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4. Electronic states of vanadium(III) in trans-VCl2(H2O)4 + chromophore

Author

Kammoun, Souha, Dammak, Mohamed, Maalej, Ramzi, and Kamoun, Mohamed

Subjects
*VANADIUM, *ABSORPTION, *ENERGY levels (Quantum mechanics), *MOLECULAR spectroscopy
Abstract

Abstract: The polarized absorption spectra of vanadium(III) in Cs3VCl6·4H2O complex are presented in the UV–vis region and correspond to the transition from the ground state 3T1g(3F) to the excited states 3T2g(3F), 3T1g(3P) and 3A2g(3F). Semiempirical calculations of the crystal-field levels of the vanadium(III) with D 4h point group symmetry in Cs3VCl6·4H2O chromophore are carried out, leading to a good agreement between the theoretical and experimental energy levels. [Copyright &y& Elsevier]

Published
2008
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