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Returning humans to the Moon presents an unprecedented opportunity to determine the origin of volatiles stored in the permanently shaded regions (PSRs), which trace the history of lunar volcanic activity, solar wind surface chemistry, and volatile delivery to the Earth and Moon through impacts of comets, asteroids, and micrometeoroids. So far, the source of the volatiles sampled by the Lunar Crater Observation and Sensing Satellite (LCROSS) plume (1, 2) has remained undetermined. We show here that the source could not be volcanic outgassing and the composition is best explained by cometary impacts. Ruling out a volcanic source means that volatiles in the top 1–3 meters of the Cabeus PSR regolith may be younger than the latest volcanic outgassing event (~ 1 billion years ago; Gya) (3).

We review the importance of recent UV observations of solar system targets and discuss the need for further measurements, instrumentation and laboratory work in the coming decade. In the past decade, numerous important advances have been made in solar system science using ultraviolet (UV) spectroscopic techniques. Formerly used nearly exclusively for studies of giant planet atmospheres, planetary exospheres and cometary emissions, UV imaging spectroscopy has recently been more widely applied. The geyser-like plume at Saturn's moon Enceladus was discovered in part as a result of UV stellar occultation observations, and this technique was used to characterize the plume and jets during the entire Cassini mission. Evidence for a similar style of activity has been found at Jupiter's moon Europa using Hubble Space Telescope (HST) UV emission and absorption imaging. At other moons and small bodies throughout the solar system, UV spectroscopy has been utilized to search for activity, probe surface composition, and delineate space weathering effects; UV photometric studies have been used to uncover regolith structure. Insights from UV imaging spectroscopy of solar system surfaces have been gained largely in the last 1-2 decades, including studies of surface composition, space weathering effects (e.g. radiolytic products) and volatiles on asteroids (e.g. [2][39][48][76][84]), the Moon (e.g. [30][46][49]), comet nuclei (e.g. [85]) and icy satellites (e.g. [38][41-44][45][47][65]). The UV is sensitive to some species, minor contaminants and grain sizes often not detected in other spectral regimes. In the coming decade, HST observations will likely come to an end. New infrastructure to bolster future UV studies is critically needed. These needs include both developmental work to help improve future UV observations and laboratory work to help interpret spacecraft data. UV instrumentation will be a critical tool on missions to a variety of targets in the coming decade, especially for the rapidly expanding application of UV reflectance investigations of atmosphereless bodies.

Understanding the origin and evolution of the lunar volatile system is not only compelling lunar science, but also fundamental Solar System science. This white paper (submitted to the US National Academies' Decadal Survey in Planetary Science and Astrobiology 2023-2032) summarizes recent advances in our understanding of lunar volatiles, identifies outstanding questions for the next decade, and discusses key steps required to address these questions.

We present observations of five stellar occultations for (11351) Leucus and reports from two efforts on (21900) Orus. Both objects are prime mission candidate targets for the Lucy Discovery mission. Combined results for Leucus indicate a very dark surface with p V = 0.037 ± 0.001, which is derived from the average of the multichord occultations. Our estimate of the triaxial ellipsoidal shape is for axial diameters of 63.8 × 36.6 × 29.6 km assuming that the spin pole is normal to the line of sight. The actual shape of the object is only roughly elliptical in profile at each epoch. Significant topography is seen with horizontal scales up to 30 km and vertical scales up to 5 km. The most significant feature is a large depression on the southern end of the object as seen from a terrestrial viewpoint. For this work we developed a method to correct for differential refraction, accounting for the difference in color between the target object and the reference stars for astrometry derived from ground-based images.