CNRS)-Université de Lorraine (UL)-Centre de recherches sur la géologie des matières premières minérales et énergétiques (CREGU)-Institut national des sciences de l'Univers (INSU - CNRS), California Institute of Technology (CALTECH), Department of Earth Sciences [St. Catharines], Brock University [Canada], Lunar and Planetary Institute [Houston] (LPI), Los Alamos National Laboratory (LANL), Institut de recherche en astrophysique et planétologie (IRAP), Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS), Mount Holyoke College, Oregon State University (OSU), University of Guelph, Research School of Earth Sciences [Canberra] (RSES), Australian National University (ANU), Rensselaer Polytechnic Institute (RPI), State University of New York (SUNY), Johns Hopkins University Applied Physics Laboratory [Laurel, MD] (APL), University of Hawaii, Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de recherche pour le développement [IRD] : UR206-Centre National de la Recherche Scientifique (CNRS), MSL Science Team, Institut national des sciences de l'Univers (INSU - CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Observatoire Midi-Pyrénées (OMP), and Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS)

Subjects
010504 meteorology & atmospheric sciences, Curiosity rover, Geochemistry, Mars, [SDU.STU]Sciences of the Universe [physics]/Earth Sciences, 010502 geochemistry & geophysics, 01 natural sciences, Jake_M: a martian mugearite, chemistry.chemical_compound, Nepheline, MSL, Chemical composition, 0105 earth and related environmental sciences, Martian, Phonolite, Multidisciplinary, Fractional crystallization (geology), petrochemistry, Igneous rock, Planetary science, MSL Mars Petrochemistry, chemistry, 13. Climate action, Petrochemistry, Geology, [SDU.STU.MI]Sciences of the Universe [physics]/Earth Sciences/Mineralogy
Abstract

International audience; "Jake_M," the first rock analyzed by the Alpha Particle X-ray Spectrometer instrument on the Curiosity rover, differs substantially in chemical composition from other known martian igneous rocks: It is alkaline (>15% normative nepheline) and relatively fractionated. Jake_M is compositionally similar to terrestrial mugearites, a rock type typically found at ocean islands and continental rifts. By analogy with these comparable terrestrial rocks, Jake_M could have been produced by extensive fractional crystallization of a primary alkaline or transitional magma at elevated pressure, with or without elevated water contents. The discovery of Jake_M suggests that alkaline magmas may be more abundant on Mars than on Earth and that Curiosity could encounter even more fractionated alkaline rocks (for example, phonolites and trachytes).

Published
2013
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19. Volatile, Isotope, and Organic Analysis of Martian Fines with the Mars Curiosity Rover

Author

Leshin, L. A., Mahaffy, P. R., Webster, C. R., Cabane, M., Coll, P., Conrad, P. G., Archer, P. D., Atreya, S. K., Brunner, A. E., Buch, A., Eigenbrode, J. L., Flesch, G. J., Franz, H. B., Freissinet, C., Glavin, D. P., McAdam, A. C., Miller, K. E., Ming, D. W., Morris, R. V., Navarro-Gonzalez, R., Niles, P. B., Owen, T., Pepin, R. O., Squyres, S., Steele, A., Stern, J. C., Summons, R. E., Sumner, D. Y., Sutter, B., Szopa, C., Teinturier, S., Trainer, M. G., Wray, J. J., Grotzinger, J. P., Kemppinen, O., Bridges, N., Johnson, J. R., Minitti, M., Cremers, D., Bell, J. F., Edgar, L., Farmer, J., Godber, A., Wadhwa, M., Wellington, D., McEwan, I., Newman, C., Richardson, M., Charpentier, A., Peret, L., King, P., Blank, J., Weigle, G., Schmidt, M., Li, S., Milliken, R., Robertson, K., Sun, V., Baker, M., Edwards, C., Ehlmann, B., Farley, K., Griffes, J., Miller, H., Newcombe, M., Pilorget, C., Rice, M., Siebach, K., Stack, K., Stolper, E., Brunet, C., Hipkin, V., Leveille, R., Marchand, G., Sanchez, P. S., Favot, L., Cody, G., Fluckiger, L., Lees, D., Nefian, A., Martin, M., Gailhanou, M., Westall, F., Israel, G., Agard, C., Baroukh, J., Donny, C., Gaboriaud, A., Guillemot, P., Lafaille, V., Lorigny, E., Paillet, A., Perez, R., Saccoccio, M., Yana, C., Armiens-Aparicio, C., Rodriguez, J. C., Blazquez, I. C., Gomez, F. G., Gomez-Elvira, J., Hettrich, S., Malvitte, A. L., Jimenez, M. M., Martinez-Frias, J., Martin-Soler, J., Martin-Torres, F. J., Jurado, A. M., Mora-Sotomayor, L., Caro, G. M., Lopez, S. N., Peinado-Gonzalez, V., Pla-Garcia, J., Manfredi, J. A. R., Romeral-Planello, J. J., Fuentes, S. A. S., Martinez, E. S., Redondo, J. T., Urqui-O'Callaghan, R., Mier, M.-P. Z., Chipera, S., Lacour, J.-L., Mauchien, P., Sirven, J.-B., Manning, H., Fairen, A., Hayes, A., Joseph, J., Sullivan, R., Thomas, P., Dupont, A., Lundberg, A., Melikechi, N., Mezzacappa, A., DeMarines, J., Grinspoon, D., Reitz, G., Prats, B., Atlaskin, E., Genzer, M., Harri, A.-M., Haukka, H., Kahanpaa, H., Kauhanen, J., Paton, M., Polkko, J., Schmidt, W., Siili, T., Fabre, C., Wilhelm, M. B., Poitrasson, F., Patel, K., Gorevan, S., Indyk, S., Paulsen, G., Gupta, S., Bish, D., Schieber, J., Gondet, B., Langevin, Y., Geffroy, C., Baratoux, D., Berger, G., Cros, A., d'Uston, C., Forni, O., Gasnault, O., Lasue, J., Lee, Q.-M., Maurice, S., Meslin, P.-Y., Pallier, E., Parot, Y., Pinet, P., Schroder, S., Toplis, M., Lewin, E., Brunner, W., Heydari, E., Achilles, C., Oehler, D., Coscia, D., Dromart, G., Robert, F., Sautter, V., Le Mouelic, S., Mangold, N., Nachon, M., Stalport, F., Francois, P., Raulin, F., Cameron, J., Clegg, S., Cousin, A., DeLapp, D., Dingler, R., Jackson, R. S., Johnstone, S., Lanza, N., Little, C., Nelson, T., Wiens, R. C., Williams, R. B., Jones, A., Kirkland, L., Treiman, A., Baker, B., Cantor, B., Caplinger, M., Davis, S., Duston, B., Edgett, K., Fay, D., Hardgrove, C., Harker, D., Herrera, P., Jensen, E., Kennedy, M. R., Krezoski, G., Krysak, D., Lipkaman, L., Malin, M., McCartney, E., McNair, S., Nixon, B., Posiolova, L., Ravine, M., Salamon, A., Saper, L., Stoiber, K., Supulver, K., Van Beek, J., Van Beek, T., Zimdar, R., French, K. L., Iagnemma, K., Goesmann, F., Goetz, W., Hviid, S., Johnson, M., Lefavor, M., Lyness, E., Breves, E., Dyar, M. D., Fassett, C., Blake, D. F., Bristow, T., DesMarais, D., Edwards, L., Haberle, R., Hoehler, T., Hollingsworth, J., Kahre, M., Keely, L., McKay, C., Bleacher, L., Brinckerhoff, W., Choi, D., Dworkin, J. P., Floyd, M., Garvin, J., Harpold, D., Martin, D. K., Pavlov, A., Raaen, E., Smith, M. D., Tan, F., Meyer, M., Posner, A., Voytek, M., Anderson, R. C., Aubrey, A., Beegle, L. W., Behar, A., Blaney, D., Brinza, D., Calef, F., Christensen, L., Crisp, J. A., DeFlores, L., Feldman, J., Feldman, S., Hurowitz, J., Jun, I., Keymeulen, D., Maki, J., Mischna, M., Morookian, J. M., Parker, T., Pavri, B., Schoppers, M., Sengstacken, A., Simmonds, J. J., Spanovich, N., Juarez, M. d. l. T., Vasavada, A. R., Yen, A., Cucinotta, F., Jones, J. H., Rampe, E., Nolan, T., Fisk, M., Radziemski, L., Barraclough, B., Bender, S., Berman, D., Dobrea, E. N., Tokar, R., Vaniman, D., Williams, R. M. E., Yingst, A., Lewis, K., Cleghorn, T., Huntress, W., Manhes, G., Hudgins, J., Olson, T., Stewart, N., Sarrazin, P., Grant, J., Vicenzi, E., Wilson, S. A., Bullock, M., Ehresmann, B., Hamilton, V., Hassler, D., Peterson, J., Rafkin, S., Zeitlin, C., Fedosov, F., Golovin, D., Karpushkina, N., Kozyrev, A., Litvak, M., Malakhov, A., Mitrofanov, I., Mokrousov, M., Nikiforov, S., Prokhorov, V., Sanin, A., Tretyakov, V., Varenikov, A., Vostrukhin, A., Kuzmin, R., Clark, B., Wolff, M., McLennan, S., Botta, O., Drake, D., Bean, K., Lemmon, M., Schwenzer, S. P., Anderson, R. B., Herkenhoff, K., Lee, E. M., Sucharski, R., Hernandez, M. A. d. P., Avalos, J. J. B., Ramos, M., Kim, M.-H., Malespin, C., Plante, I., Muller, J.-P., Ewing, R., Boynton, W., Downs, R., Fitzgibbon, M., Harshman, K., Morrison, S., Dietrich, W., Kortmann, O., Palucis, M., Williams, A., Lugmair, G., Wilson, M. A., Rubin, D., Jakosky, B., Balic-Zunic, T., Frydenvang, J., Jensen, J. K., Kinch, K., Koefoed, A., Madsen, M. B., Stipp, S. L. S., Boyd, N., Campbell, J. L., Gellert, R., Perrett, G., Pradler, I., VanBommel, S., Jacob, S., Rowland, S., Savijarvi, H., Boehm, E., Bottcher, S., Burmeister, S., Guo, J., Kohler, J., Garcia, C. M., Mueller-Mellin, R., Wimmer-Schweingruber, R., Bridges, J. C., McConnochie, T., Benna, M., Bower, H., Blau, H., Boucher, T., Carmosino, M., Elliott, H., Halleaux, D., Renno, N., Wong, M., Elliott, B., Spray, J., Thompson, L., Gordon, S., Newsom, H., Ollila, A., Williams, J., Vasconcelos, P., Bentz, J., Nealson, K., Popa, R., Kah, L. C., Moersch, J., Tate, C., Day, M., Kocurek, G., Hallet, B., Sletten, R., Francis, R., McCullough, E., Cloutis, E., ten Kate, I. L., Arvidson, R., Fraeman, A., Scholes, D., Slavney, S., Stein, T., Ward, J., Berger, J., Moores, J. E., Department of Earth and Environmental Sciences [Troy, NY], Rensselaer Polytechnic Institute (RPI), NASA Goddard Space Flight Center (GSFC), Jet Propulsion Laboratory (JPL), NASA-California Institute of Technology (CALTECH), PLANETO - LATMOS, Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA (UMR_7583)), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris Diderot - Paris 7 (UPD7)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS), Astromaterials Research and Exploration Science (ARES), NASA Johnson Space Center (JSC), NASA-NASA, Department of Atmospheric, Oceanic, and Space Sciences [Ann Arbor] (AOSS), University of Michigan [Ann Arbor], University of Michigan System-University of Michigan System, Department of Astronomy [College Park], University of Maryland [College Park], University of Maryland System-University of Maryland System, Laboratoire de Génie des Procédés et Matériaux - EA 4038 (LGPM), CentraleSupélec, Center for Research and Exploration in Space Science and Technology [GSFC] (CRESST), Department of Earth, Atmospheric and Planetary Sciences [MIT, Cambridge] (EAPS), Massachusetts Institute of Technology (MIT), Laboratorio de Química de Plasmas y Estudios Planetarios [Mexico], Instituto de Ciencias Nucleares [Mexico], Universidad Nacional Autónoma de México = National Autonomous University of Mexico (UNAM)-Universidad Nacional Autónoma de México = National Autonomous University of Mexico (UNAM), Institute for Astronomy [Honolulu], University of Hawai‘i [Mānoa] (UHM), School of Physics and Astronomy [Minneapolis], University of Minnesota [Twin Cities] (UMN), University of Minnesota System-University of Minnesota System, Cornell University [New York], Geophysical Laboratory [Carnegie Institution], Carnegie Institution for Science, University of California [Davis] (UC Davis), University of California (UC), Jacobs Technology ESCG, Institut Pierre-Simon-Laplace (IPSL), École normale supérieure - Paris (ENS-PSL), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-École polytechnique (X)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), School of Earth and Atmospheric Sciences [Atlanta], Georgia Institute of Technology [Atlanta], Division of Geological and Planetary Sciences [Pasadena], California Institute of Technology (CALTECH), NWO-NSO: The role of perchlorates in the preservation of organic compounds on Mars, Petrology, California Institute of Technology (CALTECH)-NASA, Universidad Nacional Autónoma de México (UNAM)-Universidad Nacional Autónoma de México (UNAM), Carnegie Institution for Science [Washington], University of California, École normale supérieure - Paris (ENS Paris), IMPEC - LATMOS, Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris Diderot - Paris 7 (UPD7)-Centre National de la Recherche Scientifique (CNRS), University of Minnesota [Twin Cities], Cornell University, and École normale supérieure - Paris (ENS Paris)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National d'Études Spatiales [Toulouse] (CNES)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-École polytechnique (X)

Subjects
Martian, Multidisciplinary, 010504 meteorology & atmospheric sciences, [PHYS.ASTR.EP]Physics [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP], Thermal decomposition, Curiosity rover, [SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP], chemistry.chemical_element, Mars, organic analysis, Mars Exploration Program, 01 natural sciences, Astrobiology, chemistry.chemical_compound, chemistry, 13. Climate action, Isotopes of carbon, Rocknest, 0103 physical sciences, Sample Analysis at Mars, Carbonate, MSL Mars Volatiles Isotopes Organics Soil Gale Crater, 010303 astronomy & astrophysics, Carbon, 0105 earth and related environmental sciences
Abstract

Samples from the Rocknest aeolian deposit were heated to ~835°C under helium flow and evolved gases analyzed by Curiosity’s Sample Analysis at Mars instrument suite. H 2 O, SO 2 , CO 2 , and O 2 were the major gases released. Water abundance (1.5 to 3 weight percent) and release temperature suggest that H 2 O is bound within an amorphous component of the sample. Decomposition of fine-grained Fe or Mg carbonate is the likely source of much of the evolved CO 2 . Evolved O 2 is coincident with the release of Cl, suggesting that oxygen is produced from thermal decomposition of an oxychloride compound. Elevated δD values are consistent with recent atmospheric exchange. Carbon isotopes indicate multiple carbon sources in the fines. Several simple organic compounds were detected, but they are not definitively martian in origin.

Published
2013
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20. X-ray diffraction results from mars science laboratory: Mineralogy of rocknest at Gale crater

Author

Bish, D. L., Blake, D. F., Vaniman, D. T., Chipera, S. J., Morris, R. V., Ming, D. W., Treiman, A. H., Sarrazin, P., Morrison, S. M., Downs, R. T., Achilles, C. N., Yen, A. S., Bristow, T. F., Crisp, J. A., Morookian, J. M., Farmer, J. D., Rampe, E. B., Stolper, E. M., Spanovich, N., Achilles, C., Agard, C., Verdasca, J. A. A., Anderson, R., Archer, D., Armiens-Aparicio, C., Arvidson, R., Atlaskin, E., Atreya, S., Aubrey, A., Baker, B., Baker, M., Balic-Zunic, T., Baratoux, D., Baroukh, J., Barraclough, B., Bean, K., Beegle, L., Behar, A., Bell, J., Bender, S., Benna, M., Bentz, J., Berger, G., Berger, J., Berman, D., Bish, D., Avalos, J. J. B., Blaney, D., Blank, J., Blau, H., Bleacher, L., Boehm, E., Botta, O., Bottcher, S., Boucher, T., Bower, H., Boyd, N., Boynton, B., Breves, E., Bridges, J., Bridges, N., Brinckerhoff, W., Brinza, D., Bristow, T., Brunet, C., Brunner, A., Brunner, W., Buch, A., Bullock, M., Burmeister, S., Cabane, M., Calef, F., Cameron, J., Campbell, J. I., Cantor, B., Caplinger, M., Rodriguez, J. C., Carmosino, M., Blazquez, I. C., Charpentier, A., Chipera, S., Choi, D., Clark, B., Clegg, S., Cleghorn, T., Cloutis, E., Cody, G., Coll, P., Conrad, P., Coscia, D., Cousin, A., Cremers, D., Crisp, J., Cros, A., Cucinotta, F., d'Uston, C., Davis, S., Day, M. K., Juarez, M. d. l. T., DeFlores, L., DeLapp, D., DeMarines, J., DesMarais, D., Dietrich, W., Dingler, R., Donny, C., Downs, B., Drake, D., Dromart, G., Dupont, A., Duston, B., Dworkin, J., Dyar, M. D., Edgar, L., Edgett, K., Edwards, C., Edwards, L., Ehlmann, B., Ehresmann, B., Eigenbrode, J., Elliott, B., Elliott, H., Ewing, R., Fabre, C., Fairen, A., Farley, K., Farmer, J., Fassett, C., Favot, L., Fay, D., Fedosov, F., Feldman, J., Feldman, S., Fisk, M., Fitzgibbon, M., Flesch, G., Floyd, M., Fluckiger, L., Forni, O., Fraeman, A., Francis, R., Francois, P., Franz, H., Freissinet, C., French, K. L., Frydenvang, J., Gaboriaud, A., Gailhanou, M., Garvin, J., Gasnault, O., Geffroy, C., Gellert, R., Genzer, M., Glavin, D., Godber, A., Goesmann, F., Goetz, W., Golovin, D., Gomez, F. G., Gomez-Elvira, J., Gondet, B., Gordon, S., Gorevan, S., Grant, J., Griffes, J., Grinspoon, D., Grotzinger, J., Guillemot, P., Guo, J., Gupta, S., Guzewich, S., Haberle, R., Halleaux, D., Hallet, B., Hamilton, V., Hardgrove, C., Harker, D., Harpold, D., Harri, A.-M., Harshman, K., Hassler, D., Haukka, H., Hayes, A., Herkenhoff, K., Herrera, P., Hettrich, S., Heydari, E., Hipkin, V., Hoehler, T., Hollingsworth, J., Hudgins, J., Huntress, W., Hurowitz, J., Hviid, S., Iagnemma, K., Indyk, S., Israel, G., Jackson, R., Jacob, S., Jakosky, B., Jensen, E., Jensen, J. K., Johnson, J., Johnson, M., Johnstone, S., Jones, A., Jones, J., Joseph, J., Jun, I., Kah, L., Kahanpaa, H., Kahre, M., Karpushkina, N., Kasprzak, W., Kauhanen, J., Keely, L., Kemppinen, O., Keymeulen, D., Kim, M.-H., Kinch, K., King, P., Kirkland, L., Kocurek, G., Koefoed, A., Kohler, J., Kortmann, O., Kozyrev, A., Krezoski, J., Krysak, D., Kuzmin, R., Lacour, J. L., Lafaille, V., Langevin, Y., Lanza, N., Lasue, J., Le Mouelic, S., Lee, E. M., Lee, Q.-M., Lees, D., Lefavor, M., Lemmon, M., Malvitte, A. L., Leshin, L., Leveille, R., Lewin-Carpintier, E., Lewis, K., Li, S., Lipkaman, L., Little, C., Litvak, M., Lorigny, E., Lugmair, G., Lundberg, A., Lyness, E., Madsen, M., Mahaffy, P., Maki, J., Malakhov, A., Malespin, C., Malin, M., Mangold, N., Manhes, G., Manning, H., Marchand, G., Jimenez, M. M., Garcia, C. M., Martin, D., Martin, M., Martinez-Frias, J., Martin-Soler, J., Martin-Torres, F. J., Mauchien, P., Maurice, S., McAdam, A., McCartney, E., McConnochie, T., McCullough, E., McEwan, I., McKay, C., McLennan, S., McNair, S., Melikechi, N., Meslin, P.-Y., Meyer, M., Mezzacappa, A., Miller, H., Miller, K., Milliken, R., Ming, D., Minitti, M., Mischna, M., Mitrofanov, I., Moersch, J., Mokrousov, M., Jurado, A. M., Moores, J., Mora-Sotomayor, L., Morris, R., Morrison, S., Mueller-Mellin, R., Muller, J.-P., Caro, G. M., Nachon, M., Lopez, S. N., Navarro-Gonzalez, R., Nealson, K., Nefian, A., Nelson, T., Newcombe, M., Newman, C., Newsom, H., Nikiforov, S., Niles, P., Nixon, B., Dobrea, E. N., Nolan, T., Oehler, D., Ollila, A., Olson, T., Owen, T., Hernandez, M. A. d. P., Paillet, A., Pallier, E., Palucis, M., Parker, T., Parot, Y., Patel, K., Paton, M., Paulsen, G., Pavlov, A., Pavri, B., Peinado-Gonzalez, V., Pepin, R., Peret, L., Perez, R., Perrett, G., Peterson, J., Pilorget, C., Pinet, P., Pla-Garcia, J., Plante, I., Poitrasson, F., Polkko, J., Popa, R., Posiolova, L., Posner, A., Pradler, I., Prats, B., Prokhorov, V., Purdy, S. W., Raaen, E., Radziemski, L., Rafkin, S., Ramos, M., Rampe, E., Raulin, F., Ravine, M., Reitz, G., Renno, N., Rice, M., Richardson, M., Robert, F., Robertson, K., Manfredi, J. A. R., Romeral-Planello, J. J., Rowland, S., Rubin, D., Saccoccio, M., Salamon, A., Sandoval, J., Sanin, A., Fuentes, S. A. S., Saper, L., Sautter, V., Savijarvi, H., Schieber, J., Schmidt, M., Schmidt, W., Scholes, D. D., Schoppers, M., Schroder, S., Schwenzer, S., Martinez, E. S., Sengstacken, A., Shterts, R., Siebach, K., Siili, T., Simmonds, J., Sirven, J.-B., Slavney, S., Sletten, R., Smith, M., Sanchez, P. S., Spray, J., Squyres, S., Stack, K., Stalport, F., Steele, A., Stein, T., Stern, J., Stewart, N., Stipp, S. L. S., Stoiber, K., Stolper, E., Sucharski, B., Sullivan, R., Summons, R., Sumner, D., Sun, V., Supulver, K., Sutter, B., Szopa, C., Tan, F., Tate, C., Teinturier, S., ten Kate, I., Thomas, P., Thompson, L., Tokar, R., Toplis, M., Redondo, J. T., Trainer, M., Treiman, A., Tretyakov, V., Urqui-O'Callaghan, R., Van Beek, J., Van Beek, T., VanBommel, S., Vaniman, D., Varenikov, A., Vasavada, A., Vasconcelos, P., Vicenzi, E., Vostrukhin, A., Voytek, M., Wadhwa, M., Ward, J., Webster, C., Weigle, E., Wellington, D., Westall, F., Wiens, R. C., Wilhelm, M. B., Williams, A., Williams, J., Williams, R., Williams, R. B. M., Wilson, M., Wimmer-Schweingruber, R., Wolff, M., Wong, M., Wray, J., Wu, M., Yana, C., Yen, A., Yingst, A., Zeitlin, C., Zimdar, R., Mier, M.-P. Z., GeoRessources, Institut national des sciences de l'Univers (INSU - CNRS)-Centre de recherches sur la géologie des matières premières minérales et énergétiques (CREGU)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS), NWO-NSO: The role of perchlorates in the preservation of organic compounds on Mars, and Petrology

Subjects
Multidisciplinary, 010504 meteorology & atmospheric sciences, Water on Mars, Curiosity rover, [SDU.STU]Sciences of the Universe [physics]/Earth Sciences, Mineralogy, Mars, Mars Exploration Program, Martian soil, engineering.material, 01 natural sciences, MSL Mars X-ray Diffraction Mineralogy Rocknest Gale Crater, Meteorite, Impact crater, 13. Climate action, Rocknest, 0103 physical sciences, Pigeonite, engineering, Composition of Mars, MSL, 010303 astronomy & astrophysics, 0105 earth and related environmental sciences, mineralogy of Rocknest at Gale crater
Abstract

The Mars Science Laboratory rover Curiosity scooped samples of soil from the Rocknest aeolian bedform in Gale crater. Analysis of the soil with the Chemistry and Mineralogy (CheMin) x-ray diffraction (XRD) instrument revealed plagioclase (~An57), forsteritic olivine (~Fo62), augite, and pigeonite, with minor K-feldspar, magnetite, quartz, anhydrite, hematite, and ilmenite. The minor phases are present at, or near, detection limits. The soil also contains 27 ± 14 weight percent x-ray amorphous material, likely containing multiple Fe 3+ - and volatile-bearing phases, including possibly a substance resembling hisingerite. The crystalline component is similar to the normative mineralogy of certain basaltic rocks from Gusev crater on Mars and of martian basaltic meteorites. The amorphous component is similar to that found on Earth in places such as soils on the Mauna Kea volcano, Hawaii.

Published
2013
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21. A conceptual design for cosmo-biology experiments in Earth's Orbit

Author

Greenberg, M., Brack, A., Colangeli, L., Horneck, G., Navarro-Gonzalez, R., Raulin, F., Hashimoto, Hirofumi, Kouchi, Akira, Saito, Takeshi, Yamashita, Masamichi, and Kobayashi, Kensei

Subjects
Physics, Earth's orbit, Cosmic Dust, Evolution, Chemical, Extraterrestrial Environment, Photochemistry, Ultraviolet Rays, Weightlessness, Nuclear engineering, Interstellar ice, Ice, General Medicine, Biology, Space Flight, Cold Temperature, Light intensity, Conceptual design, Experimental system, Research Design, International Space Station, Exobiology, Cosmic Radiation, Space environment, Cold trap
Abstract

著者人数: 11名, Accepted: 1998-12-20, 資料番号: SA1004802000

Published
2001

28. Organic carbon concentrations in 3.5-billion-year-old lacustrine mudstones of Mars.

Author

Stern JC, Malespin CA, Eigenbrode JL, Webster CR, Flesch G, Franz HB, Graham HV, House CH, Sutter B, Archer PD Jr, Hofmann AE, McAdam AC, Ming DW, Navarro-Gonzalez R, Steele A, Freissinet C, and Mahaffy PR

Abstract

The Sample Analysis at Mars instrument stepped combustion experiment on a Yellowknife Bay mudstone at Gale crater, Mars revealed the presence of organic carbon of Martian and meteoritic origins. The combustion experiment was designed to access refractory organic carbon in Mars surface sediments by heating samples in the presence of oxygen to combust carbon to CO 2 . Four steps were performed, two at low temperatures (less than ∼550 °C) and two at high temperatures (up to ∼870 °C). More than 950 μg C/g was released at low temperatures (with an isotopic composition of δ 13 C = +1.5 ± 3.8‰) representing a minimum of 431 μg C/g indigenous organic and inorganic Martian carbon components. Above 550 °C, 273 ± 30 μg C/g was evolved as CO 2 and CO (with estimated δ 13 C = -32.9‰ to -10.1‰ for organic carbon). The source of high temperature organic carbon cannot be definitively confirmed by isotopic composition, which is consistent with macromolecular organic carbon of igneous origin, meteoritic infall, or diagenetically altered biomass, or a combination of these. If from allochthonous deposition, organic carbon could have supported both prebiotic organic chemistry and heterotrophic metabolism at Gale crater, Mars, at ∼3.5 Ga.

Published
2022
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29. Radiolysis of aqueous formaldehyde relevant to cometary environments.

Author

Castillo-Rojas S, Landeros JC, Negron-Mendoza A, and Navarro-Gonzalez R

Subjects
Cobalt Radioisotopes, Evolution, Chemical, Formaldehyde radiation effects, Polymers chemistry, Radiation Dosage, Radiochemistry, Water chemistry, Computer Simulation, Formaldehyde chemistry, Gamma Rays, Meteoroids, Models, Chemical
Abstract

The radiation chemistry of aqueous solutions of formaldehyde was studied in order to obtain an insight into the possible role of ionizing radiation on cometary environments. Aqueous solutions of 1.0 mol dm-3 formaldehyde were exposed to gamma-radiation in the dose range from 0.01 to 1200 kGy at 298 K. The radiation chemical yield of decomposition of formaldehyde was determined to be: G(-CH2(OH)2)-26.3 +/- 1.2. The high radiation chemical yield of decomposition was explained by a chain reaction initiated by the radical CH(OH)2 with formaldehyde. Computer fitting of the experimental data gives k(CH(OH)2 + CH2(OH)2)- 8.0xl0(1) dm3 mol-1 s-1. In the computer treatment of experimental findings we used 54 equations to consider the radiolysis of water and 11 reactions for the radiolysis of aqueous formaldehyde. Based on previous estimates of the total dose of ionizing radiation that comets have accumulated over 4.6 billion years, we predict a radiation damage-depth curve of formaldehyde in comet nuclei.

Published
1992
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30. Radiation-induced syntheses in cometary simulated models.

Author

Negron-Mendoza A, Chacon E, Navarro-Gonzalez R, Draganic ZD, and Draganic IG

Subjects
Databases, Factual, Formates chemistry, Formates radiation effects, Hydrocarbons chemical synthesis, Hydrogen Cyanide chemistry, Hydrogen Cyanide radiation effects, Methanol chemistry, Methanol radiation effects, Models, Chemical, Nitriles chemistry, Nitriles radiation effects, Radiochemistry, Water chemistry, Amino Acids chemical synthesis, Carboxylic Acids chemical synthesis, Gamma Rays, Gases chemical synthesis, Meteoroids, Polymers chemical synthesis
Abstract

The behavior of an aqueous-dominant multicomponent cometary model is examined at high doses of ionizing radiation. The system is composed of a water mixture of HCN (0.2 mol dm-3), CH3CN (0.04 mol dm-3), C2H5CN (0.02 mol dm-3), CH3OH (0.12 mol dm-3) and HCO2H (0.01 mol dm-3. It was exposed to gamma rays at doses up to 18.5 MGy. The chemical kinetic database used in the computer treatment of experimental data consists of 79 reactions. A complex mixture of products has been synthesized: gases, amino acids, carboxylic acids and polymeric material. The results suggest that the pristine material in cometary nuclei may have been chemically altered by the action of cosmic rays and embedded radionuclides.

Published
1992
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