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Environmental problems of urban and rural areas are now high on the agenda of industrialized countries, becoming a key challenge for regional-level policymaking. The mutual influence of population growth, economic and technological development, and the anthropogenic pressure on the environment is still insufficiently studied in many countries, including Russia. In this paper, this relationship is studied for the municipalities of Angara–Yenisey Siberia using an ensemble of the STIRPAT-like regression models, adapted according to the available data. We found that population size and gross municipal product were positively associated with pollutant emissions (p < 0.01), while energy efficiency had no significant impact on air pollution. In addition to the poor national data quality and completeness issues, which can distort statistical conclusions, the cause of the observed lack of spatial correlation between energy efficiency and air pollutant emissions may be path dependence and an insufficient pace of transition to a greener economy. This leaves room for institutional transformations aimed at intensifying energy efficiency to reduce the environmental burden. [ABSTRACT FROM AUTHOR]