1,656 results on '"Oil droplet"'
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2. Oil-water interface and emulsion stabilising properties of rapeseed proteins napin and cruciferin studied by nonlinear surface rheology.
- Author
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Yang, Jack, Shen, Penghui, de Groot, Anteun, Mocking-Bode, Helene C.M., Nikiforidis, Constantinos V., and Sagis, Leonard M.C.
- Subjects
- *
OIL-water interfaces , *RAPESEED , *EMULSIONS , *RHEOLOGY , *PROTEINS , *PLANT proteins - Abstract
[Display omitted] Two major protein families are present in rapeseed, namely cruciferins and napins. The structural differences between the two protein families indicate that they might behave differently when their mixture stabilises oil–water interfaces. Therefore, this work focuses on elucidating the role of both proteins in interface and emulsion stabilisation. Protein molecular properties were evaluated, using SEC, DSC, CD, and hydrophobicity analysis. The oil–water interface mechanical properties were studied using LAOS and LAOD. General stress decomposition (GSD) was used as a novel method to characterise the nonlinear response. Additionally, to evaluate the emulsifying properties of the rapeseed proteins, emulsions were prepared using pure napins or cruciferin and also their mixtures at 1:3, 1:1 and 3:1 (w:w) ratios. Cruciferins formed stiff viscoelastic solid-like interfacial layers (G s ′ = 0.046 mN/m; E d ′ = 30.1 mN/m), while napin formed weaker and more stretchable layers at the oil–water interface (G s ′ = 0.010 mN/m; E d ′ = 26.4 mN/m). As a result, cruciferin-formed oil droplets with much higher stability against coalescence (coalescence index, CI up to 10%) than napin-stabilised ones (CI up to 146%) during two months of storage. Both proteins have a different role in emulsions produced with napin-cruciferin mixtures, where cruciferin provides high coalescence stability, while napin induces flocculation. Our work showed the role of each rapeseed protein in liquid–liquid multiphase systems. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
3. Variability in oil droplet numbers and proportions in the retinas of anole lizards
- Author
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Darlene Campbell and Ellis R. Loew
- Subjects
retina ,cones ,oil droplet ,anole ,lizard ,Zoology ,QL1-991 - Abstract
Colored oil droplets are a common feature in the cones of almost all diurnal lizards. Using white light microscopy, three chromotypes of droplet can be identified in anoles – yellow, green and colorless. These droplets have been associated with different cone classes using microspectrophotometry. The principal member of double cones contain a yellow droplet while the accessory member contains a diffuse yellow pigment. Both members contain the LWS visual pigment. One class of large single cone contains a yellow droplet and the LWS visual pigment. The two remaining classes of large single cone contain the green droplet and either the LWS or MWS visual pigment. As such, by noting the distribution and numbers of the different droplet chromotypes, information about cone distribution, type, and number can be deduced microscopically. Retinas from three anole species (A. cristatellus, A. sagrei, and A. carolinensis) were isolated, flattened and oriented using the two foveae as landmarks. A 19-gauge needle was used to punch out six full-thickness retinal disks from identical retinal regions from both eyes of the three species. The different oil droplets were microscopically identified by color and counted. In all three species at all six retinal areas, the colorless droplets associated with the UVS and SWS single cones represented approximately 10% of the total droplets counted. However, the proportions of the yellow and green droplets were significantly different between the species. For A. cristatellus, 80% of the droplets were green while 10% were yellow. For A. sagrei approximately 85% of the droplets were yellow while only 5% were green. For A. carolinensis 50% of the droplets were yellow while 40% were green. The possible significance of these variable proportions is discussed in terms of possible effects on color vision and ecotype of the three anoles.
- Published
- 2024
- Full Text
- View/download PDF
4. Sonication as a potential tool in the formation of protein-based stable emulsion – Concise review
- Author
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Harsh B. Jadhav, Pintu Choudhary, Parag Gogate, Seema Ramniwas, Robert Mugabi, Zubair Ahmad, Syed Mohammed Basheeruddin Asdaq, and Gulzar Ahmad Nayik
- Subjects
Ultrasound ,Emulsion stability ,Oil in water ,Protein-based emulsion ,Oil droplet ,Emulsifying characteristics ,Chemistry ,QD1-999 ,Acoustics. Sound ,QC221-246 - Abstract
Emulsion systems are extensively used in the food processing sector and the use of natural emulsifiers like proteins for stabilizing emulsion has been in demand from consumers due to increased awareness about the consumption of healthy food. Numerous methods are available for the preparation of emulsion, but ultrasound got more attention among common methods owing to its economical and environment-friendly characteristics. The physical effects caused by to bursting of the cavity bubble, result in reduced droplet size, thus forming an emulsion with appreciable stability. Ultrasound ameliorates the emulsifying characteristics of natural emulsifiers like protein and improves the storage stability of the emulsion by positively boosting the rheological, emulsifying characteristics, improving zeta potential, and reducing average droplet size. The stability of protein-based emulsion is affected by environmental stresses hence conjugate of protein with polysaccharide showed good emulsifying characteristics. However, the data on the effect of ultrasound parameters on emulsifier properties is lacking and there is a need to develop a sonication device that can carry out large-scale emulsification operation. The review covers the principles and mechanisms of ultrasound-assisted formation of protein-based and protein-based conjugate emulsions. Further, the effect of ultrasound on various characteristics of protein-based emulsion is also explored. This review will provide concise data to the researchers to extend their experiments in the area of ultrasound emulsification which will help in commercializing the technology at the industrial scale.
- Published
- 2024
- Full Text
- View/download PDF
5. INVESTIGATING ABSORPTION EFFECTS ON OIL DROPLETS IN ENHANCED OIL RECOVERY: A FORCE ANALYSIS APPROACH
- Author
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Mohammed A. Samba, Yiqiang Li, Zheyu Liu, Ibrahim A. Amar, Muslim Abdurrahman, and Peter O. Anyimah
- Subjects
oil droplet ,gravity force ,capillary force ,corner flow ,spinel oxide nanoparticle ,Mining engineering. Metallurgy ,TN1-997 ,Geology ,QE1-996.5 - Abstract
This research aims to analyze the forces that affect oil droplets to illustrate that augmenting the mass of an oil droplet fosters favorable conditions for interaction between displaced and displacing fluids. This, in turn, impedes the bypassing of the displacing fluid around the oil droplets. In this investigation, the concept of augmenting the mass of an oil droplet is realized through absorption phenomena, employing coated spinel oxide (cobalt ferrite oxide) nanoparticles (CFO NPs). The synthesis of CFO NPs was successfully carried out in the laboratory using a sol-gel technique, followed by coating with a surfactant and lauric acid. The coated spinel oxide NPs underwent characterization using IR, XRD, and XRF techniques. The procedures started with the calculation of capillary force restrictions for small and large oil droplets. Furthermore, practical experiments involving oil droplets on glass plates at a 30° angle were conducted for different scenarios: without water injection, with water injection, and during the “absorption effect” of CFO NPs. The findings revealed that a large oil droplet exhibits lower capillary pressure restrictions compared to a small oil droplet, with a disparity of 0.02 m/s2 . Consequently, it is comparatively easier for large oil droplets to become free than small ones. Moreover, a large oil droplet exhibits faster movement than small oil droplets due to gravitational effects in the absence of any injections. During the water injection scenario, the water droplets were unable to displace the oil droplet; instead, they passed through the passage beside and above the oil droplet consistently with an increase in the amount of water droplets. However, in the coated CFO NPs scenario, absorption of the coated CFO NPs onto the oil droplet was observed. This resulted in the aggregation of oil molecules, augmenting the gravity of the oil droplet and creating favourable conditions for its displacement. Notably, no water bypass beside the oil droplet was observed in this scenario, unlike the water scenario. Additionally, the aggregation of oil molecules induced corner flow, providing conducive conditions for microemulsion formation, altering wettability, modifying residual oil saturation, and enhancing injection performance. Euler’s equation was employed to analyse corner flow, indicating that the level of oil deformation increases with the rising rotation velocity, potentially leading to an increased recovery factor.
- Published
- 2024
- Full Text
- View/download PDF
6. Image of a thawed frozen specimen obtained using a cryoprobe floated with oil droplets in normal saline: An endobronchial lipomatous hamartoma image
- Author
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Yuki Takigawa, Ken Sato, Tomoyoshi Inoue, Masahiro Takada, and Keiichi Fujiwara
- Subjects
cryoprobe ,endobronchial lipomatous hamartoma ,floating tumour ,oil droplet ,thawed frozen specimen ,Diseases of the respiratory system ,RC705-779 - Abstract
Key message Hereby, we present a rare case of a resected endobronchial tumour that floated or showed oil droplets in saline. In this study, we report an interesting image related to endobronchial lipomatous hamartoma cryotherapy.
- Published
- 2024
- Full Text
- View/download PDF
7. Measurement of a Three-Dimensional Rotating Flow Field and Analysis of the Internal Oil Droplet Migration.
- Author
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Xing, Lei, Guan, Shuai, Gao, Yang, and Jiang, Minghu
- Subjects
- *
THREE-dimensional flow , *PARTICLE image velocimetry , *PETROLEUM - Abstract
Investigating the motion of discrete oil droplets in a rotating flow field can provide a theoretical basis for optimizing the flow field and structural parameters of hydrocyclones and centrifugal separation equipment. In the present work, the particle image velocimetry (PIV) method was applied to study the velocity distribution of a three-dimensional axial-rotor-driven rotating flow field and the influence of the velocity distribution of different rotor speeds on the flow field. The radial migration of oil droplets with different particle sizes in the rotating flow field was visually analyzed using high-speed video (HSV). The results showed that the oil droplets with the same radial position had diameters of 2.677 and 4.391 mm, whereas the movement times to the axis were 0.902 and 0.752 s. The larger the oil droplet size, the shorter the time to move to the axial center of the rotating flow field. The radial velocities of oil droplets with diameters of 2.677 and 2.714 mm were 0.0221 and 0.02 m·s−1, respectively. In addition, a mathematical expression was established between the radial migration time and the oil droplet size in the rotating flow field. The accuracy of the proposed expression was verified using experiments. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
8. Effect of Salinity and Temperature on the Dispersion of Spilled Oil in the Presence of Microplastics.
- Author
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Gao, Huan, Qi, Zhixin, Yu, Xinping, An, Yaya, Liu, Ziyue, Yang, Miao, and Xiong, Deqi
- Subjects
MICROPLASTICS ,TEMPERATURE effect ,OCEAN waves ,PETROLEUM ,OIL spills ,POLYSTYRENE - Abstract
Both oil spill and microplastics (MPs) are major issues in marine environments. After a spill, the oil film may disperse into the water column as droplets under the function of sea waves. The oil dispersion may be affected due to the attachment of oil to MPs. In this paper, the impacts of salinity and temperature on the dispersion of spilled oil in the presence of MPs were individually studied by batch conical flask oscillation experiments. The results indicated that the rise in salinity or temperature displayed a more significant effect on promoting, rather than inhibiting, oil dispersion with MPs. When the salinity rose from 15% to 35%, the oil dispersion efficiency (ODE) with the 13 μm polyethylene (PE) and polystyrene (PS) MPs was increased by 10.4% and 12.9%, respectively; when the temperature rose from 10 °C to 25 °C, the corresponding ODE was increased by 15.6% and 12.7%, respectively. In addition, the volumetric mean diameter (VMD) of the dispersed oil droplets decreased with an increase in salinity or temperature. Furthermore, the 13 μm MPs showed a higher impact on the oil dispersion than 106 μm of MPs, and the ODE with PE MPs was greater than that with PS MPs. The findings of this study expanded the understanding of the migration of spilled oil in seawater in the presence of MPs and may further improve the capability of predicting the impact of oil spills by marine environment managers. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
9. Hydrophilic Silica Nanoparticles in O/W Emulsion: Insights from Molecular Dynamics Simulation.
- Author
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Liu, Shasha, Zhang, Hengming, and Yuan, Shiling
- Subjects
- *
MOLECULAR dynamics , *SILICA nanoparticles , *EMULSIONS , *PETROLEUM distribution , *SINGLE nucleotide polymorphisms , *HYDROPHILIC interactions - Abstract
Previous studies have been carried out on the effect of silica nanoparticles (SNPs) on the stability of oil–water emulsions. However, the combining configuration of SNPs and oil droplets at the molecular level and the effect of SNP content on the coalescence behavior of oil droplets cannot be obtained through experiments. In this paper, molecular dynamics (MD) simulation was performed to investigate the adsorption configuration of hydrophilic SNPs in an O/W emulsion system, and the effect of adsorption of SNPs on coalescence of oil droplets. The simulation results showed: (i) SNPs adsorbed on the surface of oil droplets, and excessive SNPs self-aggregated and connected by hydrogen bonds. (ii) Partially hydrophilic asphaltene and resin molecules formed adsorption configurations with SNPs, which changed the distribution of oil droplet components. Furthermore, compared with hydrophobic asphaltene, the hydrophilic asphaltene was easier to combine with SNPs. (iii) SNPs would extend the oil droplet coalescence time, and the π–π stacking structures were formed between asphaltene and asphaltene or resin molecules to enhance the connection between oil droplets during the oil droplet contact process. (iv) Enough SNPs tightly wrapped around the oil droplet, similar to the formation of a rigid film on the surface of an oil droplet, which hindered the contact and coalescence of components between oil droplets. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
10. Measurement of a Three-Dimensional Rotating Flow Field and Analysis of the Internal Oil Droplet Migration
- Author
-
Lei Xing, Shuai Guan, Yang Gao, and Minghu Jiang
- Subjects
rotating flow field ,oil droplet ,PIV ,velocity ,diameter ,Technology - Abstract
Investigating the motion of discrete oil droplets in a rotating flow field can provide a theoretical basis for optimizing the flow field and structural parameters of hydrocyclones and centrifugal separation equipment. In the present work, the particle image velocimetry (PIV) method was applied to study the velocity distribution of a three-dimensional axial-rotor-driven rotating flow field and the influence of the velocity distribution of different rotor speeds on the flow field. The radial migration of oil droplets with different particle sizes in the rotating flow field was visually analyzed using high-speed video (HSV). The results showed that the oil droplets with the same radial position had diameters of 2.677 and 4.391 mm, whereas the movement times to the axis were 0.902 and 0.752 s. The larger the oil droplet size, the shorter the time to move to the axial center of the rotating flow field. The radial velocities of oil droplets with diameters of 2.677 and 2.714 mm were 0.0221 and 0.02 m·s−1, respectively. In addition, a mathematical expression was established between the radial migration time and the oil droplet size in the rotating flow field. The accuracy of the proposed expression was verified using experiments.
- Published
- 2023
- Full Text
- View/download PDF
11. Sonication as a potential tool in the formation of protein-based stable emulsion – Concise review.
- Author
-
Jadhav, Harsh B., Choudhary, Pintu, Gogate, Parag, Ramniwas, Seema, Mugabi, Robert, Ahmad, Zubair, Mohammed Basheeruddin Asdaq, Syed, and Ahmad Nayik, Gulzar
- Subjects
- *
SONICATION , *EMULSIONS , *POLYSACCHARIDES , *FOOD consumption , *FOOD industry , *RESEARCH personnel - Abstract
• Proteins can be used as emulsifiers due to their amphiphilic nature. • Cavitation events in sonication reduce the droplet size of the emulsion and enhance its stability. • Ultrasound ameliorates the emulsifying characteristics of natural emulsifiers like protein and improves the storage stability of the emulsion. • The study on sonication-assisted formation of protein-based stable emulsion is still limited. Emulsion systems are extensively used in the food processing sector and the use of natural emulsifiers like proteins for stabilizing emulsion has been in demand from consumers due to increased awareness about the consumption of healthy food. Numerous methods are available for the preparation of emulsion, but ultrasound got more attention among common methods owing to its economical and environment-friendly characteristics. The physical effects caused by to bursting of the cavity bubble, result in reduced droplet size, thus forming an emulsion with appreciable stability. Ultrasound ameliorates the emulsifying characteristics of natural emulsifiers like protein and improves the storage stability of the emulsion by positively boosting the rheological, emulsifying characteristics, improving zeta potential, and reducing average droplet size. The stability of protein-based emulsion is affected by environmental stresses hence conjugate of protein with polysaccharide showed good emulsifying characteristics. However, the data on the effect of ultrasound parameters on emulsifier properties is lacking and there is a need to develop a sonication device that can carry out large-scale emulsification operation. The review covers the principles and mechanisms of ultrasound-assisted formation of protein-based and protein-based conjugate emulsions. Further, the effect of ultrasound on various characteristics of protein-based emulsion is also explored. This review will provide concise data to the researchers to extend their experiments in the area of ultrasound emulsification which will help in commercializing the technology at the industrial scale. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
12. Effect of Salinity and Temperature on the Dispersion of Spilled Oil in the Presence of Microplastics
- Author
-
Huan Gao, Zhixin Qi, Xinping Yu, Yaya An, Ziyue Liu, Miao Yang, and Deqi Xiong
- Subjects
oil spill ,microplastics ,oil dispersion efficiency ,volumetric mean diameter ,oil droplet ,Naval architecture. Shipbuilding. Marine engineering ,VM1-989 ,Oceanography ,GC1-1581 - Abstract
Both oil spill and microplastics (MPs) are major issues in marine environments. After a spill, the oil film may disperse into the water column as droplets under the function of sea waves. The oil dispersion may be affected due to the attachment of oil to MPs. In this paper, the impacts of salinity and temperature on the dispersion of spilled oil in the presence of MPs were individually studied by batch conical flask oscillation experiments. The results indicated that the rise in salinity or temperature displayed a more significant effect on promoting, rather than inhibiting, oil dispersion with MPs. When the salinity rose from 15% to 35%, the oil dispersion efficiency (ODE) with the 13 μm polyethylene (PE) and polystyrene (PS) MPs was increased by 10.4% and 12.9%, respectively; when the temperature rose from 10 °C to 25 °C, the corresponding ODE was increased by 15.6% and 12.7%, respectively. In addition, the volumetric mean diameter (VMD) of the dispersed oil droplets decreased with an increase in salinity or temperature. Furthermore, the 13 μm MPs showed a higher impact on the oil dispersion than 106 μm of MPs, and the ODE with PE MPs was greater than that with PS MPs. The findings of this study expanded the understanding of the migration of spilled oil in seawater in the presence of MPs and may further improve the capability of predicting the impact of oil spills by marine environment managers.
- Published
- 2023
- Full Text
- View/download PDF
13. Study on the Performance of a Designed Annular Piezoelectric Microjet for Active Lubrication of Space Bearing.
- Author
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Li, Kai, Liu, Yingxiang, Liu, Junkao, and Chen, Weishan
- Subjects
- *
LUBRICATION systems , *SERVICE life , *PERFORMANCE theory , *PIEZOELECTRIC actuators , *LUBRICATING oils - Abstract
Lubrication failure of bearing is one of the important factors that limit the service life of the space shafting system. Due to the strict restrictions on the volume and weight, the traditional oil supply devices are difficult to meet the requirements of space active lubrication. In this article, we propose a piezoelectric microjet, which can achieve active lubricating for bearings of space equipment serving in a harsh environment. A constant pressure oil storage system, with a storage capacity of more than 4 g and can achieve vacuum oil storage, is proposed. Control accuracy of 0.012 μL per pulse is obtained and a theoretical service life of more than 20 years can be achieved. The whole active lubricating system is embedded in the bearing system, which has no effect on the normal operating of the original bearing system and almost creates no mass increment of the bearing system. The methods of controlling the characteristics of the ejected oil droplet are proposed to meet different lubrication requirements. Combined with the monitoring of bearing temperature and friction torque, active lubrication on demand can be realized. This work can provide important references for prolonging the service life of space bearing. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
14. Self-Propelled Motion of an Oil Droplet Containing a Phospholipid and its Stability in Collectivity
- Author
-
Masaki Itatani and Hideki Nabika
- Subjects
nonlinear science ,active matter ,phospholipid ,self-propelled motion ,oil droplet ,surface chemistry ,Physics ,QC1-999 - Abstract
Collective cell migration (CCM) is a universal process that is responsible for various biological phenomena in living organisms. Therefore, unraveling the mechanism of CCM is critical for understanding the principles underlying such processes and for their application in biomaterials and biomedical science. Among these phenomena, unjamming/jamming transitions are particularly intriguing as they are controlled by three factors: cell motility, cell density, and cell–cell adhesion. However, there is no experimental system to independently demonstrate and control these effects. In this study, we added 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) to a nitrobenzene droplet containing KI and I2 to develop a prototype system that shows self-propelled motion in an aqueous trimethylstearylammonium chloride (TSAC) solution. First, we explored the relationship between the motility of the droplet and experimental parameters, namely, the concentrations of TSAC, I2, and DMPC and droplet size. The droplet showed directional motion driven by Marangoni convection owing to a solubilization promoted by the formation of mixed micelles filled with oil between DMPC and TSA+; notably, droplet motility could be controlled by each parameter. Furthermore, the interfacial tension (γ) at the oil–water interface, measured using the pendant drop method, indicated that each parameter contributed to changes in γ. Based on our experimental results, we inferred that the dynamics of the insertion of TSA+ in the aqueous phase into the self-assembled DMPC membrane covering the nitrobenzene droplet, as well as the solubilization, are important factors that trigger Marangoni convection and lead to controlled droplet motility. Furthermore, the developed droplets remained stable in a confluent state, wherein they were in contact with each other and exhibited various polygonal shapes depending on their size and density because they were protected by a robust self-assembled DMPC membrane layer. The results indicated that the density and the morphology of the droplets are controllable in this system, and that they indirectly altered droplet adhesion. Thus, we procured a prototype system that could be controlled independently using three parameters to elucidate phase transition for CCM. This system can be biomodified through the combination of phospholipids with any biomolecule and can enable a more precise evaluation of the CCM exhibited by living cells.
- Published
- 2022
- Full Text
- View/download PDF
15. Image of a thawed frozen specimen obtained using a cryoprobe floated with oil droplets in normal saline: An endobronchial lipomatous hamartoma image.
- Author
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Takigawa, Yuki, Sato, Ken, Inoue, Tomoyoshi, Takada, Masahiro, and Fujiwara, Keiichi
- Subjects
- *
PETROLEUM , *HAMARTOMA , *COLD therapy , *TUMORS - Abstract
Key message: Hereby, we present a rare case of a resected endobronchial tumour that floated or showed oil droplets in saline. In this study, we report an interesting image related to endobronchial lipomatous hamartoma cryotherapy. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
16. Hydrophilic Silica Nanoparticles in O/W Emulsion: Insights from Molecular Dynamics Simulation
- Author
-
Shasha Liu, Hengming Zhang, and Shiling Yuan
- Subjects
silica nanoparticles ,oil droplet ,adsorption ,coalescence ,molecular simulations ,Organic chemistry ,QD241-441 - Abstract
Previous studies have been carried out on the effect of silica nanoparticles (SNPs) on the stability of oil–water emulsions. However, the combining configuration of SNPs and oil droplets at the molecular level and the effect of SNP content on the coalescence behavior of oil droplets cannot be obtained through experiments. In this paper, molecular dynamics (MD) simulation was performed to investigate the adsorption configuration of hydrophilic SNPs in an O/W emulsion system, and the effect of adsorption of SNPs on coalescence of oil droplets. The simulation results showed: (i) SNPs adsorbed on the surface of oil droplets, and excessive SNPs self-aggregated and connected by hydrogen bonds. (ii) Partially hydrophilic asphaltene and resin molecules formed adsorption configurations with SNPs, which changed the distribution of oil droplet components. Furthermore, compared with hydrophobic asphaltene, the hydrophilic asphaltene was easier to combine with SNPs. (iii) SNPs would extend the oil droplet coalescence time, and the π–π stacking structures were formed between asphaltene and asphaltene or resin molecules to enhance the connection between oil droplets during the oil droplet contact process. (iv) Enough SNPs tightly wrapped around the oil droplet, similar to the formation of a rigid film on the surface of an oil droplet, which hindered the contact and coalescence of components between oil droplets.
- Published
- 2022
- Full Text
- View/download PDF
17. Experimental investigation of free-rising characteristics of spilled oil droplets in natural waters.
- Author
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Jiang, Anqi, Han, Longxi, Wang, Chenfang, and Niu, Xiangming
- Subjects
- *
TERMINAL velocity , *DRAG coefficient , *PETROLEUM , *PETROLEUM sales & prices , *REYNOLDS number - Abstract
• Systematic study of the rising motion of oil droplets in natural waters. • Discovered that oil droplet properties affect the rising motion process. • Modeling the terminal velocity of oil droplets in natural waters. • Modeling the drag coefficient of oil droplets in natural waters. This work focuses on investigating the dynamics of different types of oil droplets rising freely in water columns. Fifteen different types of oils were selected to cover most of the conventional oils. The particle size range of the study is 1.41∼13.58 mm, which can cover the largest oil droplet size that may occur in the real environment. Investigation results show that oil droplet characteristics greatly influence the dynamics process of oil droplet motion. The characteristics which play a dominant role will change as the oil droplet particle size increases. Meanwhile, a set of computational models applicable to the terminal velocity and drag coefficient of oil droplets in the range of 20 < Re < 1200 in a non-pure system are obtained by organizing the experimental data and comparing with the traditional correlation equation, respectively. The models involve dimensionless parameters such as Eo, Mo, and We numbers with fitting coefficients up to 0.984. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
18. Characterization of essential oil distribution in the root cross-section of Valeriana officinalis L. s.l. by using histological imaging techniques
- Author
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Michael Penzkofer, Andrea Baron, Annette Naumann, Andrea Krähmer, Hartwig Schulz, and Heidi Heuberger
- Subjects
Valerian ,Medicinal plant ,Root slice ,Thin-section ,Oil droplet ,Fluorescence-microscopy ,Plant culture ,SB1-1110 ,Biology (General) ,QH301-705.5 - Abstract
Abstract Background The essential oil is an important compound of the root and rhizome of medicinally used valerian (Valeriana officinalis L. s.l.), with a stated minimum content in the European pharmacopoeia. The essential oil is located in droplets, of which the position and distribution in the total root cross-section of different valerian varieties, root thicknesses and root horizons are determined in this study using an adapted fluorescence-microscopy and automatic imaging analysis method. The study was initiated by the following facts:A probable negative correlation between essential oil content and root thickness in selected single plants (elites), observed during the breeding of coarsely rooted valerian with high oil content.Higher essential oil content after careful hand-harvest and processing of the roots. Results In preliminary tests, the existence of oil containing droplets in the outer and inner regions of the valerian roots was confirmed by histological techniques and light-microscopy, as well as Fourier-transform infrared spectroscopy. Based on this, fluorescence-microscopy followed by image analysis of entire root cross-sections, showed that a large number of oil droplets (on average 43% of total oil droplets) are located close to the root surface. The remaining oil droplets are located in the inner regions (parenchyma) and showed varying density gradients from the inner to the outer regions depending on genotype, root thickness and harvesting depth. Conclusions Fluorescence-microscopy is suitable to evaluate prevalence and distribution of essential oil droplets of valerian in entire root cross-sections. The oil droplet density gradient varies among genotypes. Genotypes with a linear rather than an exponential increase of oil droplet density from the inner to the outer parenchyma can be chosen for better stability during post-harvest processing. The negative correlation of essential oil content and root thickness as observed in our breeding material can be counteracted through a selection towards generally high oil droplet density levels, and large oil droplet sizes independent of root thickness.
- Published
- 2018
- Full Text
- View/download PDF
19. Coalescence and Separation Properties of Fine Oil Droplets by Lipophilic Nanofiber Membrane.
- Author
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Yasuhit, MUKAI and Motoki, HARA
- Abstract
A coalescer is a useful device for removing oil from oil-in-water (O/W) emulsion, but it is unsuitable for the coalescence of fine oil droplets less than 10 pm. In this study, a nanofiber membrane was applied as a fibrous layer equipped in the coalescer to coalesce the fine oil droplets less than 10 pm, and the lipophilic polypropylene nanofiber membrane was selected in consideration of an affinity for oil. The O/W emulsion including the fine oil droplets was permeated through the membrane for evaluating the coalescence properties of fine oil droplets. In the initial stage of permeation, the oil droplets were strongly attracted to the lipophilic surface of nanofibers, and a thin oil film was formed on the entire fiber surface. Subsequent oil droplets were incorporated into the oil film, resulting in the growth of the oil film. When the fibers could no longer hold fully grown oil film, excess oil film was finally released from the outlet of the membrane. The released oil pieces floated and formed an oil layer on the surface of permeated fluid. In the steady state, the separation ratio of 83.3 % was observed under low pressure loss of 17 kPa. The size distribution data of droplets in the permeated fluid clearly demonstrated that the polypropylene nanofiber membrane used in this study could completely coalesce and separate the fine oil droplets of 2 to 10 gni. [ABSTRACT FROM AUTHOR]
- Published
- 2020
- Full Text
- View/download PDF
20. Measurement of a Three-Dimensional Rotating Flow Field and Analysis of the Internal Oil Droplet Migration
- Author
-
Jiang, Lei Xing, Shuai Guan, Yang Gao, and Minghu
- Subjects
rotating flow field ,oil droplet ,PIV ,velocity ,diameter - Abstract
Investigating the motion of discrete oil droplets in a rotating flow field can provide a theoretical basis for optimizing the flow field and structural parameters of hydrocyclones and centrifugal separation equipment. In the present work, the particle image velocimetry (PIV) method was applied to study the velocity distribution of a three-dimensional axial-rotor-driven rotating flow field and the influence of the velocity distribution of different rotor speeds on the flow field. The radial migration of oil droplets with different particle sizes in the rotating flow field was visually analyzed using high-speed video (HSV). The results showed that the oil droplets with the same radial position had diameters of 2.677 and 4.391 mm, whereas the movement times to the axis were 0.902 and 0.752 s. The larger the oil droplet size, the shorter the time to move to the axial center of the rotating flow field. The radial velocities of oil droplets with diameters of 2.677 and 2.714 mm were 0.0221 and 0.02 m·s−1, respectively. In addition, a mathematical expression was established between the radial migration time and the oil droplet size in the rotating flow field. The accuracy of the proposed expression was verified using experiments.
- Published
- 2023
- Full Text
- View/download PDF
21. Building a multipurpose insertional mutant library for forward and reverse genetics in Chlamydomonas
- Author
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Xi Cheng, Gai Liu, Wenting Ke, Lijuan Zhao, Bo Lv, Xiaocui Ma, Nannan Xu, Xiaoling Xia, Xuan Deng, Chunlei Zheng, and Kaiyao Huang
- Subjects
Chlamydomonas ,Insertional mutants ,Mutant library ,Flagella ,Intraflagellar transport ,Oil droplet ,Plant culture ,SB1-1110 ,Biology (General) ,QH301-705.5 - Abstract
Abstract Background The unicellular green alga, Chlamydomonas reinhardtii, is a classic model for studying flagella and biofuel. However, precise gene editing, such as Clustered Regularly Interspaced Short Palindromic Repeats (CRISPR) and CRISPR-associated protein (Cas9) system, is not widely used in this organism. Screening of random insertional mutant libraries by polymerase chain reaction provides an alternate strategy to obtain null mutants of individual gene. But building, screening, and maintaining such a library was time-consuming and expensive. Results By selecting a suitable parental strain, keeping individual mutants using the agar plate, and designing an insertion cassette-specific primer for library screening, we successfully generated and maintained ~150,000 insertional mutants of Chlamydomonas, which was used for both reverse and forward genetics analysis. We obtained 26 individual mutants corresponding to 20 genes and identified 967 motility-defect mutants including 10 mutants with defective accumulation of intraflagellar transport complex at the basal body. We also obtained 929 mutants defective in oil droplet assembly after nitrogen deprivation. Furthermore, a new insertion cassette with splicing donor sequences at both ends was also constructed, which increased the efficiency of gene interruption. Conclusion In summary, this library provides a multifunctional platform both for obtaining mutants of interested genes and for screening of mutants with specific phenotype.
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- 2017
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22. Translational velocity of a charged oil droplet close to a horizontal solid surface under an applied electric field.
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Wang, Chengfa, Song, Yongxin, Pan, Xinxiang, and Li, Dongqing
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- *
DROPLETS , *ZETA potential , *TRANSLATIONAL motion , *ELECTRIC fields , *MATHEMATICAL models - Abstract
Highlights • The interactions between an oil droplet and a horizontal solid surface was analyzed. • There is a separation distance between an oil droplet and a solid surface. • The droplet and solid surface zeta potentials affect the droplet moving direction. • The droplet moving velocity increases with the decrease of the separation distance. Abstract This work numerically investigated the translational velocity of a negatively charged oil droplet in the water near a negatively charged solid surface under a DC electric field. The equilibrium separation distance between the charged oil droplet and the charged solid surface is calculated under different parameters and the translational motion of the droplet near the solid surface is simulated via a three-dimensional mathematical model. The results indicate that the velocity of the droplet is higher under a larger zeta potential of the solid surface and a smaller zeta potential of the droplet. When the absolute value of the negative zeta potential of the droplet is larger than that of the solid surface, the droplet will move in opposite direction of the electric field. It is also found that the droplet translational velocity increases with the decrease of the separation distance between the oil droplet and the solid surface. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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23. Behaviors of a micro oil droplet in an EHL contact
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Xinming Li, Feng Guo, Shaopeng Wang, Chenglong Liu, and Wenzhong Wang
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oil droplet ,spreading ,elastohydrodynamic lubrication ,optical interferometry ,Mechanical engineering and machinery ,TJ1-1570 - Abstract
Abstract Oil–air lubrication supplies lubricants in the form of droplets to elastohydrodynamic lubrication (EHL) contacts, such as those in high-speed spindle bearings. However, there is a paucity of information related to understanding the lubrication behaviors of oil droplets within EHL contacts. In this study, behaviors of lubricant droplets, in terms of spreading around a static contact as well as passing through a rolling contact, were studied with an optical ball-on-disk EHL test rig. Influences of oil droplet size, viscosity, and surface tension on droplet spreading were examined. Lubricating film formation was also investigated when droplets traveled through the EHL contact region. The results indicated that droplet size and running speed significantly influenced film profiles. With increasing entrainment speeds, a small droplet passed through the contact without spreading and generated films with a significant depression in the central contact region.
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- 2016
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24. A rheological investigation of oil-in-water Pickering emulsions stabilized by cellulose nanocrystals
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Wadood Y. Hamad, Chuanwei Miao, and Mehr-Negar Mirvakili
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Materials science ,Aqueous two-phase system ,Water ,Nanoparticle ,Pickering emulsion ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Biomaterials ,symbols.namesake ,Colloid and Surface Chemistry ,Pulmonary surfactant ,Rheology ,Chemical engineering ,Oil droplet ,Emulsion ,symbols ,Nanoparticles ,Emulsions ,van der Waals force ,Cellulose - Abstract
Hypothesis High and medium internal phase Pickering emulsions stabilized with cellulose nanocrystals (CNCs) exhibited very different performance compared to their peers stabilized with a surfactant. In this paper, we ascribed the difference to the formation of hydrogen bonding and van der Waals interactions between the CNC nanoparticles on adjacent oil droplets. Experiments Rheological properties of CNC-stabilized oil-in-water medium internal phase emulsions (MIPEs, oil content = 65% v/v) and high internal phase emulsions (HIPEs, oil content = 80% v/v) were comprehensively characterized using both oscillatory and rotational tests. Findings It was found that in the MIPEs, the van der Waals and hydrogen bonding interactions dominate the emulsion properties, whereas the compact structure of oil droplets plays a more important role in the HIPEs. CNC concentration in the aqueous phase also affects the emulsion properties, especially for the HIPEs, and the results can be correlated to the stabilization mechanisms we previously reported. The information from these tests provides a much-needed guidance for the practical application of CNC-stabilized emulsions.
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- 2022
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25. Analysis of the Influencing Factors on Oil Removal Efficiency in Large-Scale Flotation Tanks: Experimental Observation and Numerical Simulation
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Qian Huang and Xueyuan Long
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oil removal efficiency ,flotation tank ,computational fluid dynamics ,oil droplet ,gas bubble ,Technology - Abstract
A modified computational fluid dynamic (CFD) model has been developed to obtain oil removal efficiency for oily wastewater treatment in large-scale flotation tanks. According to the investigation of oil droplet/bubble interactions in a flotation tank, a modified Bloom−Heindel model is used to calculate the collision and attachment efficiencies between oil droplets and bubbles. Effects of the gas flow rate, oil diameter and oil concentration on oil removal efficiency of flotation tank were analyzed experimentally. The application scope of this modified CFD model is evaluated using experimental results. In addition, the comparison between the existing model and the modified model demonstrates that this modified CFD model can make a good prediction for the separation performance of the flotation tank.
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- 2020
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26. Diagnosing the oil drop: A case report and review of the literature
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Riddhi J Chhapan, Revathi Yerramneni, and Muralidhar Ramappa
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Metabolic cataract ,galactosemia ,Oil droplet ,Ophthalmology ,RE1-994 - Published
- 2019
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27. Numerical Simulation of Monodisperse Lube Oil Multiple Droplet Evaporation and Autoignition under Nonconstant Cylinder Conditions of Low-Speed Two-Stroke Gas Engines
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Ping Yi, Zhen Gong, Liyan Feng, Zixin Wang, and Wenjing Qu
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endocrine system ,Materials science ,Computer simulation ,General Chemical Engineering ,Dispersity ,technology, industry, and agriculture ,Autoignition temperature ,General Chemistry ,Mechanics ,complex mixtures ,eye diseases ,Article ,law.invention ,Cylinder (engine) ,Chemistry ,Low speed ,law ,Oil droplet ,Droplet evaporation ,Two-stroke engine ,QD1-999 - Abstract
The possibility of lube oil droplets’ existence in cylinders for two-stroke low-speed gas engines is higher because of the much higher lube oil consumption rate. Some droplets are directly injected into cylinders by lube oil injectors, and some are blown into cylinders through the scavenging ports. Autoignition of cylinder oil droplets is the main cause of preignition. This research study indicates that under in-cylinder conditions, overlarge single droplets cannot autoignite due to the long evaporation time, and overly small single droplets cannot autoignite because of the low vapor concentration. To find out what kinds of oil droplet groups could autoignite and cause preignition, 3-D computational fluid dynamics simulation in OpenFOAM was carried out. The model predictions were validated against the experimental results, including the evaporation rate of n-heptane droplets and the ignition delay of lube oil droplets. Also, the simulation was used to investigate the characteristics of multiple droplets under different ambient temperatures and pressures. The evaporation lifetime and the ignition delay of a large single droplet are dozens of times longer than that of multiple droplets, which confirms that the droplet group is more dangerous than a large single droplet. The evaporation rate and ignition delay are affected by the distance and number of droplets. A larger number causes a lower average evaporation rate. A smaller distance causes a shorter ignition delay. The local vapor concentration and temperature could be greatly reduced due to the existence of multiple evaporation and ignition cores. Additionally, these findings of multiple droplets were confirmed under nonconstant cylinder conditions of a natural gas engine. This research provides a guide to design the lube oil injectors and scavenging ports so as to reduce the preignition caused by lube oil autoignition.
- Published
- 2021
28. Experimental evidence of a transition from a sponge-like to a foam-like nanostructure in water-rich L3 phases
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Cosima Stubenrauch, Natalie Preisig, Philipp Menold, and Reinhard Strey
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Materials science ,Nanostructure ,Aqueous two-phase system ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,law.invention ,Biomaterials ,Colloid and Surface Chemistry ,Polymerization ,Chemical engineering ,law ,Oil droplet ,Phase (matter) ,Microemulsion ,Electron microscope ,0210 nano-technology ,Phase diagram - Abstract
Hypothesis The micrometer-sized gas bubbles of a liquid foam with a dispersed gas phase of > 74 vol% are polyhedral and surrounded by a continuous aqueous phase. The structure of a water-rich microemulsion with a water phase of > 74 vol% normally consists of oil droplets in water or is bicontinuous. We hypothesize that at these high water contents polyhedral water droplets in oil can also exist. Experiments We (a) carried out phase studies on the water-rich side of the phase diagram of the quaternary system water/NaCl – hexyl methacrylate – AOT, because AOT is known for its propensity to form water-in-oil structures and hexyl methacrylate can be polymerized, (b) measured the electrical conductivities and viscosities, and (c) visualized the nanostructure with freeze-fracture electron microscopy (FFEM). Findings We found narrow 1-phase regions emanating from the L3 phase of the oil-free water/NaCl – AOT system by adding small amounts of oil. In these regions the conductivities become extremely low and the viscosities are extremely high. In addition, FFEM images clearly show the foam-like nanostructure.
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- 2021
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29. A comparison of emulsifiers for the formation of oil-in-water emulsions: stability of the emulsions within 9 h after production and MR signal properties
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Jürgen Machann, Rolf Daniels, Victor Fritz, Fritz Schick, and Petros Martirosian
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Polysorbate ,Relaxometry ,Aqueous solution ,food.ingredient ,Chromatography ,Radiological and Ultrasound Technology ,Dwi ,Emulsifiers ,Fat Water Mri ,Oil-in-water Emulsions ,Biophysics ,Aqueous two-phase system ,Polysorbates ,Water ,Magnetic Resonance Imaging ,Lecithin ,chemistry.chemical_compound ,Creaming ,food ,chemistry ,Emulsifying Agents ,Oil droplet ,Lecithins ,Emulsions ,Radiology, Nuclear Medicine and imaging ,Particle Size ,Sodium dodecyl sulfate - Abstract
Objective To provide a basis for the selection of suitable emulsifiers in oil-in-water emulsions used as tissue analogs for MRI experiments. Three different emulsifiers were investigated with regard to their ability to stabilize tissue-like oil-in-water emulsions. Furthermore, MR signal properties of the emulsifiers themselves and influences on relaxation times and ADC values of the aqueous phase were investigated. Materials and methods Polysorbate 60, sodium dodecyl sulfate (SDS) and soy lecithin were used as emulsifiers. MR characteristics of emulsifiers were assessed in aqueous solutions and their function as a stabilizer was examined in oil-in-water emulsions of varying fat content (10, 20, 30, 40, 50%). Stability and homogeneity of the oil-in-water emulsions were evaluated with a delay of 3 h and 9 h after preparation using T1 mapping and visual control. Signal properties of the emulsifiers were investigated by 1H-MRS in aqueous emulsifier solutions. Relaxometry and diffusion weighted MRI (DWI) were performed to investigate the effect of various emulsifier concentrations on relaxation times (T1 and T2) and ADC values of aqueous solutions. Results Emulsions stabilized by polysorbate 60 or soy lecithin were stable and homogeneous across all tested fat fractions. In contrast, emulsions with SDS showed a significantly lower stability and homogeneity. Recorded T1 maps revealed marked creaming of oil droplets in almost all of the emulsions with SDS. The spectral analysis showed several additional signals for polysorbate and SDS. However, lecithin remained invisible in 1H-MRS. Relaxometry and DWI revealed different influences of the emulsifiers on water: Polysorbate and SDS showed only minor effects on relaxation times and ADC values of aqueous solutions, whereas lecithin showed a strong decrease in both relaxation times (r1,lecithin = 0.11 wt.%−1 s−1, r2,lecithin = 0.57 wt.%−1 s−1) and ADC value (Δ(ADC)lecithin = − 0.18 × 10–3 mm2/s⋅wt.%) with increasing concentration. Conclusion Lecithin is suggested as the preferred emulsifier of oil-in-water emulsions in MRI as it shows a high stabilizing ability and remains invisible in MRI experiments. In addition, lecithin is suitable as an alternative means of adjusting relaxation times and ADC values of water.
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- 2021
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30. Mechanism, kinetics, and physicochemical properties of ultrasound-produced emulsions stabilized by lentil protein: a non-dairy alternative in food systems
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Eric Keven Silva, Srujana Mekala, and Marleny D.A. Saldaña
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2. Zero hunger ,Whey protein ,Starch ,Beverage industry ,04 agricultural and veterinary sciences ,General Chemistry ,040401 food science ,Biochemistry ,Industrial and Manufacturing Engineering ,Surface tension ,03 medical and health sciences ,chemistry.chemical_compound ,Colloid ,0404 agricultural biotechnology ,0302 clinical medicine ,chemistry ,Chemical engineering ,Plant protein ,Oil droplet ,Emulsion ,030221 ophthalmology & optometry ,lipids (amino acids, peptides, and proteins) ,Food Science ,Biotechnology - Abstract
Replacement of dairy proteins by plant proteins is a current trend to produce stable colloidal systems critical to the food and beverage industry. In this study, we compared commercial samples of lentil protein concentrate (LPC) and whey protein concentrate (WPC) to stabilize ultrasound-produced sunflower oil-in-water emulsions. The effects of high-intensity ultrasound (HIUS) (0, 300, 600, 900, and 1200 W) on the LPC-stabilized emulsion properties were evaluated and compared to the emulsion stabilized by WPC, with the aim to assess the challenges and drawbacks of using LPC. Steric stabilization mechanism predominated over electrostatic mechanism. The interfacial tension results showed the ability of LPC to adsorb into the oil–water interface. HIUS processing reduced surface charge density of protein-adsorbed oil droplets, decreasing its contribution to kinetic stabilization. The mean droplet diameter of fresh emulsions showed a significant reduction from 5.44 µm at 0 W nominal power to 2.07 µm at 600 W. However, HIUS process intensification by increasing nominal power up to 1200 W increased mean droplet diameter due to starch and dietary fiber aggregation. Although LPC and WPC had distinctive technological properties due to their composition, our results demonstrated that LPC is a promising plant protein to stabilize colloidal systems.
- Published
- 2021
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31. Electrokinetic motion of a submerged oil droplet near an air–water interface.
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Wang, Chengfa, Song, Yongxin, Pan, Xinxiang, and Li, Dongqing
- Subjects
- *
ELECTROKINETICS , *DROPLETS , *AIR-water interfaces , *ELECTRIC fields , *SEPARATION (Technology) , *ZETA potential - Abstract
Highlights • There is a separation distance between an oil droplet and an air–water interface. • A negatively charged interface moves in opposite direction of the DC electric field. • The effect of the mobile air–water interface on the droplet velocity was analyzed. • This moving oil droplet surface and the inner flow affect the droplet velocity. Abstract A numerical study on the electrokinetic motion of a charged oil droplet near a charged air–water interface is presented in this paper. First, the separation distance between the oil droplet and the air–water interface is calculated, and then the electrokinetic velocity of the droplet is simulated utilizing a three-dimensional numerical model under different applied electric fields, droplet’s radii, ionic concentrations, zeta potentials of the oil–water interface, and zeta potentials of the air–water interface. The numerical results indicate that a negatively charged oil droplet near a negatively charged air–water interface moves in opposite direction of the direct current electric field and has larger velocity under higher electric field strength, droplet’s radius, ionic concentration, and absolute values of the two interface zeta potentials. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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32. A review of aqueous foam in microscale.
- Author
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Anazadehsayed, Abdolhamid, Rezaee, Nastaran, Naser, Jamal, and Nguyen, Anh V.
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- *
FOAM , *PLATEAU borders (Surface chemistry) , *FOAM fractionation , *MARANGONI effect , *NEWTONIAN fluids - Abstract
In recent years, significant progress has been achieved in the study of aqueous foams. Having said this, a better understanding of foam physics requires a deeper and profound study of foam elements. This paper reviews the studies in the microscale of aqueous foams. The elements of aqueous foams are interior Plateau borders, exterior Plateau borders, nodes, and films. Furthermore, these elements' contribution to the drainage of foam and hydraulic resistance are studied. The Marangoni phenomena that can happen in aqueous foams are listed as Marangoni recirculation in the transition region, Marangoni-driven flow from Plateau border towards the film in the foam fractionation process, and Marangoni flow caused by exposure of foam containing photosurfactants under UV. Then, the flow analysis of combined elements of foam such as PB-film along with Marangoni flow and PB-node are studied. Next, we contrast the behavior of foams in different conditions. These various conditions can be perturbation in the foam structure caused by injected water droplets or waves or using a non-Newtonian fluid to make the foam. Further review is about the effect of oil droplets and particles on the characteristics of foam such as drainage, stability and interfacial mobility. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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33. Direct Calculation of Entropic Components in Cohesive Interaction Free Energies
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Swaminath Bharadwaj, B Shadrack Jabes, and Nico F. A. van der Vegt
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Physics ,Quantitative Biology::Biomolecules ,Component (thermodynamics) ,Entropy ,Direct method ,Solvation ,Water ,Thermodynamics ,Thermodynamic integration ,Surfaces, Coatings and Films ,Solutions ,Entropy (classical thermodynamics) ,Oil droplet ,Solvents ,Materials Chemistry ,Dewetting ,Physical and Theoretical Chemistry ,Umbrella sampling - Abstract
Cohesive interaction free energies entail an entropic component related to fluctuations of the energy associated with the attractive portion of the solute-solvent potential. The corresponding "fluctuation entropy" is fundamental in the solvation thermodynamics of macromolecular solutes and is linked to interfacial solvent density fluctuations and hydrophobic effects. Since the direct calculation of fluctuation entropy in molecular simulations is hampered by the poor sampling of high-energy tails in the solute-solvent energy distribution, indirect, and often approximate, routes for the calculation of fluctuation entropy are usually required, involving the modeling of geometrically frozen repulsive solute cavities in thermodynamic integration approaches. Herein, we propose a method to directly compute the fluctuation entropy by employing indirect umbrella sampling (INDUS). To validate the method, we consider model systems consisting of subnanometer oil droplets in water for which the fluctuation entropy can be computed exactly using indirect methods. The fluctuation entropy calculated with the newly proposed direct method agrees with the indirect reference calculations. We also observe that the solvation free energy and the contribution of the fluctuation entropy to it are of comparable magnitudes, particularly for larger oil droplets (∼1 nm). The proposed method can readily be employed for flexible macromolecular solutes and systems with extended hydrophobic surfaces or in the vicinity of a dewetting transition.
- Published
- 2021
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34. Combining cellulose nanofibrils and galactoglucomannans for enhanced stabilization of future food emulsions
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Mari Lehtonen, Kirsi S. Mikkonen, Kristin Syverud, Ragnhild Aaen, Department of Food and Nutrition, Helsinki Institute of Sustainability Science (HELSUS), and Food Materials Science Research Group
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EXTRACTION ,Polymers and Plastics ,02 engineering and technology ,OXIDATION ,WOOD ,010402 general chemistry ,01 natural sciences ,Nanocellulose ,chemistry.chemical_compound ,RHEOLOGY ,Lipid oxidation ,Rheology ,Polysaccharides ,WATER ,Cellulose ,NATIVE CELLULOSE ,SPRUCE GALACTOGLUCOMANNANS ,Chemistry ,021001 nanoscience & nanotechnology ,Pickering emulsion ,0104 chemical sciences ,w emulsions ,Galactoglucomannans ,Creaming ,416 Food Science ,Chemical engineering ,Oil droplet ,Galactoglucomannans (GGM) ,Emulsion ,Stabilizers ,PICKERING EMULSIONS ,Emulsions ,MICROFIBRILLATED CELLULOSE ,0210 nano-technology ,Stability ,FIBERS ,Cellulose nanofibrils (CNFs) - Abstract
The use of wood-derived cellulose nanofibrils (CNFs) or galactoglucomannans (GGM) for emulsion stabilization may be a way to obtain new environmentally friendly emulsifiers. Both have previously been shown to act as emulsifiers, offering physical, and in the case of GGM, oxidative stability to the emulsions. Oil-in-water emulsions were prepared using highly charged (1352 ± 5 µmol/g) CNFs prepared by TEMPO-mediated oxidation, or a coarser commercial CNF, less charged (≈ 70 µmol/g) quality (Exilva forte), and the physical emulsion stability was evaluated by use of droplet size distributions, micrographs and visual appearance. The highly charged, finely fibrillated CNFs stabilized the emulsions more effectively than the coarser, lower charged CNFs, probably due to higher electrostatic repulsions between the fibrils, and a higher surface coverage of the oil droplets due to thinner fibrils. At a constant CNF/oil ratio, the lowest CNF and oil concentration of 0.01 wt % CNFs and 5 wt % oil gave the most stable emulsion, with good stability toward coalescence, but not towards creaming. GGM (0.5 or 1.0 wt %) stabilized emulsions (5 wt % oil) showed no creaming behavior, but a clear bimodal distribution with some destabilization over the storage time of 1 month. Combinations of CNFs and GGM for stabilization of emulsions with 5 wt % oil, provided good stability towards creaming and a slower emulsion destabilization than for GGM alone. GGM could also improve the stability towards oxidation by delaying the initiation of lipid oxidation. Use of CNFs and combinations of GGM and CNFs can thus be away to obtain stable emulsions, such as mayonnaise and beverage emulsions.
- Published
- 2021
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35. Oscillating Motion of Oil Droplets in the Emulsion Near the Air–Water Interface
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Vladimir Gubernov, Vladimir Sudakov, Alexey Kiverin, Elena Viktorovna Korshunova, Andrey Kolobov, Boris Kichatov, and Alexey Korshunov
- Subjects
Materials science ,Marangoni effect ,Water ,Mechanics ,Critical value ,Surfaces, Coatings and Films ,Condensed Matter::Soft Condensed Matter ,Physics::Fluid Dynamics ,Motion ,Surface-Active Agents ,Reciprocating motion ,Colloid ,Oil droplet ,Emulsion ,Convective mixing ,Materials Chemistry ,Dissipative system ,Emulsions ,Physical and Theoretical Chemistry ,Physics::Atmospheric and Oceanic Physics - Abstract
Numerous living organisms as well as artificially created self-propelled objects can form dissipative structures due to the nonlinear effects and nonequilibrium of the system. Here we present an active oil-in-water emulsion in which the oil droplets take part in the reciprocating motion under the action of Marangoni flow near the air-water interface. The droplet dynamics in the emulsion is governed by the chemical reaction proceeding between quiescent copper particles and ammonia and by the convective mixing of a surfactant. We established that the reciprocating motion of droplets in the emulsion arises as a result of a periodic change in the Marangoni flow direction at the air-water interface. The feature of the considered system is that the reciprocating motion of droplets is realized only when the surface area fraction of droplets in the emulsion is close to the density of a two-dimensional colloid crystal. Oscillations degenerate under the reduction in surface area fraction to the critical value of ∼50% since the existence of oscillations in the emulsion requires a suppression of the surfactant convective mixing between the inner layers of liquid film and the air-water interface.
- Published
- 2021
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36. Microcapsule-type stabilizers with adjustable wettability and their application in Pickering emulsion
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Jin Liu, Ying Xue, Qiuyu Zhang, Chunmei Li, Laifeng Yao, Jiaojun Tan, and Hangyu Yin
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Materials science ,Mechanical Engineering ,Composite number ,Pickering emulsion ,chemistry.chemical_compound ,Monomer ,chemistry ,Chemical engineering ,Mechanics of Materials ,Dicyclopentadiene ,Oil droplet ,Emulsion ,General Materials Science ,Wetting - Abstract
Using microcapsules as the stabilizers of Pickering emulsion can endow the resulted composite capsules with more storage microcavities, producing new functional and structural materials, which have potential application in the preparation of self-healing microcapsules to achieve multiple healing. However, the preparation and wettability of microcapsule-type stabilizers (MTS) have not been systematically researched. Herein, a facile method to prepare MTS containing a liquid healing agent (dicyclopentadiene, DCPD) was proposed, which exhibited excellent emulsifying properties in Pickering emulsion. MTS with adjustable wettability were successfully prepared and used to fabricate Pickering emulsions with different oil phases. It was found that when the mass ratio of the hydrophobic shell monomer reached 100%, MTS possessed the best emulsifying property and the resulted Pickering emulsion could be stably stored for 30 days. Additionally, via solidifying the activity monomers of the oil droplets, composite capsules with multi-storage cells were successfully prepared which confirmed the strong stability of this emulsion and the appropriate wettability of MTS again, as well as pave a new path for the preparation of new architecture microcapsules. We expected that MTS will be found more useful in encapsulation fields, such as self-healing microcapsules, biological medicine, cosmetics, and textile.
- Published
- 2021
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37. Visualizing and Quantifying Wettability Alteration by Silica Nanofluids
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Ludger P. Stubbs, Shidong Li, Hon Chung Lau, Dan Daniel, Ole Torsæter, and Anqi Sng
- Subjects
Materials science ,technology, industry, and agriculture ,FOS: Physical sciences ,Nanoparticle ,Physics - Applied Physics ,Applied Physics (physics.app-ph) ,Contact angle ,Nanofluid ,Adsorption ,Chemical engineering ,Oil droplet ,Microscopy ,General Materials Science ,Wetting ,Fumed silica - Abstract
An aqueous suspension of silica nanoparticles or nanofluid can alter the wettability of surfaces, specifically by making them hydrophilic and oil-repellent under water. Wettability alteration by nanofluids have important technological applications, including for enhanced oil recovery and heat transfer processes. A common way to characterize the wettability alteration is by measuring the contact angles of an oil droplet with and without nanoparticles. While easy to perform, contact angle measurements do not fully capture the wettability changes to the surface. Here, we employed several complementary techniques, such as cryo-scanning electron microscopy, confocal fluorescence and reflection interference contrast microscopy and droplet probe atomic force Microscopy (AFM), to visualize and quantify the wettability alterations by fumed silica nanoparticles. We found that nanoparticles adsorbed onto glass surfaces to form a porous layer with hierarchical micro- and nano-structures. The porous layer is able to trap a thin water film, which reduces contact between the oil droplet and the solid substrate. As a result, even a small addition of nanoparticles (0.1 wt%) lowers the adhesion force for a 20-$\mu$m-sized oil droplet by more than 400 times from 210$\pm$10 nN to 0.5$\pm$0.3 nN as measured using droplet probe AFM. Finally, we show that silica nanofluids can improve oil recovery rates by 8% in a micromodel with glass channels that resemble a physical rock network.
- Published
- 2021
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38. Dynamic Duo: Vibrational Sum Frequency Scattering Investigation of pH-Switchable Carboxylic Acid/Carboxylate Surfactants on Nanodroplet Surfaces
- Author
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Geraldine L. Richmond, Andrew P. Carpenter, and Marc J Foster
- Subjects
chemistry.chemical_classification ,education.field_of_study ,Scattering ,Carboxylic acid ,Population ,Carboxylic Acids ,Hydrogen-Ion Concentration ,Surfaces, Coatings and Films ,Surface-Active Agents ,chemistry.chemical_compound ,Adsorption ,Pulmonary surfactant ,Chemical engineering ,chemistry ,Dynamic light scattering ,Oil droplet ,Materials Chemistry ,Carboxylate ,Physical and Theoretical Chemistry ,education ,Hydrophobic and Hydrophilic Interactions - Abstract
Surfactants containing pH-switchable, carboxylic acid moieties are utilized in a variety of environmental, industrial, and biological applications that require controlled stability of hydrophobic droplets in water. For nanoemulsions, kinetically stable oil droplets in water, surface adsorption of the anionic form of the carboxylic acid surfactant stabilizes the droplet, whereas a dominant surface presence of the neutral form leads to destabilization. Through the use of dynamic light scattering, ζ-potential, and vibrational sum frequency scattering spectroscopy (VSFSS), we investigate this mechanism and the relative surface population of the neutral and charged species as pH is adjusted. We find that the relative population of the two surfactant species at the droplet surface is distinctly different than their bulk equilibrium concentrations. The ζ-potential measurements show that the surface concentration of the charged surfactant stays nearly constant throughout the stabilizing pH range. In contrast, VSFSS shows that the neutral carboxylic acid form increasingly adsorbs to the surface with increased acidity. The spectral features of the headgroup vibrational modes confirm this behavior and go further to reveal additional molecular details of their adsorption. A significant hydrogen-bonding interaction occurs between the headgroups that, along with hydrophobic chain-chain interactions, assists in drawing more carboxylic acid surfactant to the interface. The charged surfactant provides the stabilizing force for these droplets, while the neutral surfactant introduces complexity to the interfacial structure as the pH is lowered. The results are significantly different than what has been found for the planar oil/water studies where stabilization of the interface is not a factor.
- Published
- 2021
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39. Laser pattern-induced unidirectional lubricant flow for lubrication track replenishment
- Author
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Xinming Li, Feng Guo, P.L. Wong, and Chenglong Liu
- Subjects
Materials science ,Bearing (mechanical) ,Mechanical Engineering ,Flow (psychology) ,Mechanics ,Interfacial Force ,Surfaces, Coatings and Films ,law.invention ,law ,Oil droplet ,Lubrication ,Wetting ,Lubricant ,Anisotropy - Abstract
Effective oil replenishment to the lubrication track of a running bearing is crucial to its sustainable operation. Reliable practical solutions are rare despite numerous theoretical studies were conducted in the last few decades. This paper proposes the use of surface effect, wettability gradient, to achieve the goal. This method is simple and can be nicely implemented using femtosecond laser ablation. A periodic comb-tooth-shaped pattern with anisotropic wetting capability is devised and its effect on the anisotropic spreading behaviour of an oil droplet is studied. Results show that the comb-tooth-shaped pattern enables the rearrangement of oil distribution, thereby escalating oil replenishment to the lubrication track. The effect is due to the unbalanced interfacial force created by the surface pattern. The influence of the shape and the pitch of teeth, which are the two governing factors, on oil transport is also reported. The effects of the newly devised surface pattern on lubrication are experimentally evaluated under the conditions of limited lubricant supply. These results are promising, demonstrating the reduction in bearing friction and the increase in lubricating film thickness.
- Published
- 2021
- Full Text
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40. Efficient demulsification of ultralow-concentration crude oil-in-water emulsion by three-dimensional superhydrophilic channels
- Author
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Bo Xu, Lidong Sun, Kaiqi Zhao, Chengjie Xiang, Jian Jin, Jun Su, and Hongyun Li
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Membrane ,Materials science ,Chemical engineering ,Coating ,Superhydrophilicity ,Oil droplet ,Extraction (chemistry) ,Emulsion ,engineering ,General Materials Science ,engineering.material ,Separation process ,Anode - Abstract
Efficient extraction of crude oil, the major energy resource of current concern and high demand worldwide, is of paramount importance in both energy and environmental fields. However, it remains a great challenge to separate the crude oil-in-water emulsions with an ultralow oil content of
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- 2021
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41. Effect of biopolymers concentration and drying methods on physicochemical properties of emulsion-templated oleogel
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Goly Fayaz, Sayed Amir Hossein Goli, and Maryam Moradabbasi
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Ice crystals ,Chemistry ,engineering.material ,Viscoelasticity ,Rheology ,Chemical engineering ,Oil droplet ,Emulsion ,medicine ,engineering ,Original Article ,Sublimation (phase transition) ,Biopolymer ,Xanthan gum ,Food Science ,medicine.drug - Abstract
In current study, oleogel containing surface-active (sodium caseinate) and non-surface active biopolymers (xanthan gum) prepared in different concentrations through emulsion template (containing 60% canola oil) and dried by freeze-drying. Results showed that biopolymer content affects the oleogel structure: applying the biopolymer combination with increased concentration mainly sodium caseinate, resulted in lower droplet size in emulsions and obtained oleogels with higher firmness and less oil loss. Therefore, samples containing 4% sodium caseinate with 0.2% and 0.4% xanthan were selected as the superior formulas for examining deeply the drying methods' effects (freeze and vacuum-oven drying) on oleogel's physicochemical properties such as hardness, rheology, XRD, color, and oxidative stability. Freeze-drying with higher content of xanthan (0.4% w/w) generated a high mechanical strength oleogel. However, reducing xanthan concentration (0.2% w/w) reduced the gel strength, probably due to not enough viscoelasticity in oil droplets interface. Nevertheless, the charm of freeze-drying method is high-quality dried products in optimized biopolymer concentration due to the water removal by sublimation of ice crystals. Contrariwise, vacuum-oven revealed soft-discolored materials even in high biopolymers concentrations due to the higher temperature and structural collapse. Independence of biopolymer concentration and drying method, no significant difference in XRD patterns, and oxidative stability was observed. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s13197-021-05214-1.
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- 2021
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42. Study on the Influence of Different Factors on Spontaneous Oil Recovery of Nanosurfactants in a Tight Reservoir
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Jianzhong Zhang, Libin Song, Kai Yang, Houshun Jiang, Jie Wang, Wenli Ke, and Hualei Xu
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Chemistry ,General Chemical Engineering ,General Chemistry ,Article ,Dilution ,Surface tension ,Brine ,Pulmonary surfactant ,Chemical engineering ,Oil droplet ,Imbibition ,Microemulsion ,Wetting ,QD1-999 - Abstract
The surface of a tight reservoir appears to be oil-wet or mixed-type wet upon soaking in crude oil for a long time, and the yield decreases rapidly after fracturing under the influence of capillary force. The oil sweep efficiency affected by many factors such as formation water dilution, salinity, crude oil type, temperature, and pressure can be enhanced by adding nanosurfactants into the fracturing fluid, so it is necessary to study the influence of different factors on the spontaneous imbibition replacement efficiency of nanosurfactants. In this study, the basic properties of nanosurfactants such as particle size, oil–water interfacial tension (IFT), and the wetting modification effect were tested, and the influence of surfactant type, concentration, temperature, and pressure on imbibition replacement efficiency was studied. The main conclusions are as follows: (1) The particle size of the nanosurfactant that was synthesized by a microemulsion method is 12–21 nm, which indicated good injectability in tight cores. Moreover, the IFT values between the crude oil and five kinds of 0.30 wt % nanosurfactants were all lower than 0.15 mN/m, and nanosurfactant C had the best wetting modification effect with increasing the contact angle by 100.30°. (2) The type and concentration of surfactant have a certain influence on imbibition replacement efficiency, and appropriate concentration of anionic nanosurfactant is beneficial to enhancing the imbibition replacement efficiency. The imbibition replacement efficiency of 0.30 wt % anionic surfactant C solution is higher than that of nonionic and cationic surfactant solutions, and the imbibition replacement efficiency is as high as 33.386% under NTP. (3) The nanosurfactant in brine is prone to forming fine emulsified oil droplets with crude oil and activates the oil droplets in the small pores to enhance the imbibition replacement efficiency. The crude oil type, temperature, and pressure can influence imbibition replacement efficiency, and the influence of crude oil type and temperature is greater than that of pressure. This work further studies the influencing factors of imbibition replacement efficiency.
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- 2021
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43. Molecular Dynamics Simulations of Nanostructures Formed by Hydrophobins and Oil in Seawater
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Andrés A Vodopivec, Francisco R. Hung, Yuwu Chen, and Paul S. Russo
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Fungal protein ,Nanostructure ,Materials science ,Hydrophobin ,Molecular Dynamics Simulation ,Nanostructures ,Surfaces, Coatings and Films ,Fungal Proteins ,Surface tension ,Molecular dynamics ,Chemical physics ,Phase (matter) ,Oil droplet ,Materials Chemistry ,Cluster (physics) ,Seawater ,Physical and Theoretical Chemistry ,Oils - Abstract
Classical molecular dynamics simulations using the Martini coarse-grained force field were performed to study oil nanodroplets surrounded by fungal hydrophobin (HP) proteins in seawater. The class I EAS and the class II HFBII HPs were studied along with two model oils, namely, benzene and n-decane. Both HPs exhibit free energy minima at the oil-seawater interface, which is deeper in benzene compared to the n-decane systems. Larger constraint forces are required to keep both HPs within the n-decane phase compared to inside benzene, with HFBII being more affine to benzene compared to EAS. Smaller surface tensions are observed at benzene-seawater interfaces coated with HPs compared to their n-decane counterparts. In the latter the surface tension remains unchanged upon increases in the concentration of HPs, whereas in benzene systems adding more HPs lead to decreases in surface tension. EAS has a larger tendency to cluster together in the interface compared to HFBII, with both HPs having larger coordination numbers when surrounding benzene droplets compared to when they are around n-decane nanoblobs. The HP-oil nanostructures in seawater examined have radii of gyration ranging between 2 and 12 nm, where the n-decane structures are larger and have more irregular shapes compared to the benzene systems. The n-decane molecules within the nanostructures form a compact spherical core, with the HPs partially covering its surface and clustering together, conferring irregular shapes to the nanostructures. The EAS with n-decane structures are larger and have more irregular shapes compared to their HFBII counterparts. In contrast, in the HP-benzene structures both HPs tend to penetrate the oil part of the droplet. The HFBII-benzene structures having the larger oil/HP ratios examined tend to be more compact and spherical compared to their EAS counterparts; however, some of the HFBII-benzene systems that have smaller oil/HP ratios have a more elongated structure compared to their EAS counterparts. This simulation study provides insights into HP-oil nanostructures that are smaller than the oil droplets and gas bubbles recently studied in experiments and, thus, might be challenging to examine with experimental techniques.
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- 2021
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44. Manipulation of surface charges of oil droplets and carbonate rocks to improve oil recovery
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Jinxun Wang, Jian Hou, and Ming Han
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0303 health sciences ,Energy ,Multidisciplinary ,Chemistry ,Science ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Surface chemistry ,Article ,Surface tension ,03 medical and health sciences ,Brine ,Chemical engineering ,Pulmonary surfactant ,Oil droplet ,Emulsion ,Zeta potential ,Medicine ,Wetting ,Surface charge ,0210 nano-technology ,030304 developmental biology - Abstract
This work investigates the effect of the surface charges of oil droplets and carbonate rocks in brine and in surfactant solutions on oil production. The influences of the cations in brine and the surfactant types on the zeta-potentials of both oil droplets and carbonate rock particles are studied. It is found that the addition of anionic and cationic surfactants in brine result in both negative or positive zeta-potentials of rock particles and oil droplets respectively, while the zwitterionic surfactant induces a positive charge on rock particles and a negative charge on oil droplets. Micromodels with a CaCO3 nanocrystal layer coated on the flow channels were used in the oil displacement tests. The results show that when the oil-water interfacial tension (IFT) was at 10−1 mN/m, the injection of an anionic surfactant (SDS-R1) solution achieved 21.0% incremental oil recovery, higher than the 12.6% increment by the injection of a zwitterionic surfactant (SB-A2) solution. When the IFT was lowered to 10−3 mM/m, the injection of anionic/non-ionic surfactant SMAN-l1 solution with higher absolute zeta potential value (ζoil + ζrock) of 34 mV has achieved higher incremental oil recovery (39.4%) than the application of an anionic/cationic surfactant SMAC-l1 solution with a lower absolute zeta-potential value of 22 mV (30.6%). This indicates that the same charge of rocks and oil droplets improves the transportation of charged oil/water emulsion in the porous media. This work reveals that the surface charge in surfactant flooding plays an important role in addition to the oil/water interfacial tension reduction and the rock wettability alteration.
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- 2021
45. Adhesion forces for water/oil droplet and bubble on coking coal surfaces with different roughness
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Yaowen Xing, Xiahui Gui, Chunyun Zhu, and Guosheng Li
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Materials science ,Bubble ,0211 other engineering and technologies ,Energy Engineering and Power Technology ,02 engineering and technology ,Surface finish ,Adhesion force ,complex mixtures ,Contact angle ,Air bubble ,020401 chemical engineering ,Geochemistry and Petrology ,Floatability ,Surface roughness ,Coal ,Water/oil droplet ,0204 chemical engineering ,Composite material ,021101 geological & geomatics engineering ,Mining engineering. Metallurgy ,business.industry ,Contact line ,technology, industry, and agriculture ,TN1-997 ,Adhesion ,Geotechnical Engineering and Engineering Geology ,Roughness ,Oil droplet ,business - Abstract
Surface roughness plays a significant role in floatability of coal. In the present paper, coking coal surface was polished by three different sandpapers and the surface properties were characterized by contact angle and roughness measurements. The effect of surface roughness on floatability was investigated by adhesion force measurement system for measuring interaction forces between droplets/bubbles and coking coal surfaces with different roughness. The results showed that the contact angle decreased with increasing roughness yet the adhesion force between the water droplet and coal surface increased owing to the increased contact line and the appearance of line pinning. Maximum adhesion forces between water and surfaces were 111.70, 125.48, and 136.42 μN when the roughness was 0.23, 0.98, and 2.79 μm, respectively. In contrast, under a liquid environment, the adhesion forces between air bubble/oil droplet and coal surfaces were decreased with increasing roughness because of the restriction by water. Maximum adhesion forces of increasing roughness were 97.14, 42.76, and 17.86 μN measured at interfaces between air bubble and coal surfaces and 169.48, 145.84, and 121.02 μN between oil droplet and surfaces, respectively. Decreasing roughness could be beneficial to the spreading of oil droplets and the adhesion of bubbles which is conducive to flotation separation.
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- 2021
46. Multi – oil droplet recognition of oil-water two-phase flow based on integrated features.
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Lian-fu, Han, Ming, Chen, Long_long, Wu, Yong-kang, Zhu, Yu, Zhang, Xing-bin, Liu, and Chang-feng, Fu
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- *
TWO-phase flow , *PETROLEUM , *COMPUTER vision , *ENVIRONMENTAL quality - Abstract
Multi-oil droplet target recognition is one of the applications of machine vision in the measurement of oil-water two-phase flow parameters , which could combine other algorithms to obtain the oil droplet velocity and the water holdup of oil water two-phase flow. Appropriate target representation features can improve the recognition effect of multiple oil droplets. However, due to shooting environment differences and quality differences of oil-water two-phase flow images, existing target representation features do not perform well in low-quality oil-water two-phase flow images. To improve the precision of multi-oil droplet target recognition in oil-water two-phase flow and reduce the miss rate, this paper constructs an integrated feature on the basis of aggregate channel features (ACF). The integrated feature named aggregate channel features with histogram of local gravitational feature(ACFHG) contains the color feature channels reflecting the overall color features of the oil droplet sample, the gradient amplitude channel reflecting the overall gradient of the oil droplet sample image, the gradient direction histogram feature channels reflecting the local gradient of the oil droplet sample image, and the local gravitational feature channels that ensure oil droplet target recognition in low quality photos and photos taken in complex shooting environments. Moreover, the rotation invariance is obtained by taking the oriented gradient histogram of the local gravitational feature to further improve the multi-oil droplet target recognition effect. Experiment results show that the average precision of multi-oil droplet target recognition using the integrated features is 83.38%, which is 9.93% higher than that with using ACF, and the miss rate is 9.13%, which is 57.18% lower than that with using ACF. Compared with other existing target detection methods, the method proposed in this paper still has an advantage in the rate of missed detection. • Integrated features for improving the precision and reducing the miss rate in the multi-oil droplet recognition process are proposed. • The average precision of using integrated feature is 9.93% higher than that of using aggregate channel features. • The miss rate of using integrated feature is 57.18% lower than that of using aggregate channel features. [ABSTRACT FROM AUTHOR]
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- 2023
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47. Synthesis and characterization of low-cost hierarchical porous silica by nanoemulsion templating: influence of nanoemulsion volume and hydrodynamic diameter
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Manal Hessien and Eric Prouzet
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Materials science ,Macropore ,02 engineering and technology ,General Chemistry ,Mesoporous silica ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Microstructure ,01 natural sciences ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,Biomaterials ,Matrix (chemical analysis) ,Volume (thermodynamics) ,Chemical engineering ,Oil droplet ,Materials Chemistry ,Ceramics and Composites ,0210 nano-technology ,Porosity ,Phase inversion - Abstract
Silica as a stable and biocompatible material has attracted a great deal of interest, particularly concerning the synthesis of porous silica. Hierarchical Porous Silica (HPS) can be synthesized through nanoemulsion templating and sol–gel. The oil droplets of NE acted as a pore-forming agent and the sol-gel built the matrix around the oil droplets. The O/W-NE was prepared by the phase inversion composition (PIC) method. The effect of nanoemulsion volume (2.5, 25, and 50) and the effect of oil droplet diameter (65, 105, 150, 200, and 400 nm) on the HPS was studied. Samples were characterized by many characterization techniques. The microstructure of the samples is versatile with macropores distributed homogenously through the mesoporous silica matrix or hollow macroporous spheres. Both volume and hydrodynamic diameter of the nanoemulsions influence the microstructure through the oil/water interfacial area. The surface area ranges between 158 and 281 m2/g and the pore volume is between 0.63 and 6.59 cc/g.
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- 2021
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48. Emulsions stabilized by highly hydrophilic TiO2 nanoparticles via van der Waals attraction
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Cheng Yang, Jing Wang, Xihua Lu, Mingying Yu, Yajuan Sun, and Sridhar Komarneni
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Wax ,Materials science ,Dispersity ,Nanoparticle ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Pickering emulsion ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Biomaterials ,symbols.namesake ,Colloid and Surface Chemistry ,Chemical engineering ,Oil droplet ,visual_art ,Emulsion ,symbols ,visual_art.visual_art_medium ,Particle ,van der Waals force ,0210 nano-technology - Abstract
Hypothesis Highly hydrophilic nanoparticles are generally considered not suitable for stabilizing Pickering emulsions, since they could not be effectively wetted by the oil phase at the water-oil interface. However, highly hydrophilic nanoparticles with good dispersity are possibly absorbed and packed onto the surface of the oil droplets in water via the van der Waals attraction between the nanoparticles and the oil droplets. Hence, a novel “van der Waals emulsion” should be possible to be stabilized by highly hydrophilic nanoparticles. Experiments Oil-in-water emulsions solely stabilized by pristine TiO2 nanoparticles (i.e., TiO2 without any modification or additives) were prepared. The emulsification behavior under varying pH value, oil fraction, particle content and temperature of the emulsion were explored. Composite wax-based beads which encapsulated chemical sunscreen and was coated by TiO2 nanoparticles, was also fabricated using the obtained emulsion as the templates. Findings The emulsions displayed the highest stability near the isoelectric points of the TiO2 nanoparticles, which was attributed to the van der Waals attraction between TiO2 nanoparticles and oil droplets. Such mechanism was supported by a theoretical analysis based on calculation of the Hamaker constants and experimental evidences. Therefore, this work presents a simple, general and green method for preparing particle-stabilized emulsions.
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- 2021
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49. Flavor, antimicrobial activity and physical properties of gelatin film incorporated with of ginger essential oil
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Zhong-Ying Li, Li Xin, Xiao-mei Sha, Zong-cai Tu, and Yun-hua Ye
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0106 biological sciences ,food.ingredient ,Materials science ,Composite number ,04 agricultural and veterinary sciences ,040401 food science ,01 natural sciences ,Gelatin ,law.invention ,0404 agricultural biotechnology ,food ,Chemical engineering ,law ,010608 biotechnology ,Oil droplet ,parasitic diseases ,Ultimate tensile strength ,Original Article ,Elongation ,Antibacterial activity ,Essential oil ,Flavor ,Food Science - Abstract
Adding essential oil into the gelatin-based film can enhance the antibacterial activity of the film, but excessive amounts of addition will bring the film an unpleasant flavor and reduce its mechanical performance. Hence, we prepared functional gelatin-based films by incorporating low content of ginger essential oil (GEO). The flavor of GEO was not detected from the films containing less than 1% GEO. The antimicrobial activity of films was found to be proportional to GEO content. As GEO content increased from 0 to 1%, the value of water vapor permeability (WVP) and elongation at break (EAB) increased, whereas the value of tensile strength (TS) of film decreased. The Attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy analysis revealed the vibration of gelatin film was affected by adding low content of essential oil. Surface morphologies demonstrated oil droplets and a discontinuous structure, and cross-section morphologies proved the formation of a loose structure as GEO was incorporated in the film through SEM. Sensory evaluation revealed that composite films incorporated with 0.5% GEO exhibited the best performance. The resulting films can be used as antimicrobial packaging materials with good physical properties and sensory performance.
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- 2021
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50. Ultrastructure of the fertilized egg envelope from Melanotaenia praecox, Melanotaeniidae, Teleostei
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Dong Heui Kim and Joon Hyung Sohn
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Egg envelope ,Melanotaeniidae ,Morphology (linguistics) ,Perivitelline space ,Melanotaenia ,02 engineering and technology ,law.invention ,Protein filament ,03 medical and health sciences ,law ,lcsh:Microscopy ,Melanotaenia praecox ,030304 developmental biology ,0303 health sciences ,biology ,Fertilized egg ,lcsh:QH201-278.5 ,Chemistry ,Research ,General Medicine ,021001 nanoscience & nanotechnology ,biology.organism_classification ,Ultrastructure ,Oil droplet ,embryonic structures ,Biophysics ,Adhesive ,Electron microscope ,0210 nano-technology - Abstract
We examined the morphology of fertilized egg and ultrastructures of fertilized egg envelopes of dwarf rainbowfish (Melanotaenia praecox) belong to Melanotaeniidae using light and electron microscopes. The fertilized eggs were spherical with adhesive filament, transparent, demersal, and had a narrow perivitelline space and small oil droplets. The size of fertilized egg was 1.02 ± 0.18 mm (n = 30), and there were two kinds of adhesive filament on the fertilized eggs. The long and thick (diameter 12.22 ± 0.52 μm, n = 20) adhesive filaments were only at the area of animal pole, and short and thin (diameter 1.99 ± 0.23 μm, n = 20) adhesive filaments were around the long filaments. A micropyle was conical shaped with adhesive filament and located near the animal pole of egg. The outer surface of fertilized egg was rough side. Also, the total thickness of the fertilized egg envelope was about 7.46 ± 0.41 μm (n = 20), the fertilized egg envelope consisted of two layers, an inner lamellae layer and an outer layer with high electron-density. And the inner layer was 8 layers. Collectively, these morphological characteristics and adhesive property of fertilized egg with adhesive filaments, and ultrastructures of micropyle, outer surface, and section of fertilized egg envelope are showed species specificity.
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- 2021
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