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Abstract Nowadays nickel-rich LiNi x Co y Mn 1-x-y O 2 (0.5 < x < 1) cathode materials attract great research interests due to their high specific capacity in lithium ion batteries. However, poor cycling performance and serious safety concerns trade off their benefits. Here, we present an effective etching-induced coating strategy for surface modification of LiNi 0.8 Co 0.1 Mn 0.1 O 2 cathode materials by LiAlO 2. Hydrolysis of AlCl 3 creates H+ to etch the hydroxide precursor of LiNi 0.8 Co 0.1 Mn 0.1 O 2 and to induce oriented deposition of Al(OH) 3 layer on surface of the hydroxide precursor, which is transformed into uniform γ-LiAlO 2 coating on the LiNi 0.8 Co 0.1 Mn 0.1 O 2 particles after the subsequent lithium impregnating and annealing. The 2.2 wt% LiAlO 2 -coated LiNi 0.8 Co 0.1 Mn 0.1 O 2 cathode delivers a high rate capacity of 135.2 mAh g−1 at 10 C and long cyclability with capacity retention of 85.8% after 200 cycles at 0.5 C. In addition, the thermal stability of LiAlO 2 -coated LiNi 0.8 Co 0.1 Mn 0.1 O 2 is significantly improved. The enhanced battery performances are due to partial Al3+ doping and Li+ conductive LiAlO 2 coating layer that provides well-connected networks for Li+ transport, improves the structural stability and prevents core materials from the attack by side products. Graphical abstract The detailed etching-induced coating strategy for the synthesis of LiAlO 2 -coated NCM811 materials. Image 1 Highlights • The etching-induced coating strategy was designed to prepare LiAlO 2 -coated NCM811. • The modified NCM811 exhibits better rate and cycle performance. • The modified NCM811 displays smaller overpotential especially at high rate. • The coating of LiAlO 2 significantly improves the thermal stability of NCM811. [ABSTRACT FROM AUTHOR]

The synthesis of one-dimensional (1D) Zn-Mn-Oxide (ZMO) for lithium storage is an important research topic, since ZMO can potentially satisfy the ever-increasing demand on the high energy density, natural abundance and long lifespan of lithium ion batteries. Generally, the synthesis of 1D ZMO nanostructures relies on various templates. A facile construction of 1D ZMO nanostructures with tunable compositions via the same synthetic protocol remains a great challenge. Herein, two different Zn-Mn-Oxides of ZnMn 2 O 4 and ZnMnO 3 both with 1D rod morphology were successfully prepared via a simple co-precipitation reaction coupled with subsequent heat treatment. As the anode materials for lithium ion battery, both ZMO nanorods exhibit good lithium storage performances. Especially, ZnMn 2 O 4 nanorods display superior electrochemical performances to ZnMnO 3 nanorods, including higher discharge capacities of 1119.3 and 572.6 mAh g −1 at 0.1 C and 0.5 C, respectively and better cyclability with capacity retention of 80% after 300 cycles at 0.5 C. The improved electrochemical properties should be attributed to the porous and interparticle-bridging microstructures in ZnMn 2 O 4 nanorods, which can offer better contact between electrolyte and anode and tolerate larger volume changes during discharge/charge process. [ABSTRACT FROM AUTHOR]