14 results on '"David Wachs"'
Search Results
2. All-XUV Pump-Probe Transient Absorption Spectroscopy of the Structural Molecular Dynamics of Di-iodomethane
- Author
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Marc Rebholz, Thomas Ding, Victor Despré, Lennart Aufleger, Maximilian Hartmann, Kristina Meyer, Veit Stooß, Alexander Magunia, David Wachs, Paul Birk, Yonghao Mi, Gergana Dimitrova Borisova, Carina da Costa Castanheira, Patrick Rupprecht, Georg Schmid, Kirsten Schnorr, Claus Dieter Schröter, Robert Moshammer, Zhi-Heng Loh, Andrew R. Attar, Stephen R. Leone, Thomas Gaumnitz, Hans Jakob Wörner, Sebastian Roling, Marco Butz, Helmut Zacharias, Stefan Düsterer, Rolf Treusch, Günter Brenner, Jonas Vester, Alexander I. Kuleff, Christian Ott, and Thomas Pfeifer
- Subjects
Physics ,QC1-999 - Abstract
In this work, we use an extreme-ultraviolet (XUV) free-electron laser (FEL) to resonantly excite the I: 4d_{5/2}–σ^{*} transition of a gas-phase di-iodomethane (CH_{2}I_{2}) target. This site-specific excitation generates a 4d core hole located at an iodine site, which leaves the molecule in a well-defined excited state. We subsequently measure the time-dependent absorption change of the molecule with the FEL probe spectrum centered on the same I: 4d resonance. Using ab initio calculations of absorption spectra of a transient isomerization pathway observed in earlier studies, our time-resolved measurements allow us to assign the timescales of the previously reported direct and indirect dissociation pathways. The presented method is thus sensitive to excited-state molecular geometries in a time-resolved manner, following a core-resonant site-specific trigger.
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- 2021
- Full Text
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3. XUV-Initiated Dissociation Dynamics of Molecular Oxygen (O2)
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Kristina Meyer, Thomas Ding, Stefan Düsterer, Lennart Aufleger, Rolf Treusch, Veit Stooß, Paul Birk, Carina da Costa Castanheira, Helmut Zacharias, David Wachs, Alexander Magunia, S. Roling, Yonghao Mi, Gergana Dimitrova Borisova, Patrick Rupprecht, Marco Butz, Marc Rebholz, Uwe Thumm, Günter Brenner, Maia Magrakvelidze, Christian D. Ott, Maximilian Hartmann, and Thomas Pfeifer
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Chemistry ,Ionic bonding ,chemistry.chemical_element ,Photon energy ,Laser ,Oxygen ,Dissociation (chemistry) ,Article ,law.invention ,law ,Atomic electron transition ,Molecule ,ddc:530 ,Physical and Theoretical Chemistry ,Atomic physics ,Spectroscopy - Abstract
The journal of physical chemistry / A 125, 10138���10143 (2021). doi:10.1021/acs.jpca.1c06033, We performed a time-resolved spectroscopy experixment on the dissociation of oxygen molecules after the interactionwith intense extreme-ultraviolet (XUV) light from the free-electronlaser in Hamburg at Deutsches Elektronen-Synchrotron. Using anXUV-pump/XUV-probe transient-absorption geometry with asplit-and-delay unit, we observe the onset of electronic transitionsin the O$^{2+}$ cation near 50 eV photon energy, marking the end ofthe progression from a molecule to two isolated atoms. We observetwo different time scales of 290 �� 53 and 180 �� 76 fs for theemergence of different ionic transitions, indicating differentdissociation pathways taken by the departing oxygen atoms.With regard to the emerging opportunities of tuning the centralfrequencies of pump and probe pulses and of increasing the probe���pulse bandwidth, future pump���probe transient-absorptionexperiments are expected to provide a detailed view of the coupled nuclear and electronic dynamics during molecular dissociation, Published by Soc., Washington, DC
- Published
- 2021
4. Measuring the frequency chirp of extreme-ultraviolet free-electron laser pulses by transient absorption spectroscopy
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Lennart Aufleger, Rolf Treusch, Maximilian Hartmann, Thomas Pfeifer, Marco Butz, Veit Stooß, David Wachs, Paul Birk, Helmut Zacharias, Carina da Costa Castanheira, Thomas Ding, Zhi-Heng Loh, Marc Rebholz, Stefan Düsterer, Gergana Dimitrova Borisova, Yonghao Mi, Arvid Eislage, Alexander Magunia, Patrick Rupprecht, S. Roling, Andrew R. Attar, Christian D. Ott, Stefano M. Cavaletto, and Thomas Gaumnitz
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Research group Z. Harman – Division C. H. Keitel ,Science ,Optical spectroscopy ,General Physics and Astronomy ,Physics::Optics ,02 engineering and technology ,01 natural sciences ,Article ,General Biochemistry, Genetics and Molecular Biology ,law.invention ,Optics ,law ,Free-electron lasers ,X-rays ,0103 physical sciences ,Ultrafast laser spectroscopy ,Chirp ,010306 general physics ,Spectroscopy ,Physics ,Multidisciplinary ,business.industry ,Free-electron laser ,Nonlinear optics ,General Chemistry ,021001 nanoscience & nanotechnology ,Laser ,Extreme ultraviolet ,Physics::Accelerator Physics ,ddc:500 ,0210 nano-technology ,business ,Ultrashort pulse - Abstract
Nature Communications 12(1), 643 (1-7) (2021). doi:10.1038/s41467-020-20846-1, High-intensity ultrashort pulses at extreme ultraviolet (XUV) and x-ray photon energies, delivered by state-of-the-art free-electron lasers (FELs), are revolutionizing the field of ultrafast spectroscopy. For crossing the next frontiers of research, precise, reliable and practical photonic tools for the spectro-temporal characterization of the pulses are becoming steadily more important. Here, we experimentally demonstrate a technique for the direct measurement of the frequency chirp of extreme-ultraviolet free-electron laser pulses based on fundamental nonlinear optics. It is implemented in XUV-only pump-probe transient-absorption geometry and provides in-situ information on the time-energy structure of FEL pulses. Using a rate-equation model for the time-dependent absorbance changes of anionized neon target, we show how the frequency chirp can be directly extracted and quantified from measured data. Since the method does not rely on an additional external field, we expect a widespread implementation at FELs benefiting multiple science fields by in-situ on-target measurement and optimization of FEL-pulse properties., Published by Nature Publishing Group UK, [London]
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- 2021
5. A Potential Complication of COVID-19: A Case of Non-Traumatic Rhabdomyolisis
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David Wachs, Carrie Morgenstein, and Aakash Sathappan
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medicine.medical_specialty ,Coronavirus disease 2019 (COVID-19) ,biology ,business.industry ,SARS-CoV-2 ,Acute kidney injury ,COVID-19 ,Case Report ,medicine.disease ,medicine.disease_cause ,Rhabdomyolysis ,Coronavirus ,Pneumonia ,Acute renal failure ,medicine ,biology.protein ,Etiology ,Creatine kinase ,Intensive care medicine ,business ,Complication - Abstract
Rhabdomyolysis can present as a clinical challenge due to broad etiological spectrum, non-specific symptomatology and numerous systemic complications including acute kidney injury. Emerging evidence suggests that rhabdomyolysis may be an associated early or late complication of coronavirus disease 2019 (COVID-19) infection. We present a case of a 55-year-old woman with recent COVID-19 pneumonia who was later found to have non-traumatic rhabdomyolysis incidentally captured on COVID-19 screening labs.
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- 2020
6. Paleoclimate reconstruction for the past millennium from groundwater using 39Ar dating and noble gas temperatures
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Yannis Arck, Julian Robertz, Lisa Ringena, Markus K. Oberthaler, Werner Aeschbach, Florian Freundt, David Wachs, Maximilian Schmidt, and Timo Metz
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Earth science ,Paleoclimatology ,Noble gas (data page) ,Geology ,Groundwater - Published
- 2021
7. All-XUV Pump-Probe Transient Absorption Spectroscopy of the Structural Molecular Dynamics of Di-iodomethane
- Author
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Thomas Pfeifer, Stephen R. Leone, Gergana Dimitrova Borisova, Christian D. Ott, V. Despré, Thomas Ding, Jonas Vester, Alexander I. Kuleff, Thomas Gaumnitz, Alexander Magunia, Hans Jakob Wörner, Andrew R. Attar, Kristina Meyer, Stefan Düsterer, Georg H. Schmid, Marco Butz, Kirsten Schnorr, Maximilian Hartmann, Claus Dieter Schröter, Günter Brenner, Yonghao Mi, Veit Stooß, Helmut Zacharias, Paul Birk, Lennart Aufleger, Carina da Costa Castanheira, Patrick Rupprecht, Rolf Treusch, Zhi-Heng Loh, Marc Rebholz, Robert Moshammer, David Wachs, S. Roling, and School of Physical and Mathematical Sciences
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Physics ,Quantum Physics ,Absorption spectroscopy ,Molecular Physics ,QC1-999 ,General Physics and Astronomy ,Resonance ,Condensed Matter Physics ,Dissociation (chemistry) ,Molecular geometry ,Ab initio quantum chemistry methods ,Excited state ,Chemistry [Science] ,Atomic Physics ,Ultrafast laser spectroscopy ,ddc:530 ,Atomic physics ,Spectroscopy ,Astronomical and Space Sciences - Abstract
Physical review / X 11(3), 031001 (1-9) (2021). doi:10.1103/PhysRevX.11.031001, In this work, we use an extreme-ultraviolet (XUV) free-electron laser (FEL) to resonantly excite the I: 4$d_{5/2}–σ^∗$ transition of a gas-phase di-iodomethane (CH$_2$I$_2$) target. This site-specific excitation generates a 4$d$ core hole located at an iodine site, which leaves the molecule in a well-defined excited state. We subsequently measure the time-dependent absorption change of the molecule with the FEL probe spectrum centered on the same I: 4$_d$ resonance. Using ab initio calculations of absorption spectra of a transient isomerization pathway observed in earlier studies, our time-resolved measurements allow us to assign the timescales of the previously reported direct and indirect dissociation pathways. The presented method is thus sensitive to excited-state molecular geometries in a time-resolved manner, following a core-resonant site-specific trigger., Published by APS, College Park, Md.
- Published
- 2021
8. Sampling and purification methods for dating by Atom Trap Trace Analysis in various environments
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Markus K. Oberthaler, Yannis Arck, Julian Robertz, David Wachs, Lisa Ringena, Werner Aeschbach, and Maximilian Schmidt
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Trap (computing) ,Materials science ,Atom (order theory) ,Sampling (statistics) ,Trace analysis ,Atomic physics ,Purification methods - Published
- 2021
9. Investigations on the stratification dynamics and the gas concentrations of Lake Kivu
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Julian Robertz, Markus K. Oberthaler, Fabian Bärenbold, David Wachs, Yannis Arck, Werner Aeschbach, Bertram Boehrer, Maximilian Schmidt, and Lisa Ringena
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Oceanography ,Environmental science ,Stratification (water) - Published
- 2021
10. Building CapaCITY/É for sustainable transportation: protocol for an implementation science research program in healthy cities
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Brent E Hagel, Alison Macpherson, Ben Beck, Ian Pike, Linda Rothman, Darshini Ayton, Marie-Soleil Cloutier, Kevin Manaugh, Meridith Sones, Daniel Fuller, Yan Kestens, Meghan Winters, Audrey R Giles, Helen Skouteris, Patrick Harris, Andrew Howard, M Anne Harris, Brice Batomen, Nazeem Muhajarine, Jennifer R Tomasone, Sarah Moore, Martine Shareck, David Whitehurst, Sara Kirk, Karen Laberee, Zoé Poirier Stephens, Scott Bell, Patricia Collins, Ehab Diab, Mike S Harris, Ugo Lachapelle, Raktim Mitra, Tiffany Muller Myrdahl, Christopher J Pettit, and David Wachsmuth
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Medicine - Abstract
Introduction Improving sustainable transportation options will help cities tackle growing challenges related to population health, congestion, climate change and inequity. Interventions supporting active transportation face many practical and political hurdles. Implementation science aims to understand how interventions or policies arise, how they can be translated to new contexts or scales and who benefits. Sustainable transportation interventions are complex, and existing implementation science frameworks may not be suitable. To apply and adapt implementation science for healthy cities, we have launched our mixed-methods research programme, CapaCITY/É. We aim to understand how, why and for whom sustainable transportation interventions are successful and when they are not.Methods and analysis Across nine Canadian municipalities and the State of Victoria (Australia), our research will focus on two types of sustainable transportation interventions: all ages and abilities bicycle networks and motor vehicle speed management interventions. We will (1) document the implementation process and outcomes of both types of sustainable transportation interventions; (2) examine equity, health and mobility impacts of these interventions; (3) advance implementation science by developing a novel sustainable transportation implementation science framework and (4) develop tools for scaling up and scaling out sustainable transportation interventions. Training activities will develop interdisciplinary scholars and practitioners able to work at the nexus of academia and sustainable cities.Ethics and dissemination This study received approval from the Simon Fraser University Office of Ethics Research (H22-03469). A Knowledge Mobilization Hub will coordinate dissemination of findings via a website; presentations to academic, community organisations and practitioner audiences; and through peer-reviewed articles.
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- 2024
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11. Strong-field extreme-ultraviolet dressing of atomic double excitation
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P. Lambropoulos, Thomas Pfeifer, Alexander Magunia, David Wachs, Thomas Ding, Veit Stooß, Gergana Dimitrova Borisova, Robert Moshammer, Lennart Aufleger, Marc Rebholz, Andrew R. Attar, Rolf Treusch, Stefan Düsterer, Maximilian Hartmann, Michael Meyer, Paul Birk, Carina da Costa Castanheira, Thomas Gaumnitz, Christian D. Ott, Kristina Meyer, Patrick Rupprecht, Joachim Ullrich, Zhi-Heng Loh, Yuhai Jiang, and School of Physical and Mathematical Sciences
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Physics ,Autoionization & Auger proesses ,Atomic Physics (physics.atom-ph) ,FOS: Physical sciences ,General Physics and Astronomy ,Resonance ,Stark Effect ,Laser ,01 natural sciences ,law.invention ,Physics - Atomic Physics ,Dipole ,Atomic electron transition ,law ,Physics [Science] ,Electric field ,Extreme ultraviolet ,Excited state ,0103 physical sciences ,Physics::Atomic and Molecular Clusters ,ddc:530 ,Physics::Atomic Physics ,Atomic physics ,010306 general physics ,Excitation - Abstract
We report on the experimental observation of strong-field dressing of an autoionizing two-electron state in helium with intense extreme-ultraviolet laser pulses from a free-electron laser. The asymmetric Fano line shape of this transition is spectrally resolved, and we observe modifications of the resonance asymmetry structure for increasing free-electron-laser pulse energy on the order of few tens of $\mu$J. A quantum-mechanical calculation of the time-dependent dipole response of this autoionizing state, driven by classical extreme-ultraviolet (XUV) electric fields, reveals a direct link between strong-field-induced energy and phase shifts of the doubly excited state and the Fano line-shape asymmetry. The experimental results obtained at the Free-Electron Laser in Hamburg (FLASH) thus correspond to transient energy shifts on the order of few meV, induced by strong XUV fields. These results open up a new way of performing non-perturbative XUV nonlinear optics for the light-matter interaction of resonant electronic transitions in atoms at short wavelengths., Comment: 16 pages, 3 figures
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- 2019
12. Nonlinear coherence effects in transient-absorption ion spectroscopy with stochastic extreme-ultraviolet free-electron laser pulses
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Maximilian Hartmann, Marco Butz, Alexander Magunia, Thomas Pfeifer, Zhi-Heng Loh, Patrick Rupprecht, Marc Rebholz, Andrew R. Attar, Paul Birk, David Wachs, Carina da Costa Castanheira, Stefano M. Cavaletto, Stefan Düsterer, Kristina Meyer, Veit Stooß, Helmut Zacharias, Thomas Gaumnitz, Yonghao Mi, S. Roling, Lennart Aufleger, Rolf Treusch, Christian D. Ott, Gergana Dimitrova Borisova, Thomas Ding, and School of Physical and Mathematical Sciences
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Absorption spectroscopy ,Atomic Physics (physics.atom-ph) ,Research group Z. Harman – Division C. H. Keitel ,FOS: Physical sciences ,General Physics and Astronomy ,chemistry.chemical_element ,01 natural sciences ,Physics - Atomic Physics ,law.invention ,Ion ,Neon ,symbols.namesake ,law ,0103 physical sciences ,Ultrafast laser spectroscopy ,Chemistry [Science] ,ddc:530 ,Strong Electromagnetic Field Effects ,010306 general physics ,Spectroscopy ,Ultrafast Phenomena ,Physics ,Quantum Physics ,Resonance ,Laser ,chemistry ,Stark effect ,symbols ,Atomic physics ,Quantum Physics (quant-ph) - Abstract
Physical review letters 123(10), 103001 (2019). doi:10.1103/PhysRevLett.123.103001, We demonstrate time-resolved nonlinear extreme-ultraviolet absorption spectroscopy on multiply charged ions, here applied to the doubly charged neon ion, driven by a phase-locked sequence of two intense free-electron laser pulses. Absorption signatures of resonance lines due to $2p-3d$ bound–bound transitions between the spin-orbit multiplets $^3P_{0,1,2}$ and $^3D_{1,2,3}$ of the transiently produced doubly charged Ne$^{2+}$ ion are revealed, with time-dependent spectral changes over a time-delay range of (2.4±0.3) fs. Furthermore, we observe 10-meV-scale spectral shifts of these resonances owing to the ac Stark effect. We use a time-dependent quantum model to explain the observations by an enhanced coupling of the ionic quantum states with the partially coherent free-electron laser radiation when the phase-locked pump and probe pulses precisely overlap in time., Published by APS, College Park, Md.
- Published
- 2019
13. Tilted platforms: rental housing technology and the rise of urban big data oligopolies
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Geoff Boeing, Max Besbris, David Wachsmuth, and Jake Wegmann
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Housing markets ,Platform urbanism ,Rental housing ,Short-term rentals ,Technology ,Aesthetics of cities. City planning and beautifying ,NA9000-9428 ,Cities. Urban geography ,GF125 - Abstract
Abstract This article interprets emerging scholarship on rental housing platforms—particularly the most well-known and used short- and long-term rental housing platforms—and considers how the technological processes connecting both short-term and long-term rentals to the platform economy are transforming cities. It discusses potential policy approaches to more equitably distribute benefits and mitigate harms. We argue that information technology is not value-neutral. While rental housing platforms may empower data analysts and certain market participants, the same cannot be said for all users or society at large. First, user-generated online data frequently reproduce the systematic biases found in traditional sources of housing information. Evidence is growing that the information broadcasting potential of rental housing platforms may increase rather than mitigate sociospatial inequality. Second, technology platforms curate and shape information according to their creators’ own financial and political interests. The question of which data—and people—are hidden or marginalized on these platforms is just as important as the question of which data are available. Finally, important differences in benefits and drawbacks exist between short-term and long-term rental housing platforms, but are underexplored in the literature: this article unpacks these differences and proposes policy recommendations. Policy and practice recommendations As rental housing technologies upend traditional market processes in favor of platform oligopolies, policymakers must reorient these processes toward the public good. Long-term and short-term rental platforms offer different market benefits and drawbacks, but the latter in particular requires proactive regulation to mitigate harm. At a minimum, policymakers must require that short-term rental platforms provide the information necessary for cities to enforce current, let alone new, housing regulations. Practitioners should be cautious inferring market conditions from rental housing platform data, due to difficult-to-measure sampling biases.
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- 2021
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14. Location, location and professionalization: a multilevel hedonic analysis of Airbnb listing prices and revenue
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Robbin Deboosere, Danielle Jane Kerrigan, David Wachsmuth, and Ahmed El-Geneidy
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housing ,land use ,planning ,real estate ,transport ,short-term rentals ,hedonic analysis ,Regional economics. Space in economics ,HT388 ,Regional planning ,HT390-395 - Abstract
Hedonic modelling techniques have frequently been used to examine real estate valuation, and they have recently started to be applied to short-term rental valuation. Relying on a web-scraped data set of all Airbnb transactions in New York City (NYC) between August 2014 and September 2016, this paper presents the first hedonic regression model of Airbnb to take into account neighbourhood effects and to predict both average price per night and revenue generated by each listing. The model demonstrates that locational factors – above all, transit accessibility to jobs – and neighbourhood variation have a large impact on both price per night and monthly revenue, and further reveals how professionalization of the short-term rental market is driving more revenue to a narrower segment of hosts. Further, the findings suggest that Airbnb hosts earn a significant premium by converting long-term housing in accessible residential neighbourhoods into de facto Airbnb hotels. This premium incentivizes landlords and hosts with properties in accessible neighbourhoods to replace long-term tenants with short-term guests, forcing those in search of housing to less accessible neighbourhoods.
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- 2019
- Full Text
- View/download PDF
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