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Contaminant transport through a single hole in a geomembrane (GM) that forms part of composite liner with a geosynthetic clay liner (GCL) for applied heads (0.3 and 1 m) and an applied pressure of about 100 kPa is modeled and compared with experimental results. The system was first permeated with distilled water until a steady state was reached. The permeant was then switched to an NaCl solution. The inferred interface transmissivity at steady state (after 280 days) is about 2.3 x [10.sup.-11] [m.sup.2]/s for both heads examined. After 800 days permeation with an 0.14 mol/L NaCl solution, the interface transmissivity between the geomembrane and GCL was inferred to have decreased from 2.3 x [10.sup.-11] to 1.1 x [10.sup.-11] [m.sup.2]/s for experiments with heads of both 0.3 and 1 m. Modeling of the flow and changes in the GCL hydraulic conductivity arising from interaction between the bentonite and the 0.14 mol/L NaCl permeant is shown to give excellent agreement with the observed leakage. The differences between modeling a uniform and nonuniform interface transmissivity is found to be small--with the leakage being dominated by the interface transmissivity 0.1 to 0.15 m from the hole in the GM. Typical published values for the diffusion coefficient for both the GCL and sandy soil are shown to give good predictions of effluent concentration with time and chloride distribution in the silty sand in contact with the composite liners at the end of the test. Key words: numerical modeling, leakage, composite liner, geosynthetic clay liner, advection, transport, landfill. Cet article presente la modelisation du transport de contaminants a travers un trou unique dans de la geomembrane (GM) faisant partie d'un revetement composite avec argile et geosynthetique (GCL) pour des tetes appliquees (0,3 et 1 m) et des pressions appliquees d'environ 100 kPa. Les resultats de la modelisation sont ensuite compares a des resultats experimentaux. Le systeme est d'abord infiltre avec de l'eau distillee jusqu'a ce que le regime permanent soit atteint. Ensuite, le liquide permeant est change par une solution de NaCl. La transmissivite inferee a l'interface en regime permanent (apres 280 jours) est d'environ 2,3 x [10.sup.-11] [m.sup.2]/s pour les deux tetes testees. Apres 800 jours de permeation avec une solution de 0,14 mol/L NaCl, la transmissivite de l'interface entre la geomembrane et le GCL est supposee avoir diminue de 2,3 x [10.sup.-11] [m.sup.2]/s a 1,1 x [10.sup.-11] [m.sup.2]/s pour les essais avec des tetes de 0,3 et de 1 m. La modelisation de l'ecoulement et des variations de conductivite hydraulique du GCL survenant en reponse aux interactions entre la bentonite et la solution de 0,14 mol/L NaCl demontre des correspondances excellentes avec les fuites observees. Les differences entre la modelisation d'une transmissivite a l'interface uniforme ou non uniforme s'averent etre faibles, les fuites etant dominees par la transmissivite a 0,1 m et 0,15 m du trou dans la GM. Des valeurs typiques publiees du coefficient de diffusion autant pour le GCL que pour le sol sablonneux permettent d'obtenir des bonnes predictions de la concentration a l'effluent avec le temps et de la distribution du chlorure dans le sable silteux en contact avec les revetements composites a la fin de l' essai. Mots-cles : modelisation numerique, fuite, revetement composite, revetement d'argile et geosynthetique, advection, transport, site d' enfouissement. [Traduit par la Redaction], Introduction Composite liners used at the base of modern landfills often involve a high-density polyethylene (HDPE) geomembrane (GM) over a geosynthetic clay liner (GCL). The primary role of the GCL [...]

A promising photolysis based technology to dechlorinate polychlorinated biphenyls (PCBs), extracted from soils, in alkaline isopropanol (IPA) as reaction medium has been proposed. To be marketable the impact of co-contaminants extracted along with the PCBs, on the photodechiorination process needs investigation. In this paper the effectiveness of the photodeclorination process on PCBs extracted from samples of a representative soil containing co-contaminants is reported. The pholodechl ori nation or PCBs extracted from weathered soils showed promising results of more than 76% dechlorination within the first hour of UV irradiation. Nearly complete dechlorination (96%) was achieved after 2 h of UV irradiation. To provide quantitative controlled appraisal of the effect of co-contaminants and explanation of the effects, dechlorination of neat Aroclor 1254 in the presence of the common co-contaminant, transformer oil, was evaluated. Further, the effect of transformer oil on some of the individual PCB congeners in the Aroclor mixture was also studied. The difference in the maximum percentage dechlorination of PCBs with and without transformer oil is 15%. Key words: PCBs, extraction, dechlorination, 2-propanol, transformer oil, co-contaminants. Une technologie prometteuse basee sur la photolyse est proposee pour dechlorer les BPC extraits des sols dans un milieu de reaction compose d'alcool isopropylique alcalin. Afin d'etre commercialisable, il faut examiner l'impact des co-contaminants extraits avec les BPC lors du processus de photo-dechloration. Dans eel article, l'efficacite du processus de photo-dechloralion sur les BPC extraits d'echantillons d'un sol representatif contenant des co-contaminants est presentee. La photo-chloration des BPC extrails de sols alleres a monlre des resultals de dechloraiion prometteurs de plus de 76% dans la premiere heure de rayonnement UV. Une dechloration presque complete (96 %) a ete realisee apres 2 heures de rayonnement UV. Pour fournir une evaluation quantitative controlee de l'effet des co-contaminants et I'explication des effets. la dechloration d'Aroclor 1254 pur en presence du co-contaminant commun, de l'huile de transformateur, a ete evaluee. De plus, l'effet de l'huile de transformateur sur certains des congeneres individuels des BPC dans le melange d'Aroclor a egalement ete etudie. La difference dans le pourcentage maximum de dechloration des BPC avec et sans huile de transformateur est de 15%. Mots-cles: BPC. extraction, dechloration. alcool isopropylique. huile de transformateur, co-contaminants. [Traduit par la Redaction], Introduction Recent successes on the dechlorination of polychlorinated biphenyls (PCBs) using UV, has opened possibilities of applying this technique to remediate PCB contaminated soils and sediments. The dechlorination of PCBs [...]

Small, volatile hydrocarbons, including trichloroethylene, vinyl chloride, carbon tetrachloride, benzene, and chloroform, are common environmental pollutants that pose serious health effects. We have developed transgenic poplar (Populus tremula x Populus alba) plants with greatly increased rates of metabolism and removal of these pollutants through the overexpression of cytochrome P450 2E1, a key enzyme in the metabolism of a variety of halogenated compounds. The transgenic poplar plants exhibited increased removal rates of these pollutants from hydroponic solution. When the plants were exposed to gaseous trichloroethylene, chloroform, and benzene, they also demonstrated superior removal of the pollutants from the air. In view of their large size and extensive root systems, these transgenic poplars may provide the means to effectively remediate sites contaminated with a variety of pollutants at much faster rates and at lower costs than can be achieved with current conventional techniques. CYP2E1 | P4SO | poplar | trichloroethylene | carbon tetrachloride