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Mid-infrared (mid-IR) spectroscopy provides a way to study structures and dynamics of complicated molecules in condensed phases. Therefore, developing compact and broadband mid-IR spectrometer has been a long-standing challenge. Here, we show that a highly coherent and broadband mid-IR frequency comb can be generated by using an intra-pulse difference-frequency-generation with a train of pulses from a few-cycle Ti:Sapphire oscillator. By tightly focusing the oscillator output beam into a single-pass fan-out-type periodically-poled lithium niobate crystal and tilting the orientation of the crystal with respect to incident beam, it is shown that mid-IR frequency comb with more than an octave spectral bandwidth from 1550 cm-1 (46 THz) to 3650 cm-1 (110 THz) and vanishing carrier-envelop offset phase can be generated. Then, using two coherent mid-IR frequency combs, we demonstrate that ultrabroad mid-IR dual frequency comb spectroscopy of both aromatic compounds and amino acids in solutions is experimentally feasible. We thus anticipate that our mid-IR frequency combs could be used to further develop ultrafast and broadband IR spectroscopy of chemically reactive and biological molecules in condensed phases., Comment: 31 pages, 9 figures are included in the PDF file