1. Grain growth phenomenon during pressure-induced phase transformations at room temperature
- Author
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Levitas, Valery I., Pratoori, Raghunandan, Popov, Dmitry, Park, Changyong, and Velisavljevic, Nenad
- Subjects
Condensed Matter - Materials Science - Abstract
Significant grain growth is observed during the high-pressure phase transformations (PTs) at room temperature within an hour for various materials. However, no existing theory explains this phenomenon since nanocrystals do not grow at room temperature even over a time span of several years because of slow diffusion. Here, we suggest a multistep mechanism for the grain growth during $\alpha\rightarrow\omega$ PT in Zr. Phase interfaces and grain boundaries (GBs) coincide and move together under the action of a combined thermodynamic driving forces. Several intermediate steps for such motion are suggested and justified kinetically. Nonhydrostatic stresses due to volume reduction in the growing $\omega$ grain promote continuous growth of the existing $\omega$ grain instead of a new nucleation at other GBs. In situ synchrotron Laue diffraction experiments confirm the main predictions of the theory. The suggested mechanism provides a new insight into synergistic interaction between PTs and microstructure evolution., Comment: Main document: 16 pages, 4 figures; Supplementary document: 21 pages, 12 figures
- Published
- 2024