1. Photoluminescence of Eu2+ in BaF2-rich fluorohalides and photostimulation after X-ray irradiation
- Author
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L Struye, A. Moudden, Claude Fouassier, P Willems, Alain Garcia, B. Es-Sakhi, P. J. R. Leblans, Université Ibn Zhor, Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut Polytechnique de Bordeaux-Université de Bordeaux (UB), and Agfa-Gevaert
- Subjects
Photoluminescence ,Materials science ,Photostimulated luminescence ,Analytical chemistry ,chemistry.chemical_element ,Quantum yield ,Phosphor ,02 engineering and technology ,Crystal structure ,010402 general chemistry ,01 natural sciences ,Storage phosphors ,Eu2+-doped barium chlorofluoride ,General Materials Science ,Irradiation ,Bromine ,Mechanical Engineering ,[CHIM.MATE]Chemical Sciences/Material chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,0104 chemical sciences ,3. Good health ,chemistry ,Mechanics of Materials ,Photostimulation ,0210 nano-technology ,Luminescence ,Nuclear chemistry - Abstract
The luminescence of Eu 2+ has been investigated in two families of BaF 2 -rich fluorohalides, Ba 12 Cl 5(1− x ) Br 5 x F 19 ( x ≤0.8) and Ba 7 Cl 2(1− x ) Br 2 x F 12 ( x ≤0.5). In the two kinds of host lattices, under UV excitation Eu 2+ shows an intense blue 5d→4f band emission at 300 K. At low temperature, in addition to the latter, 4f→4f lines are present in the near UV. The efficiency of the photostimulated luminescence (PSL) after X-ray irradiation has been measured and compared with that of BaXF:Eu (X=Cl, Br). High conversion efficiencies have been obtained with compositions Ba 12 Cl 5(1− x ) Br 5 x F 19 for stimulation at 532 nm. The presence of bromine is beneficial. For all compositions a high stimulation energy (SE) is needed to excite Eu 2+ ions through colour centres.
- Published
- 2003
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