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The electrochemical oxidation of ethanol on platinum, rhodium, and platinum-rhodium electrodes is studied using on-line differential electrochemical mass spectrometry (DEMS) and in-situ infrared spectroscopy (FTIR). The result shows that rhodium produces a strong decrease in the acetaldehyde yield, compared to pure platinum electrodes.

Abstract: To evaluate the effect of the alloy phase characteristics on the ethanol oxidation activity, carbon supported (PtSnPd)alloy/SnO2 catalysts were prepared and their electrocatalytic activity compared with that of carbon supported (PtSn)alloy/SnO2. Pt–Sn–Pd/C samples in the atomic ratio (1:1:0.3) and (1:1:1) were characterized by energy dispersive X-ray (EDX) analysis, X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). XRD analysis shows the presence of fcc Pt reflexions, shifted to lower angles, and SnO2 reflexions. By comparison with the XRD patterns of carbon supported Pt–Sn (1:1) and Pt–Pd (3:1) samples, prepared by the same method, the formation of ternary PtSnPd alloys is postulated. The crystallite size of the ternary catalysts is smaller than that of both binary Pt–Sn/C (1:1) and Pt–Pd/C (3:1) catalysts. Chronoamperometry experiments and tests in direct ethanol fuel cells of the as-prepared catalysts shows that the activity for ethanol oxidation of (PtSn)alloy/SnO2 is higher than that of (PtSnPd)alloy/SnO2. This result, obtained with the same Pt/SnO2 atomic ratio in all the samples, indicates the critical role of the alloy phase characteristics of these catalysts on their activity for ethanol oxidation. [Copyright &y& Elsevier]