1. Semiconductor-based photocatalysts for photocatalytic and photoelectrochemical water splitting: will we stop with photocorrosion?
- Author
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Min Cheng, Piao Xu, Lei Lei, Xigui Liu, Wenjing Xue, Rui Deng, Danlian Huang, Rongzhong Wang, and Sha Chen
- Subjects
Materials science ,Renewable Energy, Sustainability and the Environment ,business.industry ,Doping ,Energy conversion efficiency ,Heteroatom ,Nanotechnology ,Heterojunction ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Semiconductor ,Photocatalysis ,Water splitting ,Energy transformation ,General Materials Science ,0210 nano-technology ,business - Abstract
The status of photocatalytic (PC)/photoelectrochemical (PEC) water splitting as a promising approach to solar-to-chemical energy conversion has increased significantly over the past several decades for addressing the energy shortage. However, the overall energy conversion efficiency is still relatively poor due to the severe photocorrosion in photosensitive semiconductors. Herein, the review begins with the discussion of the photocorrosion mechanism with several typical semiconductors as examples. Then the feasible characterization methods used to evaluate the stability of semiconductors are summarized. Notably, most studies regarding water splitting focus on achieving high efficiency by improving the charge separation and transfer efficiency within the semiconductors. This review focuses on the recent advances in effective strategies for photocorrosion inhibition of semiconductor-based composites with respect to their intrinsic properties and interface charge transfer kinetics, including morphology/size control, heteroatom doping, heterojunction construction, surface modification, and reaction environment regulation. Furthermore, an in-depth investigation of photocorrosion pathways and mechanisms is critical to accurately and effectively address the photocorrosion of semiconductor-based composites to improve PC/PEC water splitting performance in the future.
- Published
- 2020