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Gold extraction from ores using non-cyanide lixiviants is currently a significant topic worldwide. Herein, we report the synthesis of an eco-friendly lixiviant that not only is much less toxic than sodium cyanide (NaCN) but also shows excellent effect in the leaching of gold. The lixiviant can be synthesized from roasting of the well-mixed potassium hexacyanoferrate(II) trihydrate (K 4 Fe(CN) 6 ·3H 2 O), urea (CO(NH 2) 2) and sodium carbonate (Na 2 CO 3) with a mass ratio of 1:6:2 under the conditions of heating rate 10–15 °C/min, roasting temperature 700 °C, and temperature holding time 1 h. X-ray diffraction (XRD) analysis suggested that the synthetic lixiviant contained a new phase that is efficient in leaching gold playing the role of the gold lixiviant. Gold leaching results from a gold concentrate showed that the synthetic lixiviant not only has a gold leaching efficacy comparable to NaCN but also achieves faster leaching kinetics than NaCN. Under the optimal leaching conditions of lixiviant concentration 0.3 wt%, initial pH 10–11, liquid to solid ratio 2.5:1, and agitation speed 600 rpm, the synthetic lixiviant could achieve a gold extraction of 87.0% in 8 h and 97.5% in 24 h on the gold concentrate, reducing the leaching time by 12 h compared with cyanidation (97.1% gold extraction in 36 h). In addition, the method of activated carbon adsorption was shown to efficiently adsorb almost all the gold (> 99.0%) from the leach solutions, and the barren leach solution could be reused back to the leaching stage to extract gold. • An efficient gold lixiviant is synthesized by a simple roasting process. • The synthetic lixiviant has a gold leaching efficacy comparable to NaCN. • The synthetic lixiviant achieves faster gold leaching kinetics than NaCN. • The lixiviant can leach 97.5% of gold from a gold concentrate in 24 h. • Activated carbon adsorption efficiently recovers gold (>99.0%) from leach solutions. [ABSTRACT FROM AUTHOR]