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An elastoplastic fracture mechanics model is formulated for determining the fracture toughness of adhesively bonded joints (ABJs) with large plastic deformations and elastic springback. The analysis is made on the basis of the post-fracture configuration of double cantilever beam (DCB) specimen consisting of two adhesively bonded thin plates of ductile metals ( e.g. , thin aluminum alloy or mild steel plates). Due to the springback after large plastic deformation, the post-fracture configuration of the adherends was noticeably different from that at the peak loading. To model the fracture process, the ductile metal adherends are treated as elastoplastic solids with power-law strain-hardening behavior, and springback of the adherends is considered in the strain energy calculation. The present model is capable of determining the fracture toughness of ABJs with extensive plastic deformation. Numerical simulations are performed to evaluate the effects of material parameters and specimen geometries on the springback and fracture toughness of the ABJs. Compared to the experimental data available in the literature, the present model can predict reliable fracture toughness of ABJs with large plastic deformations. The present study is applicable for the analysis of various fracture tests of thin ductile films with large plastic deformations and elastic springback such as peeling test, metal cutting, etc . [ABSTRACT FROM AUTHOR]

High interfacial stresses near the edges of bonded joints are responsible for their debonding failure. This paper reports a new semianalytic stress-function variational approach to the interfacial stresses of a bonded joint, which is made of a straight tension bar covered with a reinforcing patch and subjected to mechanical loads and/or uniform change of temperature. The process introduces two interfacial shear and normal stress functions, which are correlated via the approximately same radius of curvature of the slender adherends. All the stress components in the joint are expressed in terms of the interfacial stress functions based on the classic Euler-Bernoulli beam theory and equilibrium equations of elasticity. Deformation compatibility of the joint is satisfied by minimizing the complementary strain energy, which leads to a fourth-order ordinary differential equation (ODE) of the interfacial shear stress function. The interfacial shear and normal stresses are determined explicitly and compared with those given by the elementary beam theory and FEM, respectively. The results gained in this study are applicable to scaling analysis of joint strength and optimization of structural design of joints. The present formalism can be extended conveniently to the mechanical stress and thermal stress analysis of various bonded structures, including adhesively bonded joints, composite joints, and recently developed flexible electronics. [ABSTRACT FROM AUTHOR]

Abstract: This paper reports the fabrication and electrochemical properties of novel high-performance pseudosupercapacitor electrodes made of graphene-beaded carbon nanofibers (G/CNFs) surface-coated with nanostructured conducting polymers. The G/CNFs were produced by electrospinning the precursor graphene-beaded polymer nanofibers, followed by controlled pyrolysis. In situ polymerization in aqueous solution was utilized to coat an ultrathin layer of thorn-like polyaniline (PANI) nanorods onto the G/CNFs to form ternary PANI-coated G/CNFs (PANI-G/CNFs). The highly porous network morphology of PANI-G/CNFs exhibited a very large specific surface area, low internal resistance, and fast redox rate. Electrochemical characterization indicated that the PANI-G/CNF based pseudosupercapacitors carried a high value of specific capacitance up to 637 F g−1 at a current density of 0.15 A g−1 and still maintained the high value of specific capacitance of 478 F g−1 (only 25% decrease) even at a high current density of 6 A g−1. The pseudosupercapacitor showed a very good cycling stability of 87% after 1000 charge/discharge cycles at a very high current density of 15 A g−1. The experimental results indicated that the novel hierarchical, porous PANI-G/CNFs are a promising electrode material for use in high-performance energy storage devices. [Copyright &y& Elsevier]

Abstract: High interfacial stresses at the free edges of adherends are responsible for the debonding failure of adhesively bonded joints (ABJs). In this paper, a general stress-function variational method is formulated to determinate the interfacial shear and normal (peeling) stresses in ABJs in high accuracy. By extending authors’ prior work in stress analysis of bonded joints (Wu and Jenson, 2011), all the planar stress components in the adherends and adhesive layer of an ABJ are expressed in terms of four unknown interfacial stress functions, which are introduced at the upper and lower surfaces of the adhesive layer. A set of governing ordinary differential equations (ODEs) of the four interfacial stress functions is obtained via minimizing the complimentary strain energy of the ABJ, which is further solved by using eigenfunctions. The obtained semi-analytic stress field can satisfy all the traction boundary conditions (BCs) of the ABJ, especially the stress continuity across the bonding lines and the shear-free condition at the ends of adherends and adhesive layer. As an example, the stress field in an adhesively single-sided strap joint is determined by the present method, whose numerical accuracy and reliability are validated by finite element method (FEM) and compared to existing models in the literature. Parameter studies are performed to examine the dependencies of the interfacial stresses of the exemplified ABJ upon the geometries, moduli and temperature change of the adherends and adhesive layer, respectively. The present method is applicable for scaling analysis of joint strength, optimal design of ABJs, etc. [Copyright &y& Elsevier]

Abstract: This paper studies the synthesis and electrochemical characterization of novel graphene-beaded carbon nanofibers (G/CNFs) as electrode material for use in supercapacitor. The porous G/CNF films were prepared by electrospinning polyacrylonitrile (PAN)/N,N-dimethylformamide (DMF) solution dispersed with oxidized graphene nanosheets, followed by carbonization at 800 °C in a tubular quartz furnace. The morphology and chemical structure of the porous G/CNF films were characterized by means of scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Raman spectroscopy. The electrochemical behavior of the synthesized G/CNF films as supercapacitor electrodes was characterized by means of cyclic voltammetry (CV), galvanotactic charge/discharge, and electrochemical impedance test in a 6 m KOH aqueous electrolyte. Electrochemical measurements revealed that the maximum specific capacitance of the porous G/CNF electrodes reached up to 263.7 F g− 1 at a discharge current density 100 mA g− 1. Furthermore, the supercapacitor exhibited very good cycling stability of energy storage with the retention ratio of 86.9% after 2000 cycles. The high electrochemical performance of the G/CNF electrodes was attributed to the unique nanostructural configuration, high electrical conductivity, and large specific surface area of the graphene nanosheets. [Copyright &y& Elsevier]

Abstract: The morphology of liquid droplets wetting on filaments depends on the filament configuration, droplet volume, and contact angle. A stable morphology is the one that minimizes the potential energy of the droplet–filament system, while morphology transition may happen when an intermediate state exists which corresponds to a higher potential energy. This paper aims to explore such morphology transition of droplet wetting on filament rails made of two parallel identical microfilaments. Detailed numerical simulations were performed to extract the surface energy of the droplet–filament system at varying filament spacings, droplet volumes, and contact angles. Critical conditions of the morphology transition between two symmetrical wetting morphologies (i.e., liquid droplet bridge and barrel-shaped droplet) were determined. A family of characteristic curves in terms of the dimensionless droplet volume vs the filament spacing at varying contact angles was obtained, which can be used as a universal law to govern the morphology transition for such droplet–filament rail systems. The results and concepts presented in this work can be extended to broad wetting systems and utilized for the analysis and design of microfluidic devices and testers based on droplet–filament systems. [Copyright &y& Elsevier]

Abstract: This paper considers the explicit solutions of free-edge stresses near circumferential cracks in surface coatings of circular torsion bars and their application in determining the progressive cracking density in the coating layers. The problem was formulated within the framework of linear elastic fracture mechanics (LEFM). The free-edge stresses near crack tip and the shear stresses in the cross-section of the torsion bar were approached in explicit forms based on the variational principle of complementary strain energy. Criterion for progressive cracking in the coating layer was established in sense of strain energy conservation, and the crack density is thereby estimated. Effects of external torque, aspect ratio, and elastic properties on the density of progressive cracking were examined numerically. The present study shows that, in the sense of inducing a given crack density, compliant coating layer with lower modulus has much higher critical torque than that of a stiffer one with the same geometries and substrate material, i.e., compliant coating layer has greater cracking tolerance. Meanwhile, the study also indicates that thicker surface coating layer is more pliant to cracking than the thinner ones. The present model can be used for analyzing the damage mechanism and cracking tolerance of surface coatings of torsion shafts and for data reduction of torsional fracture test of brittle surface coatings, etc. [Copyright &y& Elsevier]

Abstract: Dispersion relation of antiplane surface acoustic waves (SAWs) propagating in elastic half-space coated with an anisotropic laminate was determined explicitly by means of Stroh’s formalism within the subsonic range, where is no energy leakage into the substrate. During the procedure, the governing dynamic equation in each anisotropic layer and the displacement–traction continuity at interfaces were exactly satisfied by Stroh’s functions. Explicit algebraic equation was derived for determining the dispersion relation. As an example, the wave number vs. phase velocity diagram for steel half-space coated with a graphite-fiber/epoxy laminate with a lay-up was demonstrated. The given method can be used for the study of SAW properties of anisotropic coating systems and non-destructive evaluation based on surface/guided wave methods. [Copyright &y& Elsevier]

Abstract: Probabilistic edge-delamination strength of a thermosetting polymer composite was studied experimentally in this work. During the procedure, by means of edge-delamination tensile test, the graphite–fiber/epoxy laminate made of unidirectional Toray P7051S-20Q-1000 prepregs with an optimized lay-up of [122/–122/02]S was used for examining its probabilistic distributions of the edge-delamination onset stress and the ultimate tensile strength. Acoustic emission (AE) equipment and optical microscope were utilized to capture the edge-delamination initiation and characterize the failure modes during delaminating. Fractographical analysis based on scanning electron microscope (SEM) was conducted for the characterization of the microscopic failure mechanisms of the composite laminate during edge delaminating. Probabilistic models were introduced for data reduction. Test results show that the edge-delamination onset stress and the ultimate tensile strength of the laminate tested satisfy two two-parameter Weibull distributions very well. AE signals show the main failure mode during edge delaminating is interlaminar shear failure, corresponding to that predicted by numerical simulation and confirmed by SEM fractographical results in this study. [Copyright &y& Elsevier]

This paper reports the fabrication and filtration characterization of advanced fibrous cellulose acetate (CA) membranes for high-flux water filtration. The ultrathin nonwoven fibrous CA membranes with varying fiber diameter and areal weight were produced by electrospinning and post-processed by hot-press. The filtration efficiency of the ultrathin fibrous CA membranes was characterized by controlled water-filtration tests based on artificial colloids prepared via dispersing polystyrene (PS) particles of the diameters of 5 μm, 2 μm, 500 nm, and 100 nm in water, respectively. Natural river water was further used for evaluating the filtration capability of the electrospun fibrous CA membranes. Experimental results show that the rejection rate of the present fibrous CA membranes to PS particles with the diameter of 2 μm was up to 99.8%. In addition, the filtration efficiency of the electrospun fibrous CA membranes increased with increasing areal weight of the membranes. In the case of the filtering electrospun fibrous CA membranes with the fiber diameter of ∼800 nm and membrane areal weight ∼0.005 g/cm 2 , the measured turbidity of natural river water after filtration can reach as low as 0.135 nephelometric turbidity unit (NTU) while the initial flow flux can reach up to 20,455 L/m 2 h at the feed pressure 14 psi. The study suggests that low-cost electrospun fibrous membranes can be used for stable, high-flux water microfiltration with the filtration efficiency. [ABSTRACT FROM AUTHOR]

Polymer electrolyte membrane fuel cells (PEMFCs) expect a promising future in addressing the major problems associated with production and consumption of renewable energies and meeting the future societal and environmental needs. Design and fabrication of new proton exchange membranes (PEMs) with high proton conductivity and durability is crucial to overcome the drawbacks of the present PEMs. Acid-doped polybenzimidazoles (PBIs) carry high proton conductivity and long-term thermal, chemical, and structural stabilities are recognized as the suited polymeric materials for next-generation PEMs of high-temperature fuel cells in place of Nafion® membranes. This paper aims to review the recent developments in acid-doped PBI-based PEMs for use in PEMFCs. The structures and proton conductivity of a variety of acid-doped PBI-based PEMs are discussed. More recent development in PBI-based electrospun nanofiber PEMs is also considered. The electrochemical performance of PBI-based PEMs in PEMFCs and new trends in the optimization of acid-doped PBIs are explored. [ABSTRACT FROM AUTHOR]

Abstract: Mechanically flexible mats consisting of electrospun carbon nanofibers (ECNFs) were prepared by first electrospinning aqueous mixtures containing a natural product of alkali lignin together with polyvinyl alcohol (PVA) into composite nanofiber mats followed by stabilization in air and carbonization in an inert environment. Morphological and structural properties, as well as specific surface area, total pore volume, average pore size, and pore size distribution, of the lignin-based ECNF mats were characterized; and their electrochemical performances (i.e., capacitive behaviors) were evaluated by cyclic voltammetry, galvanostatic charge/discharge, and electrochemical impedance spectroscopy. The lignin-based ECNF mats exhibited outstanding performance as free-standing and/or binder-free electrodes of supercapacitors. For example, the ECNFs made from the composite nanofibers with mass ratio of lignin/PVA being 70/30 (i.e., ECNFs (70/30)) had the average diameter of ∼100 nm and the Brunauer–Emmett–Teller (BET) specific surface area of ∼583 m2 g−1. The gravimetric capacitance of ECNFs (70/30) electrode in 6 M KOH aqueous electrolyte exhibited 64 F g−1 at current density of 400 mA g−1 and 50 F g−1 at 2000 mA g−1. The ECNFs (70/30) electrode also exhibited excellent cycling durability/stability, and the gravimetric capacitance merely reduced by ∼10% after 6000 cycles of charge/discharge. [Copyright &y& Elsevier]

Abstract: This paper reports the fabrication and mechanical properties of hybrid multi-scale epoxy composites reinforced with conventional carbon fiber (CF) fabrics surface-attached with electrospun carbon nanofiber (ECN) mats. The ECNs were prepared via thermal treatments of polyacrylonitrile copolymer nanofibers, which were produced by the electrospinning technique and collected as overlaid mats on the T300 CF fabrics. The ECN-CF fabrics/mats were used as innovative reinforcement fillers for the fabrication of hybrid multi-scale composites (with SC-15 epoxy resin) through the composite-manufacturing technique of vacuum assisted resin transfer molding. Three-point bending test and short-beam shear test were carried out to evaluate the strengthening/toughening effects of ECNs on mechanical properties of the novel composites. The results indicated that out-of-plane mechanical properties of the ECN-CF/epoxy composites were considerably higher than the control sample of traditional CF/epoxy composites. [Copyright &y& Elsevier]

Abstract: In this study, hybrid multi-scale composites were developed from glass microfiber fabrics (GFs) and nano-epoxy resins containing electrospun glass nanofibers (EGNFs). The hypothesis was that, through dispersing a small amount of EGNFs into epoxy resin, mechanical properties (particularly out-of-plane mechanical properties) of the resulting hybrid multi-scale composites would be significantly improved. The composites were fabricated by the technique of vacuum assisted resin transfer molding (VARTM). The interlaminar shear strength, flexural properties, impact absorption energy, and tensile properties of the composites were evaluated, and the results were compared to those acquired from GFs/epoxy composite as well as GFs/epoxy composites containing chopped glass microfibers (GMFs); additionally, the reinforcement and/or toughening mechanisms were investigated. The study revealed that the nano-epoxy resin with 0.25wt.% of EGNFs resulted in substantial improvements on mechanical properties of the resulting hybrid multi-scale composites. [Copyright &y& Elsevier]