Search

Polyvinylidene fluoride (PVDF) electrospun nanofibrous membranes (ENMs), consolidated with a heatpress process and of various thicknesses were fabricated and tested in a DCMD cell at five different operating conditions. Membranes as thin as 27 μm were sufficiently robust for evaluation and gave a transmembrane flux as high as 60 L/h m 2 . An analytical model was created to estimate the optimal membrane thickness for DCMD operations. It is found that the value of optimal thickness increases with reduced heat transfer coefficients; decreased feed inlet temperature; increased membrane permeability; and increased salinity. Even for 10% NaCl the predicted optimum was estimated to be 13 μm which was too thin for experimental confirmation. Based upon this analysis but with due allowance for the variation of heat transfer coefficients with temperature dependent physical properties a single Matlab model was created to fit the five sets of data. With the introduction of a structural derivation factor, which reflected the experimentally determined variation of porosity and pore size with thickness, the model was found to fit the data very well. [ABSTRACT FROM AUTHOR]

Abstract: As an extended exploration of process enhancing strategies, nine modified hollow fiber modules with various turbulence promoters were designed and modeled using a two dimensional computational fluid dynamic (CFD) heat-transfer model to investigate their potential in improving heat transfer and module performance for a shell-side feed direct contact membrane distillation (DCMD) system. With the aids of turbulence promoters, the feed heat-transfer coefficient h f of the modified modules generally showed much slower decreasing trends along the fiber length compared to the original (unmodified) module. A 6-fold h f enhancement could be achieved by a modified module with annular baffles and floating round spacers. Consistently, the temperature polarization coefficient (TPC) and mass flux distribution curves of these modified modules presented increasing trends and gained an optimal improvement of 57% and 74%, respectively. With the local flow fields and temperature profiles visualized in CFD simulations, it was confirmed that an appropriate selection of turbulence promoters could promote intense secondary flows and radial mixing to improve the shell-side hydrodynamics and enhance heat transfer. Moreover, an increase of flow velocity was used and compared as a conventional approach to improve hydrodynamics. It was found that a well-designed module could bring more significant enhancement for a liquid-boundary layer dominant heat-transfer process. Finally, the hydraulic energy consumption (HEC) caused by the insertion of turbulence promoters or the increase of circulating velocity was compared. Configurations with attached quad spacers or floating round spacers achieved a good compromise between enhanced permeation fluxes and modest HECs. Overall, the TPC decreases with increasing MD coefficient (C) values and operating temperatures; while the thermal efficiency increases dramatically with increasing C and operating temperatures in a MD system. [Copyright &y& Elsevier]

Membrane distillation (MD) technology is being extensively studied to address operational challenges such as undesired thermal efficiency and scaling phenomenon in recovering valuable solutes and minimizing brine disposal. This study has explored the working mechanisms of utilizing gas–liquid two-phase flow to enhance heat transfer and mitigate scaling formation in MD concentration process, based on the quantification of heat-transfer coefficients and local scaling-resistance associated with bubble size properties. With the aid of direct observation and statistical analysis on the bubble characteristics in a specially-designed direct contact MD (DCMD) module, it was found that the bubbles with small mean bubble size and narrow size distribution were preferred for creating even flow distribution, intensifying mixing and enhancing surface shear rate. Compared to non-bubbling DCMD, the heat-transfer coefficient and temperature polarization coefficient ( TPC ) reached up to 2.30- and 2.13-fold, respectively, at an optimal gas flowrate of 0.2 L min −1 . With the theoretical expressions for local scaling resistance derived based on the resistance-in-series model, the relative permeation flux ( J w/o|t=t1 /J w/o|t=0 ) in non-bubbling MD was quantified and found to rapidly decline by 65% as the concentration process progressed, consistent with the increasing trend of the ratio of local scaling resistance to the overall resistance ( r fl /r ov ). Fortunately, the introduction of gas bubbles has shown benefits for supersaturation brine concentrating MD process – remarkably decreased the local-scaling resistance due to bubble-intensified shear stress and enhanced hydrodynamics. Also, the total water removal for the brine concentration process was significantly improved by 131% and the discharged brine volume was reduced accordingly at appropriately selected gas flow rates. Nevertheless, at inappropriately high gas flowrates, high energy consumption and potential fiber breakage should be avoided. [ABSTRACT FROM AUTHOR]