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The understanding of clustering aspects at the ground state of nuclei and in fast rotating ones within the framework of covariant density functional theory has been reviewed and reanalyzed. The appearance of many exotic nuclear shapes in nuclear chart can be inferred from combined analysis of nodal structure of the densities of the single-particle states and the evolution of such states in the Nilsson diagram with deformation and particle number. Such analysis which is supported by fully self-consistent calculations allows to predict the existence of nuclear configurations with specific shape or cluster properties at ground state and at high spin. For example, it indicates that in a given shell with principal quantum number N only the lowest in energy two-fold degenerate deformed state can contribute to the formation of linear chain α cluster structures. [ABSTRACT FROM AUTHOR]

The transition from cluster structures to extremely elongated ellipsoidal shapes and nuclear molecules in light A=12-50 (N~Z) nuclei has been studied within the framework of covariant density functional theory. Nodal structure of the occupied single-particle states plays a critical role in microscopic understanding of this transition. This is illustrated by the analysis of dominant types of single-particle density distributions and their evolution (from the bottom of nucleonic potential) with deformation and particle number. The microscopic mechanism of the transition from clustered structures to ellipsoidal shapes and nuclear molecules and between them is discussed. [ABSTRACT FROM AUTHOR]