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The resistance of a large Pure Car Truck Carrier (PCTC) with a bulbous bow and a transom stern is evaluated in the present paper. Several cases at nine different ship speeds in calm water are simulated and results are compared with the experimental measurements. The maximum relative error is 0.93% at a Froude number (Fr) of 0.209. The total resistance coefficient of the ship in calm water shows a parabolic trend with increasing Fr, and it reaches a minimum value at Fr = 0.1794. Furthermore, the cases of the ship in regular waves with six different wavelengths and three wave heights are simulated. It is observed that the total resistance exhibits a quadratic relationship with the wavelength when the wave height is fixed. The wave-making resistance increases with the increase in wave height at any fixed wavelength, and it reaches a maximum value when the wave-length is 1.2 times the ship length (Lpp). Additionally, we also investigated the resistance in three different sea states at four different speeds. When the significant wave height of irregular waves is the same as regular waves, the wave-making resistance under irregular waves is much smaller than that of the regular waves. All of these results indicate that the bulbous bow and transom stern can reduce the wave-making and residuary resistances, which can provide a useful reference for the subsequent design and manufacturing of related ships. [ABSTRACT FROM AUTHOR]

Chlorine species, widely presented in industrial flue gas such as the waste incineration plants, can poison the catalysts and affect the selective catalytic reduction (SCR) performance. In this work, effects of Cl on the SCR performance of V2O5–WO3/TiO2 (VW/Ti) catalysts were investigated by NH4Cl deposition. The results showed that the NOx conversion efficiency at low reaction temperature (< 300 °C) decreased with the loading of NH4Cl after calcination. It was found that instead of causing the chlorination of VW/Ti catalyst the NH4Cl decomposed into volatile Cl species due to the weak V–Cl bonding. Such decomposition reduced significantly the surface non-lattice oxygen species to inhibit NO adsorption and activation, but hardly affected the redox ability and acidity of VW/Ti catalyst. Time–resolved in situ DRIFTs results indicated that NH3 activation and the SCR process predominated by Eley–Rideal mechanism were not influenced with NH4Cl impregnation, while the SCR at low temperature following a Langmuir–Hinshelwood path was limited by the decreased and weaker binding sites for NO activation. [ABSTRACT FROM AUTHOR]

[Display omitted] • Hierarchically devised NiFeO x H y catalyst showed high OER activity under alkaline condition. • NiFeO x H y /Ni heterostructure was in-situ formed via a surface reconstruction process. • Charge transfer at the catalyst-electrolyte interface was improved with Fe incorporation into Ni (oxy)hydroxide. • Fe species located at the outer surface of NiOOH structure served as the OER active site. Nickel iron (oxy)hydroxide (NiFeO x H y) is among the most active electrocatalysts for oxygen evolution reaction (OER) in the alkaline media. Development of new design strategy for NiFeO x H y electrode with respect to intrinsic activity and number of active species is highly attractive. Here we report a hierarchical fabrication for NiFeO x H y electrode towards efficient oxygen evolution. Three-dimensional mesoporous NiO was initially prepared and reduced to a polycrystalline Ni metal framework. Despite the poor OER activity for Ni-based catalyst, the incorporation of surface Fe species induced a notably high current density for the oxygen evolution. The results indicated that the Fe species, located at outer surface region, played a key role as the OER active sites. It is also found that the surface of metallic Ni was reconstructed to (oxy)hydroxide phase with ease compared to NiO. As a result, a heterostructure composed of an OER-active NiFe (oxy)hydroxide shell and an electron-conductive Ni core was formed. In this fabricated NiFeO x H y /Ni catalyst, the promoted intrinsic activity, number of active sites and charge-transfer ability all taken into account contribute to an efficient OER process. [ABSTRACT FROM AUTHOR]

Highlights: [•] Vanadia species suppress the reducibility and defect sites of ceria. [•] Polymeric VO x , ceria provide Lewis and CeVO4 provide Brønsted acid sites. [•] Polymeric VO x low energy barriers and CeVO4 increase rate constant. [•] The reaction mechanism depends on the temperature. [ABSTRACT FROM AUTHOR]

Highlights: [•] Mn, Co, Ni and Zn are doped into the structure of iron spinel oxides. [•] Surface acidity and redox properties are related to iron spinel structures. [•] Competition of NH3-CR and NH3-CO exists over metal-doped iron spinel catalysts. [•] SCR performance is affected by the redox cycle of Fe3+/Fe2+ in octahedral sites. [Copyright &y& Elsevier]

Highlights: [•] Presence of bulk WO3 on titania surface leads to deficiency of Brønsted acid sites. [•] Two-dimension VO x has a tendency to anchor onto titania surface in vicinity of WO x . [•] WO x shows compressing effects on monolayer VO x species at high vanadium loadings. [•] NH3-SCR performance is mainly dependent on vanadium contents of V W/TiO2 catalysts. [ABSTRACT FROM AUTHOR]

Abstract: (Fe3−x Mn x )1−δ O4 was synthesized using a co-precipitation method and then developed as a catalyst for the low temperature selective catalytic reduction (SCR) of NO with NH3. The SCR activity of (Fe3−x Mn x )1−δ O4 was clearly enhanced with the increase of Mn content. The results of in situ DRIFTS study demonstrated that both the Eley–Rideal mechanism (i.e. reaction of activated ammonia with gaseous NO) and the Langmuir–Hinshelwood mechanism (i.e. reaction of adsorbed ammonia species with adsorbed NO x species) might happen during the SCR reaction over (Fe3−x Mn x )1−δ O4. According to the kinetic analysis, the respective contribution of the Langmuir–Hinshelwood mechanism and the Eley–Rideal mechanism on the SCR reaction was studied. Only the adsorption of NO+O2 on (Fe2.8Mn0.2)1−δ O4 was promoted, so the Langmuir–Hinshelwood mechanism predominated over NO conversion on (Fe2.8Mn0.2)1−δ O4 especially at lower temperatures. Both the adsorption of NO+O2 and the adsorption of NH3 on (Fe2.5Mn0.5)1−δ O4 were obviously promoted, so NO conversion on (Fe2.5Mn0.5)1−δ O4 mainly followed the Eley–Rideal mechanism especially at higher temperatures. Both the nitrate route and the over-oxidization of adsorbed ammonia species contributed to the formation of N2O on (Fe2.8Mn0.2)1−δ O4 above 140°C. However, the formation of N2O on (Fe2.5Mn0.5)1−δ O4 mainly resulted from the over-oxidization of adsorbed ammonia species. Although the activity of (Fe2.5Mn0.5)1−δ O4 was suppressed in the presence of H2O and SO2, the deactivated catalyst can be regenerated after the water washing. [Copyright &y& Elsevier]

Chlorine species, widely presented in industrial flue gas such as the waste incineration plants, can poison the catalysts and affect the selective catalytic reduction (SCR) performance. In this work, effects of Cl on the SCR performance of V2O5–WO3/TiO2 (VW/Ti) catalysts were investigated by NH4Cl deposition. The results showed that the NOx conversion efficiency at low reaction temperature (< 300 °C) decreased with the loading of NH4Cl after calcination. It was found that instead of causing the chlorination of VW/Ti catalyst the NH4Cl decomposed into volatile Cl species due to the weak V–Cl bonding. Such decomposition reduced significantly the surface non-lattice oxygen species to inhibit NO adsorption and activation, but hardly affected the redox ability and acidity of VW/Ti catalyst. Time–resolved in situ DRIFTs results indicated that NH3 activation and the SCR process predominated by Eley–Rideal mechanism were not influenced with NH4Cl impregnation, while the SCR at low temperature following a Langmuir–Hinshelwood path was limited by the decreased and weaker binding sites for NO activation. [ABSTRACT FROM AUTHOR]

Abstract: A series of non-stoichiometric Fe–Ti spinel (Fe3−x Ti x )1−δ O4 were synthesized using a co-precipitation method and then developed as environmental-friendly and low cost catalysts for the selective catalytic reduction (SCR) of NO with NH3. As Ti was incorporated into γ-Fe2O3, the SCR reaction over (Fe3−x Ti x )1−δ O4 through the Langmuir–Hinshelwood mechanism was restrained. Therefore, the SCR activity of (Fe3−x Ti x )1−δ O4 (x ≠0) was less than that of γ-Fe2O3 at 150–250°C. However, the SCR reaction over (Fe3−x Ti x )1−δ O4 through the Eley–Rideal mechanism was promoted due to the incorporation of Ti. The SCR activity of (Fe3−x Ti x )1−δ O4 (x ≠0) was mainly related to the oxidative ability of Fe3+ cation on the surface, the concentration of NH3 adsorbed on the surface and the concentration of reducible Fe3+ cation on the surface. Although the oxidative ability of Fe3+ cation on the surface decreased due to the incorporation of Ti into γ-Fe2O3, the concentration of NH3 adsorbed on the surface and the concentration of reducible Fe3+ cation on the surface both increased. As a result, (Fe2Ti)0.8O4 showed excellent activity, selectivity, and H2O/SO2 durability for the SCR reaction at 300–400°C. [Copyright &y& Elsevier]