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3 results on '"White, Keith F."'

1. Alkali metal salts of 4-hydroxybenzoic acid: a structural and educational study

Author

Abrahams, Brendan F., primary, Commons, Christopher J., additional, Hudson, Timothy A., additional, Sanchez Arlt, Robin, additional, White, Keith F., additional, Chang, Michael, additional, Jackowski, John J., additional, Lee, Matthew, additional, Lee, Shang X., additional, Liu, Harrison D., additional, Mei, Bill M., additional, Meng, Joshua E., additional, Poon, Lincoln, additional, Xu, Xiaolin, additional, and Yu, Zekai, additional

Published
2021
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3. A Multifunctional, Charge‐Neutral, Chiral Octahedral M L Cage

Author

Boer, Stephanie A., White, Keith F., Slater, Benjamin, Emerson, Adrian J., Knowles, Gregory P., Donald, William A., Thornton, Aaron W., Ladewig, Bradley P., Bell, Toby D. M., Hill, Matthew R., Chaffee, Alan L., Abrahams, Brendan F., and Turner, David R.

Subjects
Technology, 010405 organic chemistry, Chemistry, Organic Chemistry, Supramolecular chemistry, Sorption, General Chemistry, 010402 general chemistry, 01 natural sciences, Catalysis, 0104 chemical sciences, Crystallography, Enantiopure drug, Octahedron, General chemistry, Self-assembly, Chirality (chemistry), Cage, ddc:600
Abstract

A chiral, octahedral M12 L12 cage, which is charge neutral and contains an internal void of about 2000 A3 , is reported. The cage was synthesised as an enantiopure complex by virtue of amino-acid-based dicarboxylate ligands, which assemble around copper paddlewheels at the vertices of the octahedron. The cage persists in solution with retention of the fluorescence properties of the parent acid. The solid-state structure contains large pores both within and between the cages, and displays permanent porosity for the sorption of gases with retention of crystallinity. Initial tests show some enantioselectivity of the cage towards guests in solution.

Published
2019
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