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The characteristics of dissolved organic matter (DOM) serve as indicators of nitrate pollution in groundwater. However, the specific DOM components associated with nitrate in groundwater systems remain unclear. In this study, dual isotopes of nitrate, three-dimensional Excitation emission matrices (EEMs) and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) were utilized to uncover the sources of nitrate and their associations with DOM characteristics. The predominant nitrate in the targeted aquifer was derived from soil organic nitrogen (mean 46.0%) and manure &sewage (mean 34.3%). The DOM in nitrate-contaminated groundwater (nitrate-nitrogen >20 mg/L) exhibited evident exogenous characteristics, with a bioavailable content 2.58 times greater than that of uncontaminated groundwater. Regarding the molecular characteristics, DOM molecules characterized by CHO + 3N, featuring lower molecular weights and H/C ratios, indicated potential for mineralization, while CHONS formulas indicated the exogenous features, providing the potential for accurate traceability. These findings provided insights at the molecular level into the characterization of DOM in nitrate-contaminated groundwater and offer scientific guidance for decision-making regarding the remediation of groundwater nitrate pollution., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests that could have appeared to influence the work reported in this manuscript., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The widespread presence of entrapped dense non-aqueous phase liquid (DNAPL) in the subsurface poses a continuing challenge to groundwater remediation. Cost-effective and high-resolution subsurface characterization is a critical issue for further DNAPL recovery due to the complexity of DNAPL source zone architecture (SZA). Geophysical techniques provide a noninvasive, spatially continuous and cost-effective way for monitoring the DNAPL remediation process. In particular, the spectral induced polarization (SIP) method has shown great potential in environmental problems. In this study, we performed real-time SIP measurements on DNAPL contaminated soil in columns to quantitatively assess the ability of SIP method for monitoring surfactant-enhanced DNAPL remediation process. Chemical data was simultaneously collected during the remediation process to verify the results obtained by SIP method. Taking account into the variations of subsurface environment, we conducted a series of column flushing experiments under different flow rate, surfactant concentrations and fluid salinities. The results highlight that SIP method is able to effectively monitor the DNAPL remediation process, as well as to evaluate the remediation efficiency under different conditions. The variations in the flow rate, the concentration of surfactant and the salinity of pore water not only affect remediation effectiveness, but also have an impact on the SIP signatures. This study shows that SIP performs better for monitoring DNAPL remediation at a relatively low flow rate of ~ 0.4 m/d, low surfactant concentration of 5000 mg/L and high salinity of 1.0 S/m, with an error of saturation estimation (RMSE S ) <0.1., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Precise delineation of contaminant plume distribution is essential for effective remediation of contaminated sites. Traditional in situ investigation methods like direct-push (DP) sampling are accurate, but are usually intrusive and costly. Electrical resistivity tomography (ERT) method, as a non-invasive geophysical technique to map spatiotemporal changes in resistivity of the subsurface, is becoming increasingly popular in environmental science. However, the resolution of ERT for delineation of contaminant plumes still remains controversial. In this study, ERT and DP technique were both conducted at a real inorganic contaminated site. The reliability of the ERT method was validated by the direct comparisons of their investigation results that the resistivity acquired by ERT method is in accordance with the total dissolved solid concentration in groundwater and the overall variation of the total iron content in soil obtained by DP technique. After testifying the applicability of ERT method for contaminant identification, the extension of contaminant plume at the study site was revealed by supplementary ERT surveys conducted subsequently in the surrounding area of the contaminant source zone.

In this work, column experiments were conducted to investigate the transport characteristics of graphene oxide (GO) nanoparticles in limestone media under various electrolytes, solution pH, and humic acid (HA) concentration conditions. In the limestone media, GO exhibited relatively low mobility with the mass recovery rate lower than 65.2%, even when solution ionic strength was low. The presence of HA enhanced its mobility. In addition, the presence of S 2- , a divalent anion, also promoted GO transport in limestone media compared to Cl − under similar ionic strength conditions through neutralizing more positive charge and thus diminishing the cation bridging. Solution pH showed slight effect on the transport of GO in limestone with the mass recovery range from 40.3% to 51.7%. Over all, decreases in solution pH, HA concentration and increases in solution ionic strength reduced the mobility of GO in the limestone media under the tested conditions. These results indicated both environmental conditions and media characteristics played important roles in controlling GO fate and transport in porous media. The one-site kinetic deposition model was applied to describe the interactions between the GO and limestone media and model simulations fitted the observed experimental data very well. As limestone is an important component of aquiferous media in subsurface, findings from this study elucidated the key factors and processes controlling the fate of GO particles in limestone media, which can inform the prediction and assessment of the risks of GO in groundwater environment. [ABSTRACT FROM AUTHOR]

Abstract: Suzhou is located at the lower reaches of the Yangtze River in southeastern Jiangsu, China. It is part of the Su-Xi-Chang area including Suzhou, Wuxi and Changzhou. As one of the most developed areas in China, this region has suffered from severe land subsidence caused by extensive groundwater exploitation since 1980s. The land subsidence was controlled by prohibition of groundwater exploration in the past several years. However, the surface water pollution prompted a new task of how to sustainably utilize the groundwater resource, especially to satisfy the emergency demands of water supply. In this paper, we took Suzhou as a representative case to discuss how to develop groundwater resources while controlling the land subsidence. The relationship between the deformation and the groundwater level was analyzed, with focus on the deformation features after the period of groundwater exploitation ban. The results confirmed the conclusion by Shi et al. (2007, 2008a): even in the period of rising groundwater level, same units may manifest different deformation characteristics, such as elasticity, elasto-plasticity, and visco-elasto-plasticity, at different locations of the cone of depression. A land subsidence model that couples a 3-D groundwater model and a 1-D deformation model was developed to simulate the groundwater level and deformation. A high-resolution local grid (child model) for Suzhou was built based on the regional land subsidence model of Su-Xi-Chang area by Wu et al. (2009). The model was used for a number of predictive scenarios up to the year of 2012 to examine how to develop sustainable use of groundwater resources under the conditions of land subsidence control. Our results indicated that about 3.08×107 m3/a groundwater could be provided as emergency and standby water source while meeting the land subsidence control target of 10mm/a. [Copyright &y& Elsevier]