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27 results on '"Bao, Lian-Jun"'

3. Isotopic exchange on solid-phase micro extraction fiber in sediment under stagnant conditions: Implications for field application of performance reference compound calibration.

Author

Bao, Lian-Jun, Wu, Xiaoqin, Jia, Fang, Zeng, Eddy Y, and Gan, Jay

Subjects
Animals, Polychaeta, Deuterium, Water, Carbon Isotopes, Polychlorinated Biphenyls, Dichlorodiphenyl Dichloroethylene, Dimethylpolysiloxanes, Water Pollutants, Chemical, Calibration, Environmental Monitoring, Geologic Sediments, Solid Phase Extraction, Hydrophobic organic compounds, Nonsymmetrical relationship, Passive sampling, Performance reference compound calibration, Stagnant sediment, Environmental Sciences, Chemical Sciences, Biological Sciences
Abstract

An overlooked issue for field application of in situ performance reference compound (PRC) calibration methods is the validity of the assumption that both the sorption of a target compound and desorption of its corresponding PRC follow the first-order kinetics with the same rate constants under stagnant conditions. In the present study, disposable polydimethylsiloxane fibers of 2 sizes (7 and 35 µm) impregnated with 8 (13) C-labeled or deuterated PRCs were statically deployed into different marine sediments, from which the kinetics for sorption of the target compounds and desorption of the PRCs were characterized. Nonsymmetrical profiles were observed for exchange of the target analytes and their corresponding PRCs in sediment under stagnant conditions. The hysteretic desorption of PRCs in the kinetic regime may be ascribed to the low chemical potential between the fiber and sediment porewater, which reflects the inability of water molecules to rapidly diffuse through sediment to solvate the PRCs in the aqueous layer around the fiber surface. A moderate correlation (r = 0.77 and r = 0.57, p

Published
2016

4. Use of isotope dilution method to predict bioavailability of organic pollutants in historically contaminated sediments.

Author

Jia, Fang, Bao, Lian-Jun, Crago, Jordan, Schlenk, Daniel, and Gan, Jay

Subjects
Animals, Biological Availability, Carbon Isotopes, Geologic Sediments, Hydrophobic and Hydrophilic Interactions, Isotope Labeling, Kinetics, Organic Chemicals, Polychaeta, Polychlorinated Biphenyls, Polymers, Water Pollutants, Chemical
Abstract

Many cases of severe environmental contamination arise from historical episodes, where recalcitrant contaminants have resided in the environment for a prolonged time, leading to potentially decreased bioavailability. Use of bioavailable concentrations over bulk chemical levels improves risk assessment and may play a critical role in determining the need for remediation or assessing the effectiveness of risk mitigation operations. In this study, we applied the principle of isotope dilution to quantify bioaccessibility of legacy contaminants DDT and PCBs in marine sediments from a Superfund site. After addition of 13C or deuterated analogues to a sediment sample, the isotope dilution reached a steady state within 24 h of mixing. At the steady state, the accessible fraction (E) derived by the isotope dilution method (IDM) ranged from 0.28 to 0.89 and was substantially smaller than 1 for most compounds, indicating reduced availability of the extensively aged residues. A strong linear relationship (R2=0.86) was found between E and the sum of rapid (Fr) and slow (Fs) desorption fractions determined by sequential Tenax desorption. The IDM-derived accessible concentration (Ce) was further shown to correlate closely with tissue residue in the marine benthic polychaete Neanthes arenaceodentata exposed in the same sediments. As shown in this study, the IDM approach involves only a few simple steps and may be readily adopted in laboratories equipped with mass spectrometers. This novel method is expected to be especially useful for historically contaminated sediments or soils, for which contaminant bioavailability may have changed significantly due to aging and other sequestration processes.

Published
2014

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