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A two-dimensional study of mass transfer from a circular composite particle settling in a vertical channel is conducted with the lattice Boltzmann method. The particle is composed of two materials, one insoluble while the other soluble in the ambient fluid. In the problem, mass transfer, particle motion and fluid flow are closely coupled, where the concentration at the particle surface and particle properties vary with mass transfer. It is observed that mass transfer follows a Schmidt number independent scaling law of [ t / ( t ν Sc ) ] - 1.5 ( t is the physical time, t ν is the momentum diffusion time scale and Sc is the Schmidt number), which is quite different from the pure diffusion of a stationary particle, ∼ ( t / t α ) - 0.5 ( t α is the mass diffusion time scale). An analysis of the concentration and flow pattern around the particle suggests that the scaling law for a settling particle is related to both diffusion distance and convection distance, while it is only relevant to the diffusion distance in the case of a stationary particle. For a settling particle, mass transfer is enhanced by two mechanisms due to convection, i.e., the concentration around the particle surface transported to the downstream of the particle by the fluid flow and the interface of mass transfer stretched with the particle motion, which are absent in the case of a stationary particle. Thus, the rate of mass transfer in the case of a settling particle is much higher than that for a stationary particle. [ABSTRACT FROM AUTHOR]