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Iron silicide samples were grown on Si (111) substrates by solid phase epitaxy and reactive deposition epitaxy. The different iron silicide phases and their correlations with the growth parameters were analyzed by x-ray photoelectron spectroscopy, conversion electron Mossbauer spectroscopy, x-ray diffraction, atomic force microscopy, and magnetic force microscopy. The authors investigated the potential of each technique for identifying and quantifying of the phases. In particular, the authors used a semiquantitative analysis of magnetic force microscopy images to spatially resolve the semiconductor β-FeSi2 phase.

Off-stoichiometric NiZn ferrite was obtained by hydrothermal process and compacted in torus form under different pressures. Two samples A1 and A2 - cobalt doped (0.5 %) were sintered at 1573 K in air atmosphere during 3 h. The magnetic properties were studied by vibrating sample magnetometry, Mössbauer spectroscopy and complex impedanciometry. X-ray diffraction and Hg porosimetry were used in order to determine the average grain size and the type of packing in the samples. Both samples exhibited superparamagnetic behavior in the hysteresis loop. This effect does not agree with Mössbauer results, which were fitted using Normos, a commercial computer program. All samples parameters were compared.

We analyze the effects of the environment on the spin tunneling process of paramagnetic and superparamagnetic particles and conclude that the non assisted macroscopic tunneling rate is hardly affected in such case, but other more effective (phonon mediated) processes change the magnetization state of the particle. We conclude that for both, paramagnetic and superparamagnetic particles, the decoherence time scale is extremely short (~ 10^(-8..-16)seg), indicating thar coherent tunneling should be strongly suppressed in favor of incoherent tunneling, i.e., the population of higher levels with subsequent decay., 5 pages, 2 figures, 1 table