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1. Cross-Metathesis of Brønsted Acid Masked Alkenylamines with Acrylates for the Synthesis of Polyamide Monomers

Author

William Roy Jackson, Szabolcs Solyom, Clint Peter Woodward, Nicolas Daniel Spiccia, and Andrea J. Robinson

Subjects
010405 organic chemistry, Organic Chemistry, 010402 general chemistry, Metathesis, 01 natural sciences, 0104 chemical sciences, Catalysis, chemistry.chemical_compound, Monomer, chemistry, Polyamide, Polymer chemistry, Organic chemistry, Brønsted–Lowry acid–base theory
Abstract

Ruthenium-alkylidene-catalyzed cross-metathesis of a range of homologous alkenylamine salts provides expedient and high-yielding routes to commercially valuable polyamide monomers using a single catalyst, telescopic workup, and mild experimental conditions.

Published
2016
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