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Estuaries are an important contributor to the global carbon budget, facilitating carbon removal, transfer and transformation between land and coastal ocean. Estuaries are also susceptible to global climate change and anthropogenic perturbations. We find that a long-term significant increase in dissolved inorganic carbon (DIC) of 6–21 µmol kg-1 yr-1 (1997–2020) in a temperate estuary in Germany (Elbe Estuary), was driven by an increase in upper estuary particulate organic carbon (POC) content of 8–14 µmol kg-1 yr-1. The temporal POC increase was due to an overall improvement in water quality observed in the form of high rates of primary production and a significant drop in biological oxygen demand. The magnitude of mid-estuary DIC gain was equivalent to the increased POC production in the upper estuary, suggesting that POC is efficiently remineralized and retained as DIC in the mid-estuary, with the estuary acting as an efficient natural filter for POC. In the context of the significant DIC increase, the impact of a recent extensive drought period (2014–2020) significantly lowered the annual mean river discharge (468 ± 234 m3 s-1) compared to the long-term mean (690 ± 441 m3 s-1, 1960–2020). During the drought period, the late spring internal DIC load in the estuary doubled. This suggests that the drought induced a longer dry season, starting in May (earlier than normal), increased the residence time in the estuary and allowed for a longer remineralization period for POC. Annually, 77–94 % of the total DIC export was laterally transported to coastal water, reaching 89 ± 4.8 Gmol C yr-1, and thus only a maximum of 23 %, at 10 Gmol C yr-1, was released via carbon dioxide (CO2) evasion, between 1997 and 2020. Export of DIC to coastal waters decreased significantly during the drought (2014–2020: 38 ± 5.4 Gmol C yr-1), on average by 24 % compared to the non-drought period. In addition, we have identified that seasonal changes in DIC processing in an estuary require consideration in order to understand both the long-term and future changes in air-water CO2 flux, DIC export to coastal waters, as well as the impacts of prolonged droughts on the land-ocean carbonate system.

Over the last few decades many quantitative erosion studies have revealed that olive orchard expansion and increased mechanization in southern European countries have led to increased soil erosion under olive trees. Consequently, these studies have suggested different methods of mitigation. In light of the 2014 European trading zone expansion to countries east and south of the Mediterranean, a further intensification of olive plantations is postulated to meet market demands. To attain first medium-term estimates of erosion in Northern Jordan and its driving factors, a new method measuring olive mounds was implemented. Seven fields with clearly erosive structures were chosen throughout the Wadi Al-Arab catchment in Northern Jordan. Topographic measurements were used to reconstruct the historical and recent surface level and calculate the volume eroded since the planting of the trees. A total of 81 bulk density measurements and 14 tree cores allowed the estimation of the soil loss in tons per hectare. The combination of modified land use map and slope information helped to identify similar olive fields with high erosive potential. Results show that the method provides medium-term quantitative estimates for averaged soil loss consistent with some existing results from similar research areas in the Mediterranean. They clearly indicate the significant potential for erosion in olive orchards with around 95 ± 8 t ha − 1 yr − 1 . Tillage practice and water erosion were identified as critical erosion processes, both depending on tillage characteristics, tillage timing, and soil parent material. The investigated fields represent about 19% of the catchment's surface area and are likely to contribute to the measured yearly sediment yield that fills up the Wadi Al-Arab reservoir with sediments.

Riverine dissolved organic carbon (DOC) supports the production of estuaries and coastal ecosystems, constituting one of the most actively recycled pools of the global carbon cycle. A substantial proportion of DOC entering oceans is highly aged, but its origins remain unclear. Significant fluxes of old DOC have never been observed in temperate headwaters where terrestrial imports take place. Here, we studied the radiocarbon age of DOC in three streams draining forested headwater catchments of the river Mulde (Ore Mountains, Germany). In a 4 week summer precipitation event DOC aged at between 160 and 270 years was delivered into the watershed. In one stream, the DOC was modern but depleted in radiocarbon compared to other hydrological conditions. The yield was substantial and corresponded to 20–52 % of the annual DOC yields in wet and dry years, respectively. The analysis of long-term data suggested that the DOC export in extreme precipitation events added to the annual yield and was not compensated for by lower exports in remaining periods. We conclude that climate change, along with additional processes associated with human activities, channels old soil carbon into more rapidly cycled carbon pools of the hydrosphere.

Several pressure sensors were deployed in a small lake to determine its storage change. It could be shown that a deep enough deployment and an averaging over a time interval of 1 hour and 5 measuring points allowed for a measurement of 1 or 2 kg/m 2 (i.e. 2 mm of water column) of changes in the storage on the scale of the lake size. This accuracy for the lake storage could not be achieved by other methods, especially if conditions were difficult, e.g. snowfall, or in cases when precipitation was small. Finally, the pressure measurement – originally intended to roughly determine the water level – turned out to be a direct measurement of water mass in the lake, which was the proper magnitude for exchanges between atmosphere and lake. Hence the measurement of lake storage could become an interesting approach even for meteorological measurements, such as precipitation and evaporation on a water surface.

Temporal variability and spatial heterogeneity of surface runoff generation triggers the dynamics of source areas of sediment and sediment-associated nutrient transport. Reliable modelling of hydrological special situations i.e. snowmelt is of high importance for the quality of erosion and sediment yield modelling. Data from the research catchment Schafertal demonstrate the individuality of snowmelt events in terms of runoff coefficient and delivery ratio. This 1.44 km2 low mountain catchment is characterised by a high portion of arable land with a winter grain/winter rape crop rotation. The integrated winter erosion and nutrient load model (IWAN) considers these dynamic aspects by coupling a hydrological model with a sediment load model. Cell size of this raster-based approach is 10 × 10 m2. Additionally, snowmelt rill erosion is simulated with a newly developed physically based model that is firstly applied on a catchment scale. A sensitivity analysis of this model system component demonstrates the plausibility of the model approach and the overall robustness of the model system IWAN. The results of the long-term hydrological modelling from 1991 to 2003 are reliable and form the basis for the simulation of six snowmelt events which were observed in the Schafertal catchment. The estimated total runoff volumes for these events match the observations well. The modelled overland runoff coefficients vary from 0.001 to 0.72. The mean values of cell erosion, which were modelled with one set of parameters for all six events range from 0.0006 to 0.96 t ha− 1. The total modelled erosion for the events with unfrozen soil and low amount of surface runoff is of a factor 50 below those with partly frozen soil. In addition to these distinctions, the major differences are caused by flow accumulation in shallow depressions in variable parts of the catchment. However, the validation of these results on the single event scale is restricted due to limited spatial data. Total simulated sediment yield at the catchment outlet was as high as 13.84 t which underestimates the observed values, with the exception of one event. Oversimplification of the modelled channel processes may be a reason. The temporal variability and spatial heterogeneity of the surface roughness parameter, which was identified to be sensitive, also causes uncertainty in the parameter estimation. Despite these findings, the model system IWAN was applied successfully on the catchment scale and the simulated results are reliable.

Abstract Current research suggests that strategies to control sediment and phosphorus loss from non-point sources should focus on different runoff components and their spatial and temporal variations within the river basin. This is a prerequisite for determining effective management measures for reducing diffuse source pollution. Therefore, non-point source models, especially in humid climatic regions, should consider variable hydrologically active source areas. These models should be able to consider runoff generation by saturated overland flow, as well as Hortonian overland flow. A combination of the hydrological model WaSiM-ETH and the erosion and P-transport model AGNPS was chosen for this study. The models were run in the WaSiM runoff generation mode (Green & Ampt/TOPMODEL or Richards equation approach) and the SCS curve number mode to assess the effect of these different runoff calculation procedures on the dissolved phosphorus yield. A small and a medium-sized river basin, of the area of 1...