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In this study, Melamine–formaldehyde (MF) resins were subjected to modification with benzoguanamine (BG) to produce MF-BG resins, followed by a comprehensive analysis of their chemical composition using advanced spectroscopic techniques such as Fourier transform infrared (FTIR), 1H-NMR, and 13C-NMR spectroscopy. The flame-retardant characteristics and thermal decomposition behavior of papers impregnated with MF-BG were examined and contrasted with those treated with standard MF. In particular, the optimized MF-BG5-treated paper exhibited a Limiting Oxygen Index (LOI) value exceeding 30%, and analysis using a cone calorimeter indicated a notable decrease in parameters such as the heat-release rate (P-HRR), total heat release (THR), smoke production rate (SPR), and total smoke production (TSP) when compared to papers impregnated with standard MF. The findings from the scanning electron microscopy (SEM) analysis of the residual char following cone calorimeter experiments revealed that the MF-BG5-treated paper exhibited a denser and more uniform char formation. This phenomenon consequently limits the emission of combustion by-products and impedes the spread of flame. This study provides a feasible method for low-pressure laminates with better flame retardancy by using the BG additive up to a limit in MF resin. [ABSTRACT FROM AUTHOR]

This paper identifies physical properties of an interesterified palm‐based fat (EIEPO) that predict oil binding capacity (OBC). A 100% EIEPO sample, 50% EIEPO sample diluted with 50% soybean oil (SBO), and a 20% EIEPO sample diluted with 80% SBO were used to test how saturation level impacts OBC. All samples were crystallized using either a fast (6.4°C/min) or slow (0.1°C/min) cooling rate as well as with or without the application of high‐intensity ultrasound (HIU; 20 kHz) to generate a wide range of physical properties. Immediately after crystallization, the sample's physical properties, including crystal microstructure, solid fat content (SFC), viscoelasticity (G′, G″, and δ), melting behavior, hardness, and OBC (centrifuge method) were quantified. The samples were then stored for 48 h at 22 and 5°C and the aforementioned physical properties were measured again, with one additional measurement for the samples stored at 5°C—OBC using a filter paper method (OBCp). The results indicate that OBC can be optimized in a palm‐based fat by modifying the physical properties which was achieved via the processing conditions. Both measurements of OBC were significantly correlated with SFC, hardness, δ, and enthalpy. A model was developed to predict a sample's OBCc using the following dominant variables—SFC, hardness, peak temperature, enthalpy, and the number of crystals. These results suggest that OBC can be predicted using a sample's SFC, hardness, peak temperature, enthalpy, and number of crystals and that SFC, hardness, and enthalpy are main drivers of OBC. [ABSTRACT FROM AUTHOR]

Abstract: Large numbers of soil samples are routinely analyzed using methylene blue (MB) titration to determine clay content. Although, the MB filter paper spot test titration is simple, it is labor-intensive, subjective, and leaves no record for subsequent re-examination. Preliminary thermometric monitoring of the titration indicated a switch from endothermic to exothermic reaction during titration. We examined this nearly universal property of physicochemical processes as a potential replacement method to automate the MB clay titration, making use of literature data. We translated the isothermal enthalipmetric titration of montmorillonite using MB by Rytwo and Ruiz-Hitzky to an adiabatic thermometric titration (2003). The plot of temperature versus titrant volume gave two intersecting linear segments dependent on the titrated percentage of the clay''s cation exchange capacity (CEC). The MB filter paper spot test endpoint reflects the first excess MB that persists in the solid suspension, which also happens to be a function of the clay''s CEC. The spot test endpoint is correlated to the thermometric indicator point and, for montmorillonite, the two are related by an exact factor of two. Although this factor will naturally be dependent on the clay minerals in the samples, the analyses show that the thermometric indicator titration method is a viable replacement for the spot test. The proposed automation is commonplace as it is practiced with other types of titrations. [Copyright &y& Elsevier]

Traditional fire warning sensors usually work under directly fire attack or relatively high temperature and overlook electrical safety. Therefore, it is imperative to develop an efficient early fire warning sensor with the circuit safety during flame exposure. Herein, a flame-retardant paper with thermosensitive fire-alarm response and self-cutting performance is proposed. The paper consists of shape memory thermoplastic polyurethane (SMPU) and MXene is prepared via facile electrospinning and vacuum filtering process, which can be utilized as a fire early alarm triggered by the shape memory behavior of SMPU. The SMPU/MXene paper can provide a stable detection signal and ideal early fire warning responses when the ambient temperature is above transition temperature of SMPU. Meanwhile, it is possible for SMPU/MXene paper to serve as a fuse to protect the fire alarm system from fire attacking based on the electro-activated property. Compared to SMPU paper, SMPU/MXene paper showed superior fire retardancy with a rapid self-extinguishing performance, as well as 66.0% and 49.8% reduction in peak of heat release rate (pHRR) and total heat rate (THR), respectively. This work provides a novel perspective for designing early detection fire-alarm sensors and fire-protection applications. [ABSTRACT FROM AUTHOR]

About 7% of people's daily time is spent in taking vehicles between office and home. Besides, with the improvement of the living standard in today's society, people's requirements for a comfortable environment inside the car are constantly increasing and this must rely on an effective vehicle air conditioner to maintain the comfort of the cabin environment. In general, a vehicle air conditioner uses the air-mixing mode to regulate the temperature control system. In this mode of operation, the compressor needs to work continuously, which is extremely energy consuming. The vehicle's air conditioner is greatly affected by the inner and outer heat load, which are generated therein. Furthermore, the heat load is instantly changeable. Therefore, only when the controller can adapt to the feature of heat load, then we can find the optimal control method, thus enabling the vehicle's air conditioner to interact with the actual heat load to supply the balanced cooling capacity and, as a result, create the most comfortable environment inside the cabin with minimum energy consumption. For this purpose, we bring up in this paper a low-energy-consumption smart vehicle air-conditioning control system to detect total heat load, which can change the vehicle's air-conditioning capacity mode to maintain the average temperature at 25.2°C∼26.2°C and the average humidity at 46.6%∼54.4% in the cabin. When the inner heat load is stable, the rest times of the compressor can reach 16∼23 times per hour, which attains a rate of fuel saving around 21%∼28%. With the proposed architecture, the purpose of the low-energy-consumption vehicle air-conditioning system can be achieved, which, at the same time, creates a comfortable environment inside the cabin. [ABSTRACT FROM AUTHOR]

The experimental measurement of density and enthalpy of mixture for two binary liquid mixtures of n-tridecane or n-tetradecane with decalin was reported in this paper. The measurements were conducted at a temperature range of 293.15–323.15 K and at 303.15 K using calorimeter C80. The mixtures were analyzed at various proportions, including the entire composition range and dilute solutions. The excess molar volume (VE) and excess molar enthalpy (HE) of mixtures were calculated and fitted using the Redlich–Kister equation. The paper observed the expansion phenomenon for the VE at all temperatures, including over the entire composition range and dilute solutions. Additionally, the HE exhibited endothermic behavior at the studied temperature range and composition range. The Prigogine–Flory–Patterson (PFP) theory was utilized to predict both thermodynamic properties, namely the VE and HE. The results obtained using the PFP theory were compared with those obtained using the Treszczanowicz and Benson association (TB) model for VE and with the NRTL, Wilson, and Flory models for HE. The PFP model, which employed a single-fitted parameter to describe VE, demonstrated satisfactory performance in predicting VE. Conversely, the Treszczanowicz and Benson association (TB) model yielded relatively poor results in fitting VE. However, the NRTL, Wilson, PFP, and Flory models exhibited good performance in predicting HE. [ABSTRACT FROM AUTHOR]

Atlantic time‐mean heat transport is northward at all latitudes and exhibits strong multidecadal variability between about 30°N and 55°N. Atlantic heat transport variability influences many aspects of the climate system, including regional surface temperatures, subpolar heat content, Arctic sea‐ice concentration and tropical precipitation patterns. Atlantic heat transport and heat transport variability are commonly partitioned into two components: the heat transport by the Atlantic Meridional Overturning Circulation (AMOC) and the heat transport by the gyres. In this paper we compare four different methods for performing this partition, and we apply these methods to the Community Earth System Model Large Ensemble at 34°N, 26°N and 5°S. We discuss the strengths and weaknesses of each method. The four methods all give significantly different estimates for the proportion of the time‐mean heat transport performed by AMOC. One of these methods is a new physically‐motivated method based on the pathway of the northward‐flowing part of AMOC. This paper presents a preliminary version of our method that works only when the AMOC follows the western boundary of the basin. All the methods agree that at 26°N, 80%–100% of heat transport variability at 2–10 years timescales is performed by AMOC, but there is more disagreement between methods in attributing multidecadal variability, with some methods showing a compensation between the AMOC and gyre heat transport variability. Plain Language Summary: Scientists often want to quantify how much heat is transported by the Atlantic Meridional Overturning Circulation (sometimes called the "Conveyor Belt" circulation) and how much heat is transported by the ocean's gyres. This paper compares some different methods for estimating the heat transport by the overturning circulation and by the gyres, including a new method that has not been used before. There are significant differences in the results of each method, and here we discuss the strengths and weaknesses of each method. The heat transport at about 30°N has a lot of variability: all the methods agree that short‐timescale variability (2–10 years timescale) is due to the overturning circulation. All methods agree that more than half of the time‐mean heat transport across 30°N is performed by the overturning, but the exact proportion varies from 65% to 120% depending on the method we use. Key Points: We compare four diagnostics for Atlantic Meridional Overturning Circulation (AMOC) heat transport that partition the flow into mass‐conserving gyre and overturning componentsA new physically‐motivated method is compared with the standard method that relies on zonally averaging the temperature and velocity fieldsAll four methods yield different estimates of the fraction of time‐mean heat transport performed by AMOC [ABSTRACT FROM AUTHOR]

Copyright of Atomic Energy Science & Technology is the property of Editorial Board of Atomic Energy Science & Technology and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

A 30-year (1980–2010) climatology of the major variables and terms of the transformed Eulerian-mean (TEM) momentum and thermodynamic equations is constructed by using four global atmospheric reanalyses: the Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2); the Japanese 55-year Reanalysis (JRA-55); the European Centre for Medium-Range Weather Forecasts (ECMWF) interim reanalysis (ERA-Interim); and the Climate Forecast System Reanalysis (CFSR). Both the reanalysis ensemble mean (REM) and the differences in each reanalysis from the REM are investigated in the latitude–pressure domain for December–January–February and for June–July–August. For the REM investigation, two residual vertical velocities (the original one and one evaluated from residual meridional velocity) and two mass streamfunctions (from meridional and vertical velocities) are compared. Longwave (LW) radiative heating and shortwave (SW) radiative heating are also shown and discussed. For the TEM equations, the residual terms are also calculated and investigated for their potential usefulness, as the residual term for the momentum equation should include the effects of parameterized processes such as gravity waves, while that for the thermodynamic equation should indicate the analysis increment. Inter-reanalysis differences are investigated for the mass streamfunction, LW and SW heating, the two major terms of the TEM momentum equation (the Coriolis term and the Eliassen–Palm flux divergence term), and the two major terms of the TEM thermodynamic equation (the vertical temperature advection term and the total diabatic heating term). The spread among reanalysis TEM momentum balance terms is around 10 % in Northern Hemisphere winter and up to 50 % in Southern Hemisphere winter. The largest uncertainties in the thermodynamic equation (about 50 %) are found in the vertical advection, for which the structure is inconsistent with the differences in heating. The results shown in this paper provide basic information on the degree of agreement among recent reanalyses in the stratosphere and upper troposphere in the TEM framework. [ABSTRACT FROM AUTHOR]

Today, the World Health Organization has declared a global health emergency, caused by the Monkeypox outbreak. In the monthly analysis for June, 3500 cases have been reported in 50 countries around the world. In the analysis for July, more than 30000 cases have been reported in 75 countries. Thus, in the circumstances of the continuing COVID-19 pandemic, the appearance and dynamics of spreading of Monkeypox is alarming. In this paper, for the first time, elemental composition of Poxvirus, Monkeypox virus, and Vaccinia virus have been reported. Additionally, thermodynamic properties have been reported for nucleic acids, nucleocapsids, and entire virus particles. The similarity in chemical composition and thermodynamic properties of the analyzed viruses has been used to explain the crossed immunity to Poxviruses. Finally, binding thermodynamic properties have been reported for the Vaccinia virus. [ABSTRACT FROM AUTHOR]

Existing research on the analysis heat pump operation generally focuses on the efficiency of doing work while ignores heat loss in the transfer process. Hence, heat pumps are often studied based on theory of minimum entropy production. However, this theory is rarely applied to optimizing heat transfer process without heat work conversion. Taking the air source heat pump hot water supply system of a hotel building as an example, this paper simulates the heat production, power and COP of the air source heat pump during operation based on the theory of entransy and entransy dissipation proposed by Professor Zengyuan Guo. The findings show that heat pump operates best at inlet water temperatures of 293 K and 298 K, with a COP of 4.8. In the water at a temperature of 298 K, water temperature can be adjusted by the function of heating capacity between 30 kW and 40 kW to minimize the system's entransy dissipation, where the system's unit power consumption reaches its minimum at 9 kW, corresponding to an entransy dissipation of 245.4 kJK. This study provides a good research idea to optimize the thermal power conversion process using the theory of entransy and entransy dissipation. [ABSTRACT FROM AUTHOR]

The magnetohydrodynamics (MHD) model of the alternating current (AC) arc is complex, so a simplified equivalent heat source (EHS) model can be used to replace the complex model in studying the AC arc's thermal characteristics and cable fire risk. A 2D axisymmetric AC arc MHD simulation model in the short gap of a copper-core cable is established in this paper. The AC arc voltage and current obtained by the model are consistent with experiments. The AC arc's heat source distribution obtained by the MHD model is fitted to obtain the heat source function Q of the AC arc. Q is divided into 16 independent segmented heat sources, and a correction matrix is constructed to optimize the segmented heat sources. A neural network and a genetic algorithm give the prediction model and the optimal correction matrix of the segmented heat source. The EHS model optimized by the optimal correction matrix can obtain a minimum temperature error of 5.8/4.4/4.2% with the MHD model in different AC arc peak currents 2/4/6 A. The probability of a cable fire is calculated by using AC arc's optimized EHS model when different numbers of AC arcs are generated randomly in AC half-waves. The EHS model can replace the complex MHD model to study the thermal characteristics of AC arcs and quickly calculate the probability of a cable fire caused by random AC arcs. [ABSTRACT FROM AUTHOR]

This paper presents the results of numerical simulations of heat transfer in a tube with a protective chromium layer on the inner surface made of steel, with different shrinkage temperatures. Shrinkage in the steel is an unfavorable phenomenon because it causes cracks in the chrome coating. The cracks contribute to the peeling of the protective material on the inner surface of the tube. Wear and damage to the chrome layer significantly shortens the tube's service life. The influence of the type of steel with medium carbon content on heat transfer for a sequence of ten, thirty, and sixty heat impulses was examined. Simulations were carried out for two selected steels with clearly different shrinkage temperatures, i.e., 30HN2MFA and X37CrMoV5-1 (1.2343). In 30HN2MFA steel, the shrinkage effect occurred at a temperature of approx. 750 °C, while in X37CrMoV5-1 steel it occurred at a temperature of approx. 870 °C. In the computational model, 30 cross-sections of the three-meter-long tube were analyzed. A time-dependent heat transfer coefficient was calculated in each zone. Heat transfer simulations were carried out using COMSOL version 6.1 software. This paper shows that for X37CrMoV5-1 steel, the shrinkage temperature on the inner surface of the tube was reached after approx. 60 heat impulses, while for 30HN2MFA steel, it was reached after approx. 30. The greatest differences in the number of impulses occurred for a pipe with a 200 µm thick chrome layer. [ABSTRACT FROM AUTHOR]

A common belief is that any closed, counterclockwise cycle on a pV diagram represents a refrigerator or heat pump. It has been established that this is not the case, but previous papers on this topic have made unnecessary assumptions about the temperatures of the energy reservoirs and about how the system exchanges energy with the reservoirs. Relaxing these assumptions leads to a wide array of unexpected behaviors. In some cases, the same pV cycle can be a heat pump, a cold pump, or a Joule pump simply by changing how the system is connected to the reservoirs. This paper explores the strange world of counterclockwise cycles. Editor's note: In this paper, author Randall Knight explores the rich behavior of counterclockwise thermodynamic cycles. A counterclockwise cycle can function as a heat pump or refrigerator, but this is not the only possibility. The choice of thermal reservoirs and the choice of which reservoir heat is absorbed from and exhausted to during the cycle affect the coefficient of performance and even the basic function of the device. The author illustrates these possibilities through an analysis of counterclockwise Carnot, Kelvin, Brayton, and Stirling cycles. The analysis includes interesting possibilities, such as a cycle that operates with a single reservoir, as well as practical applications like the role of heat exchangers. The surprising results of this analysis will likely be of interest to anyone who has studied thermodynamics, and the material can easily be incorporated into any course that includes thermodynamics, from introductory physics to graduate study. [ABSTRACT FROM AUTHOR]

In this paper, we explore different prognostic methods to account for skin sea surface temperature diurnal variations in a coupled ocean–atmosphere regional model of the Mediterranean Sea. Our aim is to characterise the sensitivity of the considered methods with respect to the underlying assumption of how the solar radiation shapes the warm layer of the ocean. All existing prognostic methods truncate solar transmission coefficient at a warm-layer reference depth that is constant in space and time; instead, we implement a new scheme where this latter is estimated from a chlorophyll dataset as the e -folding depth of solar transmission, which thus allows it to vary in space and time depending on seawater's transparency conditions. Comparison against satellite data shows that our new scheme, compared to the one already implemented within the ocean model, improves the spatially averaged diurnal signal, especially during winter, and the seasonally averaged one in spring and autumn, while showing a monthly basin-wide averaged bias smaller than 0.1 K year-round. In April, when most of the drifters' measurements are available, the new scheme mitigates the bias during nighttime, keeping it positive but smaller than 0.12 K during the rest of the monthly averaged day. The new scheme implemented within the ocean model improves the old one by about 0.1 K, particularly during June. All the methods considered here showed differences with respect to objectively analysed profiles confined between 0.5 K during winter and 1 K in summer for both the eastern and the western Mediterranean regions, especially over the uppermost 60 m. The new scheme reduces the RMSE on the top 15 m in the central Mediterranean for summertime months compared to the scheme already implemented within the ocean model. Overall, the surface net total heat flux shows that the use of a skin sea surface temperature (SST) parameterisation brings the budget about 1.5 Wm-2 closer to zero on an annual basis, despite all simulations showing an annual net heat loss from the ocean to the atmosphere. Our "chlorophyll-interactive" method proved to be an effective enhancement of existing methods, its strength relying on an improved physical consistency with the solar extinction implemented in the ocean component. [ABSTRACT FROM AUTHOR]

Nuclear thermal propulsion is an evolving technology that can be utilized for long-distance space travel. This technology yields the advantage of a high thrust and specific impulse, but requires an examination of the potential design adjustments necessary to enhance its feasibility. The development of nuclear thermal propulsion requires a comprehensive understanding of the system-level behavior during transient and steady-state operation. This paper extends our previous research by including the proper handling of turbomachinery with multi-channel thermal hydraulic simulations only for steady-state solutions. The system-level approach presented here enables the treatment of the turbopump components through non-dimensional analysis that eliminates the assumption of constant efficiencies. All the other components within the system (e.g., reflector and core) can be discretized to multiple channels and layers, in which the full thermal hydraulic solution is established. The approach chosen here enables the realistic modeling of the propellant flow within the expander cycle by capturing the pressure losses, mass flow rate splits, and enthalpy gain for various operational conditions. The verification of the package is completed through point comparisons of previous investigations into similar system designs. Furthermore, sensitivity studies are used to benchmark the capabilities of the package and investigate solution variations due to the perturbation of operational conditions and regimes. The sensitivity studies performed here are important to capture variation in flow characteristics (e.g., temperature, pressure, mass flow rates) for different design objectives such as the thrust and specific impulse. This work demonstrates that system-level simulations lacking multi-channel capability and proper turbomachinery treatment may yield higher uncertainties in understanding the engine's response and characteristics to changing various requirements. This is extremely important when screening the design space of such propulsion systems and when transient simulations are required. [ABSTRACT FROM AUTHOR]

A third paper [[3]] modelled the performance of a cogeneration system in a greenhouse and evaluates its economic efficiency versus the European country and the kind of cultivation. The first [[1]] analysed the long-term economic performance of some projects in the Mediterranean climate of Athens, Greece, while the second [[2]] focused on the short-term, detailed economic performance of a cogeneration system in a hospital. The most favourable conditions for cogeneration use were found in Italy and the United Kingdom, with average spark ratios of more than 4, resulting in an annual total cost of heating energy close to -7 EUR/m SP 2 sp per year. [Extracted from the article]

We present here a novel experimental setup able to measure the enthalpy of sublimation of a given compound by means of Piezoelectric Crystal Microbalances (PCM). This experiment was performed in the TG-Lab facility in IAPS-INAF, dedicated to the development of TGA sensors for space measurements, such as detection of organic and non-organic volatile species and refractory materials in planetary environments. In order to study physical-chemical processes concerning the Volatile Organic Compounds (VOC) present in atmospheric environments, the setup has been tested on Dicarboxylic acids. Acids with low molecular weight are among the components of organic fraction of particulate matter in the atmosphere, coming from different sources (biogenic and anthropogenic). Considering their relative abundance, it is useful to consider Dicarboxylic acid as "markers" to define the biogenic or anthropogenic origin of the aerosol, thus obtaining some information of the emission sources. In this work, a temperature controlled effusion cell was used to sublimate VOC, creating a molecular flux that was collimated onto a cold PCM. The VOC re-condensed onto the PCM quartz crystal allowing the determination of the deposition rate. From the measurements of deposition rates, it was possible to infer the enthalpy of sublimation of Adipic acid, i.e. ? Hsub: 141.6 ± 0.8 kJ mol-1, Succinic acid, i.e. 113.3 ± 1.3 kJ mol-1, Oxalic acid, i.e. 62.5 ± 3.1 kJ mol-1 and Azelaic acid, i.e. 124.2 ± 1.2 kJ mol-1 (weight average values). The results obtained are in very good agreement with literature within 10% for the Adipic, Succinic and Oxalic acid. [ABSTRACT FROM AUTHOR]

The combustion process of traditional diesel engines is mainly determined by the injection timing of diesel. There is a trade-off relationship between the soot and NOx (nitrogen oxides) during this combustion process, making it difficult to reduce these two emissions simultaneously. The use of methanol can not only solve the above problem, but also replace some fossil fuels. However, the effects of methanol injection into the intake duct on the flame propagation in diesel/methanol dual-fuel engines is not yet clear, and there is relatively little research on it. The effects of methanol addition on the combustion process of diesel/methanol dual fuel (DMDF) were achieved based on a modified optical engine in this paper. One injector is installed on the intake inlet to inject methanol, and the other injector is installed in the cylinder to inject diesel in two stages before the top dead center of compression. There are three tests conducted separately in this paper. Firstly, the effects of the methanol ratio (40%, 50%, 60%, and 70%) on the combustion process are investigated, with the total heat remaining unchanged. Secondly, the effects of the pre-injection mass of diesel (20%, 30%, 40%, and 50%) on the combustion process are investigated, which keeps the total diesel mass unchanged. Finally, the effects of the total mass of diesel on the combustion process are investigated while maintaining the mass of methanol unchanged. The dual-fuel combustion process is recorded by a high-speed camera. A combustion analyzer and other equipment were used to analyze the combustion. The results showed that CA10 is delayed, the pressure and the heat release rate (HRR) are reduced, and the number of pixels of the KL factor (KL) decreases significantly with the increasing methanol ratio. CA10 and CA50 are advanced, the pressure and HRR decrease, and the KL increases when the mass of pre-injected diesel increases. CA10 and CA50 are advanced, respectively, and CA90 is postponed due to the increase in diesel mass. The pressure and HRR increase, and the KL increases when the total mass of diesel increases. [ABSTRACT FROM AUTHOR]

In this paper, the finite volume method was used to numerically study the heat transfer and flow of double-pipe heat exchangers (DPHE) under static and ocean motion conditions. The ocean motion is simplified as a harmonic oscillation with the center of the DPHE as the axis of rotation. In addition the flow direction and the inlet Reynolds number, the effects of amplitude and period ontal heat transfer coefficient, pump power and thermal performance factor were also analyzed quantitatively. The results showed that as the heat exchanger oscillates, the total heat transfer coefficient, and pump power exhibit a periodic change and the period is half of the oscillating period of the heat exchanger. The total heat transfer coefficients for all oscillating DPHE are higher compared to static conditions, reaching a maximum improvement of 9.84% at low Reynolds numbers. The total heat transfer coefficient and pump power of DPHE under oscillation are significantly regular, positively correlated with amplitude and negatively correlated with period. When the amplitude exceeds 0.5 rad/s, the oscillatory condition has thermal performance improvement for the oscillating DPHE with the inner tube with low Reynolds number and the outer tube with high Reynolds number. In the optimum condition, the thermal performance of the inner and outer tubes is improved by 5.01% and 1.48%, respectively. The thermal performance coefficient of DPHE hardly changed when the period exceeded 5 seconds. The results herein provide a theoretical basis for predicting the development of offshore double-pipe heat exchange equipment. [ABSTRACT FROM AUTHOR]

Biothermodynamics is a discipline which has developed intensely during the last 50 years. Thermodynamic properties have been reported for humans, animals, plants, and microorganisms. However, this paper reports for the first time the empirical formula and thermodynamic properties for insects. Thermodynamic properties can be applied in research on thermodynamic interactions between organisms and their environment, as well as between organisms themselves. This paper reports for the first time the empirical formula and reactions of catabolism, biosynthesis and entire metabolism for Bombyx mori (domestic silk moth), as well as the thermodynamic properties of Bombyx mori. It is shown that growth of Bombyx mori is tightly related to catabolism of carbohydrates and lipids, which represents the driving force for the entire metabolism. [ABSTRACT FROM AUTHOR]

This paper deals with the austempering of ductile iron (ADI) and clarifies the influential austempering parameters during the production of ADI. During the austempering process, the heat treatment parameters can be varied, thus influencing the final microstructure and, of course, the mechanical properties of ADI. To appropriately conduct experiments and obtain good results, an experimental plan was developed using the Design Expert 13 software. Along with the heat treatment parameters, the influence of the copper content on the ADI toughness, tensile strength, and elongation was determined. The obtained results from this experiment were used to develop unique mathematical models which describe the influences of heat treatment and copper content on the observed mechanical properties of ADI samples. These mathematical models can be applied to predict the analysed mechanical properties of ADI in the dependence of heat treatment parameters and copper content in base ductile iron. For the multi response optimisation of toughness, tensile strength, and elongation, a hybrid grey-fuzzy technique was presented as a significant contribution to the enhancement of the analysed mechanical properties. Consequently, the copper content and heat treatment parameter levels that resulted in the maximal mechanical properties' functions were defined. [ABSTRACT FROM AUTHOR]

In this paper, the influence of bismuth content and heating rate on the morphology of MnS inclusions in bismuth-containing free-cutting steel during heating was investigated through in situ observation experiments and 3D electrolytic corrosion experiments. By observing the microscopic morphology of inclusions in the original sample, it was found that MnS inclusions in the sample were rod-shaped, spherical, irregular, small in size, and mostly clustered at the grain boundary in the form of chains and divergences. With the addition of bismuth, MnS inclusions of a larger size appear in the steel, and the inclusions distributed at grain boundaries are also reduced. When bismuth (0.010~0.020%) is added to the steel, MnS is mainly spherical and uniformly dispersed in the steel matrix. If the bismuth content is too high, the inclusions aggregate. Through in situ observations of the inclusions in the sample, it was found that the addition of bismuth in the heating process delays the appearance of ferrite grain boundaries and contributes to the spheroidization of MnS inclusions. Mn and S elements can fully diffuse slowly in the matrix with a heating rate below 1 °C/s and a long holding time (300 s), which provides the possibility for the spheroidization of MnS inclusions. [ABSTRACT FROM AUTHOR]

Copyright of Scientia Agropecuaria is the property of Scientia Agropecuaria and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

With the rapid development of the electric vehicle industry, the widespread utilization of lithium-ion batteries has made it imperative to address their safety issues. This paper focuses on the thermal safety concerns associated with lithium-ion batteries during usage by specifically investigating high-capacity lithium iron phosphate batteries. To this end, thermal runaway (TR) experiments were conducted to investigate the temperature characteristics on the battery surface during TR, as well as the changes in battery mass and expansion rate before and after TR. Meanwhile, by constructing a TR simulation model tailored to lithium iron phosphate batteries, an analysis was performed to explore the variations in internal material content, the proportion of heat generation from each exothermic reaction, and the influence of the heat transfer coefficient during the TR process. The results indicate that as the heating power increases, the response time of lithium-ion batteries to TR advances. Furthermore, the heat released from the negative electrode–electrolyte reaction emerges as the primary heat source throughout the entire TR process, contributing to 63.1% of the total heat generation. [ABSTRACT FROM AUTHOR]

The authors determined the morphological composition of refuse derived fuel (RDF) produced in Latvia and Lithuania by manually sorting. The parameters of RDF (moisture, net calorific value, ash content, carbon, nitrogen, hydrogen, sulphur, chlorine, metals) was determined using the EN standards. Comparing obtained results with data from literature, authors have found that the content of plastic is higher but paper and cardboard is lower than typical values. Results also show that the mean parameters for RDF can be classified with the class codes: Net heating value (3); chlorine (3); mercury (1), and responds to limits stated for 3rd class of solid recovered fuel. It is recommended to separate biological waste at source to lower moisture and ash content and increase heating value for potential fuel production from waste. [ABSTRACT FROM AUTHOR]

Mangrove forests are ecosystems susceptible to changing water levels and temperatures due to climate change as well as perturbations resulting from tropical storms. Numerical models can be used to project mangrove forest responses to regional and global environmental changes, and the reliability of these models depends on surface energy balance closure. However, for tidal ecosystems, the surface energy balance is complex because the energy transport associated with tidal activity remains poorly understood. This study aimed to quantify impacts of tidal flows on energy dynamics within a mangrove ecosystem. To address the research objective, an intensive study was conducted in a mangrove forest located along the Shark River in the Everglades National Park, FL. Forest-atmosphere energy exchanges were quantified with an eddy covariance system deployed on a flux tower. The lateral energy transport associated with tidal activity was calculated based on a coupled mass and energy balance approach. The mass balance included tidal flows and accumulation of water on the forest floor. The energy balance included temporal changes in enthalpy, resulting from tidal flows and temperature changes in the water column. By serving as a net sink or a source of available energy, tidal flows reduced the impact of high radiational loads on the mangrove forest. Including tidal energy advection in the surface energy balance improved the 30-min daytime energy closure from 73% to 82% over the study period. Also, the cumulative sum of energy output improved from 79% to 91% of energy input during the study period. Results indicated that tidal inundation provides an important mechanism for heat removal and that tidal exchange should be considered in surface energy budgets of coastal ecosystems. Results also demonstrated the importance of including tidal energy advection in mangrove biophysical models that are used for predicting ecosystem response to changing climate and regional freshwater management practices. [ABSTRACT FROM AUTHOR]

Momentum work enables a complete shift from kinematics to dynamics. This involves changes in the very fundamentals of physics, not only in mechanics, statistical mechanics, and special relativity, as shown in Papers I–III [G. Kalies and D. D. Do, AIP Adv. 13(6), 065121 (2023); G. Kalies, D. D. Do, and S. Arnrich, AIP Adv. 13(5), 055317 (2023); and G. Kalies and D. D. Do, AIP Adv. (in press) (2023)] of this series, but also in thermodynamics. In this paper, we challenge the narrative that classical phenomenological thermodynamics is completed and show that it represents an efficient interim solution that hides essential information. The essence of heat transfer and entropy is revealed, and an answer is given to the question of why entropy had to remain abstract and elusive in the past. Furthermore, we uncover the specific forms of energy behind thermodynamic state variables, such as enthalpy, Helmholtz free energy, and Gibbs free energy, which play a central role in describing chemical reactions and phase transitions. We thereby lay the foundation for thermodynamics to evolve from a framework theory valid for macroscopic systems to vivid quantum-process thermodynamics. [ABSTRACT FROM AUTHOR]

Condensers are often required in power generation systems to condense the exhaust steam generated at the end of the turbine. This paper will investigate the enhanced condensation process of spent steam in a parallel flow type. The operating parameters of steam temperature (Tcond), steam flow rate (Gin), cooling water temperature (Tin), and cooling water flow rate (Lw) will affect the condensation effect by changing the gas–liquid arrangement in the tower. In this experiment, an orthogonal test was designed in the Raschig ring to investigate the significance of these four operating parameters on the experimental results. Different types of packings have different condensation effects due to different accumulation methods. The same type of packing has a different surface area, resulting in different contact areas between the gas and liquid phases during condensation. In this experiment, four different packings will be investigated to find their condensation performance. This paper uses the size of subcooling (ΔT) as an indicator to evaluate the effectiveness of condensation, and the values of condensation rate (R), number of liquid phase heat transfer units (NTUL), and total volume heat transfer coefficient (Kv) are used as a reference for the effectiveness of condensation. The results show that the overall condensation effect of regular packing is better than that of random packing, The average condensation rate of regular packing is 95%, the average condensation rate of random packing is 90%, the subcooling of regular packing is about three to five smaller than that of random packing, the heat transfer coefficient of regular packing is about 1.5 times of that of random packing. And by fitting the Kv data for different packings, an empirical formula was obtained that can be used to predict the Kv size of other packings. [ABSTRACT FROM AUTHOR]

The structure of metallic materials has a significant impact on their properties. One of the most popular methods to form the properties of metal alloys is heat treatment, which uses thermally activated transformations that take place in metals to achieve the required mechanical or physicochemical properties. The phase transformation in steel results from the fact that one state becomes less durable than the other due to a change in conditions, for example, temperature. Phase transformations are an extensive field of research that is developing very dynamically both in the sphere of experimental and model research. The objective of this paper is the development of a 3D heat flow model to model heat transfer during diffusional phase transformations in carbon steels. This model considers the two main factors that influence the transformation: the temperature and the enthalpy of transformation. The proposed model is based on the lattice Boltzmann method (LBM) and uses CUDA parallel computations. The developed heat flow model is directly related to the microstructure evolution model, which is based on frontal cellular automata (FCA). This paper briefly presents information on the FCA, LBM, CUDA, and diffusional phase transformation in carbon steels. The structures of the 3D model of heat flow and their connection with the microstructure evolution model as well as the algorithm for simulation of heat transfer with consideration of the enthalpy of transformation are shown. Examples of simulation results of the growth of the new phase that are determined by the overheating/overcooling and different model parameters in the selected planes of the 3D calculation domain are also presented. [ABSTRACT FROM AUTHOR]

The paper is focused on the uncertainty estimation of the mean isobaric and isochoric specific heat capacity calculation. The differences in the data among the individual sources for the technical calculation are presented in the first part of the paper. These differences are discussed in this paper. Research of scientific work with listed values of measurement uncertainties has been carried out in the second part of the paper. Furthermore, mathematical models were calculated which describe the dependence of the specific heat capacities and temperature. The maximal error models were carried out. Two approaches were used for the calculation of the mean specific heat capacity. The first approach is the calculation with help of integration of the function which describes the dependence of the specific heat capacity and temperature. The second approach is the calculation of a simple arithmetic mean of the specific heat capacity related to the maximal and minimal value of the temperature interval. The conclusion of the work shows that the time-effective second way is applicable in the case of a narrow temperature range. A value of 5.5% (?t = 200 K) was reached for the relative uncertainty. This is a similar value to that in the case of using the first way. [ABSTRACT FROM AUTHOR]