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U–Pb ages, trace element content and oxygen isotope ratios of single zircons from five plagiogranite intrusions of the Troodos ophiolite were measured to determine their crystallization age and assess the importance of fractional crystallization versus crustal anatexis in their petrogenesis. The results indicate that oceanic magmatism in Troodos took place at 94·3 ± 0·5 Ma, about 3 Myr earlier than previously recognized. Later hydrothermal alteration has affected most of the Troodos plagiogranitic rocks, resulting in growth of new zircon and/or partial alteration of zircon domains, causing slightly younger apparent crystallization ages. The new age inferred for seafloor spreading and ocean crust accretion in Troodos nearly overlaps that of the Semail ophiolite in Oman (95–96 Ma), strengthening previous indications for simultaneous evolution of both ophiolites in similar tectonic settings. Average δ18O(Zrn) values in the Troodos plagiogranites range between 4·2 and 4·8 ‰. The lower values in this range are lower than those expected in equilibrium with mantle-derived melt (5·3 ± 0·6 ‰), indicating variable contribution from hydrothermally altered, deep-seated oceanic crust in most of the Troodos plagiogranite intrusions. The inferred substantial involvement of crustal component is consistent with the existence of a shallow axial magma chamber, typical of fast-spreading mid-ocean ridge settings, within the Troodos slow-spreading ridge environment. This apparent contradiction may be reconciled by episodically intense magmatism within an otherwise slow, magmatically deprived spreading axis.

The timing and mode of uplift of the Troodos ophiolite are constrained by low-temperature thermochronology combined with geomorphic analysis. Zircon (U-Th)/He and apatite fission track cooling ages in the Troodos plutonic sequence are all Cretaceous (83–106 Ma) and within error of published zircon U-Pb crystallization ages. This indicates early cooling of the oceanic crust and termination of spreading axis magmatism at ~90 Ma. Apatite (U-Th)/He ages decrease with reconstructed crustal depths from ~40 Ma near the top of the sheeted-dike complex to ~4 Ma within the mantle sequence. A prominent inflection point in the age versus depth curve defines the bottom of the exhumed helium partial retention zone and records the onset of rapid exhumation of the main Troodos massif at 6 ± 2 Ma. Inverse thermal modeling supports this conclusion, indicating that the timing of uplift is earlier than previously estimated. The boundaries of the mantle sequence exposed in the core of the Troodos structure closely overlap the boundaries of a concentric zone delineated by high local relief and higher channel steepness indices, indicating differential exhumation and uplift of this area relative to its surroundings. This zone also overlaps with a prominent negative Bouguer gravity anomaly. The timing and pattern of the Troodos ophiolite uplift suggest that it is driven by serpentinite diapirism, possibly triggered by Miocene reactivation of subduction along the Cyprean Arc. The worldwide ubiquity of suprasubduction zone ophiolites may thus reflect the importance of extensive serpentinization at the overthrusting mantle wedge in obduction processes.

21 pages; International audience; The ∼3.5 Ga Dresser Formation from the North Pole Dome of the Pilbara Craton (Western Australia) contains some of the oldest evidence for life on Earth. Here, we present a detailed study of microstructure-specific carbon isotopic composition of organic matter (OM) preserved in Dresser Formation bedded cherts and hydrothermal chert vein using in situ Secondary-Ion Mass Spectrometry (SIMS). The OM in these rocks occurs mainly as clots that, together with minor fine OM layers and laminae, are considered primary textures formed prior to host rock lithification. Other than rare OM-rich stylolites, no evidence was found for later OM migration beyond the micrometer scale. Average δ13C(OM) values in specific microstructural types range between −33.6‰ and −25.7‰. No correlation is seen between measured δ13C values and H/C ratios in the studied OM microstructures. This lack of correlation and the low metamorphic grade of the rocks studied argue against significant modification of OM isotopic composition by later metamorphic alteration. It is thus concluded that the range of δ13C values found in the samples represents primary OM isotopic variability. Within some individual samples variable δ13C(OM) values are correlated with specific microstructural types. This observation is not consistent with solely abiotic OM formation via Fisher-Tropsch type reactions. When compared with associated δ13C(ankerite) values, average δ13C(OM) values indicate C isotopic fractionation [Δ13C(Ank–OM)] of 25–33‰, which translates to dissolved CO2–OM isotopic fractionation [Δ13C(CO2–OM)] of 20–30‰. This range of Δ13C(CO2–OM) is consistent with enzymatic C fixation via the Calvin cycle utilized by photoautotrophs and the reductive acetyl-CoA pathway utilized by chemolithoautotrophs. Photosynthetic OM formation is supported by the relatively shallow water depth inferred for the Dresser environment and the restricted occurrence of stromatolites to shallow water deposits in this unit, whereas chemolithosynthesis is supported by the abundance of OM in sub-seafloor hydrothermal chert veins. The range of δ13C(OM) values observed in the samples may therefore represent the remains of different organisms utilizing different C-fixation pathways. Other biologic effects, such as the growth rate and density of microbial communities, and further heterotrophic overprinting of the autotrophic biomass may have also contributed to the observed range of δ13C(OM) values.

A voluminous Cambrian–Ordovician sequence of quartz-rich sandstones was deposited in northern Gondwana following its assembly by a series of Neoproterozoic–Cambrian orogenic events. Paleocurrent markers indicate that the sediments were carried from Gondwana hinterland toward the supercontinent margins in the north (present coordinates). Derivation from Neoproterozoic terranes is evident from the ubiquity of detrital zircons with Neoproterozoic U-Pb ages, but the exact provenance of these siliciclastic deposits remains unclear. Herein we present new Hf isotopic data from U-Pb dated detrital zircons of the Cambrian–Ordovician sandstone that tops the juvenile Neoproterozoic basement of the Arabian-Nubian Shield in Israel and Jordan. It is remarkable that the detrital zircon Hf isotopic signal is in marked contrast to the Nd and Hf isotopic signature of the underlying basement. A preponderance (61%) of the Neoproterozoic-aged detrital zircons from the Cambrian–Ordovician sandstones yielded negative e Hf(t) values incompatible with a juvenile source. Therefore, most of the detrital zircons were derived from distant terranes comprising pre-Neoproterozoic crust reworked during the assembly of Gondwana, rather than from the adjacent Arabian-Nubian Shield. Because our sampling sites are situated at the northern tip of the Arabian-Nubian Shield, sand must have been transported several thousand kilometers before deposition. This finding also implies that the Arabian-Nubian Shield and other Neoproterozoic orogens of northeast Africa were completely worn down by the onset of Cambrian deposition and that vast areas in the northern part of Gondwana were low lying at that time.

[1] Tertiary convergence, high-pressure−low-temperature (HP-LT) metamorphism and subsequent exhumation in the internal Western Alps were concurrent with detrital deposition in foreland basins at the external periphery of the orogen. In the present work we have probed the geochronology and chemistry of white mica grains and metamorphic pebbles from the foreland basins of SE France in order to gain additional perspective on exhumation rates and mountain building processes in the internal domain of the Tertiary orogen. Our data indicate that throughout the Tertiary these basins were mainly fed from a relatively low pressure source, dominated by Si-poor micas yielding pre-Alpine 40Ar/39Ar ages. Small amounts of detritus composed of high-pressure minerals and pebbles are first detected in early Oligocene (∼30−32 Ma) strata of the Barreme basin. The 40Ar/39Ar geochronology of phengites from garnet-blueschist pebbles from these strata yielded 34 ± 3 Ma ages indicating rapid ascent and exposure of HP-LT rocks in the internal part of the orogen shortly after metamorphism. To explain the preponderance of pre-Alpine micas alongside the rare presence of Alpine HP-LT detritus we suggest that the general architecture of the Western Alps, whereby inner HP-LT metamorphic units are cut off from the SE France basins by a low-grade lid of Brianconnais back thrusts, was rapidly built in the early Oligocene and did not change significantly since then.