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Legume-based cropping increased the diversity of residues and rhizodeposition input into the soil, thus affecting soil organic matter (SOM) stabilization. Despite this, a comprehensive understanding of the mechanisms governing SOM mineralization and its temperature sensitivity across bulk soil and aggregate scales concerning legume inclusion remains incomplete. Here, a 6-year field experiment was conducted to investigate the effects of three cropping systems (i.e., winter wheat/summer maize, winter wheat/summer maize-soybean, and nature fallow) on SOM mineralization, its temperature sensitivity, and the main drivers in both topsoil (0–20 cm) and subsoil (20–40 cm). Soybean inclusion decreased the SOM mineralization by 17%–24%, while concurrently increasing the majority of soil biochemical properties, such as carbon (C) acquisition enzyme activities (5%–22%) and microbial biomass C (5%–9%), within the topsoil regardless of temperature. This is attributed to the increased substrate availability (e.g., dissolved organic C) facilitating microbial utilization, thus devoting less energy to mining nutrients under diversified cropping. In addition, SOM mineralization was lower within macroaggregates (∼12%), largely driven by substrate availability irrespective of aggregate sizes. In contrast, diversified cropping amplified the Q10 of SOM mineralization in mesoaggregates (+6%) and microaggregates (+5%) rather than in macroaggregates. This underscores the pivotal role of mesoaggregates and microaggregates in dominating the Q10 of SOM mineralization under soybean-based cropping. In conclusion, legume-based cropping diminishes soil organic matter mineralization despite increasing its temperature sensitivity, which proposes a potential strategy for C-neutral agriculture and climate warming mitigation.

Soil acidification is an ongoing problem in intensively cultivated croplands due to inefficient and excessive nitrogen (N) fertilization. We collected high-resolution data comprising 19,969 topsoil (0–20 cm) samples from the Land Use and Coverage Area frame Survey (LUCAS) of the European commission in 2009 to assess the impact of N fertilization on buffering substances such as carbonates and base cations. We have only considered the impacts of mineral fertilizers from the total added N, and a N use efficiency of 60 %. Nitrogen fertilization adds annually 6.1 × 107 kmol H+ to European croplands, leading to annual loss of 6.1 × 109 kg CaCO3. Assuming similar acidification during the next 50 years, soil carbonates will be completely removed from 3.4 × 106 ha of European croplands. In carbonate-free soils, annual loss of 2.1 × 107 kmol of basic cations will lead to strong acidification of at least 2.6 million ha of European croplands within the next 50 years. Inorganic carbon and basic cation losses at such rapid scale tremendously drop the nutrient status and production potential of croplands. Soil liming to ameliorate acidity increases pH only temporarily and with additional financial and environmental costs. Only the direct loss of soil carbonate stocks and compensation of carbonate-related CO2 correspond to about 1.5 % of the proposed budget of the European commission for 2023. Thus, controlling and decreasing soil acidification is crucial to avoid degradation of agricultural soils, which can be done by adopting best management practices and increasing nutrient use efficiency. Regular screening or monitoring of carbonate and base cations contents, especially for soils, where the carbonate stocks are at critical levels, are urgently necessary.

Over-fertilization has a significant impact on soil microbial properties and its ecological environment. However, the effects of long-term fertilization on microbial properties on a large scale are still vague. This meta-analysis collected 6211 data points from 109 long-term experimental sites in China to evaluate the effects of fertilizer type and fertilization duration, as well as soil and climate conditions, on the effect sizes on various microbial properties and indices. The organic fertilizers combined with straw (NPKS) and manure (NPKM) had the highest effect sizes, while the chemical fertilizers N (sole N fertilizer) and NPK (NPK fertilizer) had the lowest. When compared with the control, NPKM treatment had the highest effect size, while N treatment had the lowest effect size on MBN (111% vs. 19%), PLFA (110% vs. −7%), fungi (88% vs. 43%), Actinomycetes (97% vs. 44%), urease (77% vs. 25%), catalase (15% vs. −11%), and phosphatase (58% vs. 4%). NPKM treatment had the highest while NPK treatment had the lowest effect size on bacteria (123% vs. 33%). NPKS treatment had the highest while N treatment had the lowest effect sizes on MBC (77% vs. 8%) and invertase (59% vs. 0.2%). NPKS treatment had the highest while NPK treatment had the lowest effect size on the Shannon index (5% vs. 1%). The effect sizes of NPKM treatment were the highest predominantly in arid regions because of the naturally low organic carbon in soils of these regions. The effect sizes on various microbial properties were also highly dependent on soil texture. In coarse-textured soils the effect sizes on MBC and MBN peaked sooner compared with those of clayey or silty soils, although various enzymes were most active in silty soils during the first 10 years of fertilization. Effect sizes on microbial properties were generally higher under NPKM and NPKS treatments than under NPK or N treatments, with considerable effects due to climate conditions. The optimal field fertilizer regime could be determ

Soil inorganic carbon (SIC) contributes to up to half of the terrestrial C stock and is especially significant in arid and semi-arid environments, yet has not been explored as much as soil organic carbon (SOC). SIC plays an important role in agriculture, CO2 sequestration and emission and climate regulation. To address this, a comprehensive review is presented on the digital mapping of soil inorganic carbon including a discussion of SIC vertical variation, its controlling factors, and sequestration/emission capability. We surveyed SIC distribution and mapping efforts in Australia, South Africa, Chile, the Mediterranean basin, Iran, China, France, and the United States. We found that current detailed spatial information on SIC distribution and stock is relatively scarce and digital soil mapping (DSM) efforts to address this are modest. Furthermore, we do not have a complete soil C model that explicitly accounts for all sources and sinks of soil carbon. This review showed that many aspects of SIC in DSM and soil C studies have been so far ignored and that SIC has a crucial role in climate regulation. This review provides some insights into the importance and unknown aspects of SIC.

Soil salinization is one of the main causes of global desertification and soil degradation. Although previous studies have investigated the hyperspectral inversion of soil salinity using machine learning, only a few have been based on soil types. Moreover, agricultural fields can be improved based on the accurate estimation of the soil salinity, according to the soil type. We collected field data relating to six salinized soils, Haplic Solonchaks (HSK), Stagnic Solonchaks (SSK), Calcic Sonlonchaks (CSK), Fluvic Solonchaks (FSK), Haplic Sonlontzs (HSN), and Takyr Solonetzs (TSN), in the Hetao Plain of the upper reaches of the Yellow River, and measured the in situ hyperspectral, pH, and electrical conductivity (EC) values of a total of 231 soil samples. The two-dimensional spectral index, topographic factors, climate factors, and soil texture were considered. Several models were used for the inversion of the saline soil types: partial least squares regression (PLSR), random forest (RF), extremely randomized trees (ERT), and ridge regression (RR). The spectral curves of the six salinized soil types were similar, but their reflectance sizes were different. The degree of salinization did not change according to the spectral reflectance of the soil types, and the related properties were inconsistent. The Pearson’s correlation coefficient (PCC) between the two-dimensional spectral index and the EC was much greater than that between the reflectance and EC in the original band. In the two-dimensional index, the PCC of the HSK-NDI was the largest (0.97), whereas in the original band, the PCC of the SSK400 nm was the largest (0.70). The two-dimensional spectral index (NDI, RI, and DI) and the characteristic bands were the most selected variables in the six salinized soil types, based on the variable projection importance analysis (VIP). The best inversion model for the HSK and FSK was the RF, whereas the best inversion model for the CSK, SSK, HSN, and TSN was the ERT, and the

The long-term overuse of fertilizers negatively affects soil chemical properties and health, causing unsustainable agricultural development. Although many studies have focused on the effects of long-term fertilization on soil properties, few comparative and comprehensive studies have been conducted on fertilization management over the past 35 years in China. This meta-analysis (2058 data) evaluated the effects of the fertilizer, climate, crop types, cultivation duration and soil texture on the soil chemical properties of Chinese croplands. NPKM (NPK fertilizers + manure) led to the highest increase in pH (−0.1), soil organic carbon (SOC) (+67%), total nitrogen (TN) (+63%), alkali-hydrolysable nitrogen (AN) (+70%), total phosphorus (TP) (+149%) and available potassium (AK) (+281%) compared to the unfertilized control, while the sole nitrogen fertilizer (N) led to the lowest increase. The SOC (+115%) and TN (+84%) showed the highest increase under the influence of NPKM in an arid region. The increase in the chemical properties was higher in unflooded crops, with the maximum increase in the wheat–maize rotation, compared to rice, under NPKM. The SOC and TN increased faster under the influence of organic fertilizers (manure or straw) compared to mineral fertilization. Fertilizers produced faster effects on the change in the SOC and TN in sandy loam compared to the control. Fertilizers showed the highest and lowest effects on change in pH, organic C to total N ratio (C/N), TP and TK in clay loam with the cultivation duration. NPKM greatly increased the C/N compared to NPK in an arid region by 1.74 times and in wheat by 1.86 times. Reaching the same SOC increase, the lowest TN increase was observed in wheat, and the lowest increase in TP and AK was observed in rice, compared to the other crops. These results suggest that organic fertilizers (manure or straw) play important roles in improving soil fertility and in acidification. NPKM greatly increased the potential for soi

Desert rhizoliths are generally found as weathered, broken and scattered samples on dune field surface, but rarely in-situ in their initial states buried under the soil of desert in the Badain Jaran Desert, northwest China. This study offers an assessment of the morphological, mineralogical, and chemical properties of intact and in-situ rhizoliths found in soils of swales and depressions among dune chains. The characteristics of these rare and precious objects were assessed using optical polarizing microscopy, cathodoluminescence, scanning electronic microscopy, radiocarbon dating, and stable isotopic analyses, providing the opportunity for discussion of the rhizolith formation mechanisms and associated environmental conditions. Field and laboratory investigations showed that the in-situ intact rhizoliths were formed only in the places where Artemisia shrubs are living, and the remaining root relicts within rhizoliths belong to this species. The spatial distribution of rhizoliths also suggested that low topographic positions on a landscape provided soil moisture, and redox environments favored rhizolith formation. A semi-closed redox environment in the subsoil at swales and depressions, where water is always present, along with the sandy soil texture, facilitated fast water percolation to deeper depths and condensation. Such a soil environment not only provides water for Artemisia growth, but also for the weathering of minerals such as felspars and calcite from primary carbonates, and for the decomposition of root relicts. Furthermore, harsh climatic conditions, such as strong winds and solar radiation, led to water evaporation through dead root channels and triggered the calcification along the root relicts. The entrapped lithogenic carbonates and to a lesser extent the decomposition of Artemisia roots provided the carbon sources for the rhizoliths formation, while the weathering of soil minerals, particularly feldspars and carbonates, was the main source of Ca. Rh