1. Robust electrical current modulation in functionalized graphene channels
- Author
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E. A. Yakimchuk, Irina V. Antonova, Saeid Shojaei, and S. M. Sattari Esfahlan
- Subjects
010302 applied physics ,Materials science ,Graphene ,business.industry ,Transistor ,Chemical modification ,Condensed Matter Physics ,01 natural sciences ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials ,law.invention ,Ion ,law ,Quantum dot ,Modulation ,0103 physical sciences ,Optoelectronics ,Crystallite ,Electrical and Electronic Engineering ,business ,Order of magnitude - Abstract
Within the approach based on chemical modification of domain boundaries of polycrystalline graphene, a transistor channel is proposed for enhanced current modulation, Ion/Ioff ratio, in the 3 to 5 order of magnitude. We observed that two types of samples functionalized by N-methylpirrolidone (NMP) and weakly fluorinated graphene are able to demonstrate high current modulation. Experimentally, Ion/Ioff ~ 103 was found for NMP functionalized graphene and Ion/Ioff ~ 104–105 for weakly fluorinated graphene. Modeling of these two systems allows us to clarify the mechanism of carrier transport in the multi-barrier films of functionalized graphene films. It is shown that remarkable value for Ion/Ioff as about 106 can be observed for the films comprising graphene regions (graphene quantum dots, GQDs) with size of ~ 30–300 nm and ~ 75–100 nm fluorinated graphene barriers. Relatively high values of Ion/Ioff ~ 103–105 are also predicted for large graphene areas separated with thin (100 nm) barriers for the weakly fluorinated graphene samples. Our study paves a way towards controllable 2D transistors.
- Published
- 2021
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